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A New Facile One-Pot Method for Preparation of 1,1-bis(silyl)alkene Via Imine Precursor

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Abstract

Aniline reacts with variety of aryl aldehydes in ethanol to afford the corresponding imines. The reaction of imines with tris(dimethylsilyl)methyl lithium, (HMe2Si)3CLi, in THF at − 10°C gives 1,1-bis(silyl)-1-alkenes derivatives bearing Si-H functional and reactive groups.

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Authors and Affiliations

  1. Department of Chemistry, Malek-ashtar University of Technology, Shahin-shahr, 83145/115, Iran

    Yones Mosaei Oskoei, Ali Mousavi-azar, Alireza Madram & Mehran Hayaty

  2. Islamic Azad University Marand Branch, Marand, Iran

    Akbar Hassanpour

Authors
  1. Yones Mosaei Oskoei
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  2. Ali Mousavi-azar
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  3. Alireza Madram
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  4. Akbar Hassanpour
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  5. Mehran Hayaty
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Correspondence to Yones Mosaei Oskoei.

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Oskoei, Y.M., Mousavi-azar, A., Madram, A. et al. A New Facile One-Pot Method for Preparation of 1,1-bis(silyl)alkene Via Imine Precursor. Silicon 4, 251–257 (2012). https://doi.org/10.1007/s12633-012-9128-9

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  • DOI: https://doi.org/10.1007/s12633-012-9128-9

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