Nano Research

, Volume 4, Issue 4, pp 414–424

Block copolymer-templated BiFeO3 nanoarchitectures composed of phase-pure crystallites intermingled with a continuous mesoporosity: Effective visible-light photocatalysts?

Authors

  • Christian Reitz
    • Institute of Physical ChemistryJustus-Liebig-University Giessen
  • Christian Suchomski
    • Institute of Physical ChemistryJustus-Liebig-University Giessen
  • Christoph Weidmann
    • Institute of Physical ChemistryJustus-Liebig-University Giessen
    • Institute of Physical ChemistryJustus-Liebig-University Giessen
Research Article

DOI: 10.1007/s12274-011-0096-y

Cite this article as:
Reitz, C., Suchomski, C., Weidmann, C. et al. Nano Res. (2011) 4: 414. doi:10.1007/s12274-011-0096-y

Abstract

Herein is reported the soft-templating synthesis of visible-light photoactive bismuth ferrite (BiFeO3) nanoarchitectures in the form of thin films using a poly(ethylene-co-butylene)-block-poly(ethylene oxide) diblock copolymer as the structure-directing agent. We establish that (1) the self-assembled materials employed in this work are highly crystalline after annealing at 550 °C in air and that (2) neither the bismuth-poor Bi2Fe4O9 phase nor other impurity phases are formed. We further show that there is a distinct restructuring of the high quality cubic pore network of amorphous BiFeO3 during crystallization. This restructuring leads to films with a unique architecture that is composed of anisotropic crystallites intermingled with a continuous mesoporosity. While this article focuses on the characterization of these novel materials by electron microscopy, krypton physisorption, grazing incidence small-angle X-ray scattering, time-of-flight secondary ion mass spectrometry, X-ray photoelectron spectroscopy, UV-vis and Raman spectroscopy, we also examine the photocatalytic properties and show the benefits of the combination of mesoporosity and nanocrystallinity. Templated BiFeO3 thin films (25% porosity) with a direct optical band gap at 2.9 eV exhibit a catalytic activity for the degradation of rhodamine B much better than that of nontemplated samples. We attribute this improvement to the nanoscale porosity, which provides for more available active sites on the photocatalyst.

https://static-content.springer.com/image/art%3A10.1007%2Fs12274-011-0096-y/MediaObjects/12274_2011_96_Fig1_HTML.jpg

Keywords

Self-assembly mesoporous nanocrystalline thin films photocatalysis multiferroic

Supplementary material

12274_2011_96_MOESM1_ESM.pdf (926 kb)
Supplementary material, approximately 340 KB.

Copyright information

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2011