Abstract
Bio-energy is now emerging as a future source of energy. Pyrolysis is one of the main thermo-chemical processes that can provide a useful and valuable bio-fuel such as bio-oil and bio-char. Bio-oil was produced from an undesired bio-weed named Ipomoea carnea by thermal pyrolysis at a terminal temperature range from 350 to 600 °C with a heating rate of 10 °C/min. Maximum bio-oil yield (41.17 % of which 11.45 % is the oil phase) was obtained at a pyrolysis temperature of 550 °C. The oil obtained was characterized by Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR; 1H and 13C), and gas chromatography–mass spectroscopy (GC-MS) which revealed the presence of various hydrocarbons and alcohols. The H/C molar ratio (1.49) of the bio-oil was found to be comparable with petroleum-derived diesel. However, the presence of oxygen (35.86 %) in the form of oxygenates especially organic acids make the bio-oil acidic, which needs to be upgraded to use in the current IC engine.
Similar content being viewed by others
References
Sagi S, Patel A, Hornung A, Singh H, Apfelbacher A, Berry R (2012) Decentralised off-grid electricity generation in India using intermediate pyrolysis of residue straws. In: World Renewable Energy Forum (WREF)
Singh J, Gu S (2010) Biomass conversion to energy in India—a critique. Renew Sust Energ Rev 14:1367–1378
Ghosh S (2009) Import demand of crude oil and economic growth: evidence from India. Energ Policy 37(2):699–702
Bioenergy India (2010) A quarterly magazine on biomass energy, published under the UNDP-GEF biomass power project of MNRE, Govt. of India. Published by Winrock International India
Heo HS, Park HJ, Yim JH, Sohn JM, Park J, Kim SS, Ryu C, Jeon JK, Park YK (2010) Influence of operation variables on fast pyrolysis of Miscanthus sinensis var. purpurascens. Bioresour Technol 101:3672–3677
Yaman S (2004) Pyrolysis of biomass to produce fuels and chemical feedstocks. Energy Convers Manage 45:651–671
Jenkins BM, Ebeling JM (1985) Thermochemical properties of biomass fuels. California Agriculture. May–June, 14–16
Skoulou V, Zabaniotou A (2012) Fe catalysis for lignocellulosic biomass conversion to fuels and materials via thermochemical processes. Catal Today 196(1):56–66
Li Z, Savage PE (2013) Feedstocks for fuels and chemicals from algae: treatment of crude bio-oil over HZSM-5. Algal Res 2(2):154–163
Zhou M, Tian L, Niu L, Li C, Xiao G, Xiao R (2014) Upgrading of liquid fuel from fast pyrolysis of biomass over modified Ni/CNT catalysts. Fuel Process Technol 126:12–18
Sushil K (2011) Aquatic weeds problems and management in India. Indian J Weed Sci 43(3&4):118–138
Konwer D, Kataki R, Saikia M (2007) Production of solid fuel from Ipomoea carnea wood. Energy Sources Part A-Recovery Utilization Environ Effects 29(9):817–822. doi:10.1080/00908310500281189
Demirbas A (2009) Biorefineries: current activities and future developments. Energy Convers Manage 50:2782–2801
Mullen CA, Strahan DG, Boateng AA (2009) Characterization of various fast-pyrolysis bio-oils by NMR spectroscopy. Energy Fuels 23:2707–2718
Kanaujia PK, Sharma YK, Garg MO, Tripathi D, Singh R (2014) Effects of temperature on the physicochemical characteristics of fast pyrolysis bio-chars derived from Canadian waste biomass. Fuel 125:90–100
Demirbas A (2007) The influence of temperature on the yields of compounds existing in bio-oils obtained from biomass samples via pyrolysis. Fuel Process Technol 88:591–597
Yang H, Yan R, Chen H, Lee DH, Zheng H (2007) Characteristics of hemicelluloses, cellulose and lignin pyrolysis. Fuel 86:1781–1788
Gasparovic L, Korenova Z, Jelemensky L (2009) Kinetic study of wood chips decomposition by TGA. Proceedings of 36th International Conference of Slovak Society of Chemical Engineering, May 25–29, Tatranske Matliare, Slovakia, ISBN 978-80-227-3072-3, pp. (178) 1–14
Vallejos ME, Felissia FE, Curvelo AAS, Zambon MD, Ramos L, Area MC (2011) Analysis of lignin fractions. BioResources 6(2):1158–1171
Park HJ, Heo HS, Park Y, Yim J, Jeon J, Park J, Ryu C, Kim S (2010) Clean bio-oil production from fast pyrolysis of sewage sludge: effects of reaction conditions and metal oxide catalysts. Bioresour Technol 101:S83–S85
Ucar S, Karagoz S (2009) The slow pyrolysis of pomegranate seeds: the effect of temperature on the product yields and bio-oil properties. J Anal Appl Pyrolysis 84:151–156
Sensoz S, Angin D (2008) Pyrolysis of safflower (Charthamus tinctorius L.) Seed press cake: part 1: the effects of pyrolysis parameters on the product yields. Bioresour Technol 99(13):5492–7
Farha S, Farha K, Farha P (2014) Method for the production of polyethylene terephthalate with low carbon footprint. World patent WO2014079572 A1, filed November 21, 2013 and issued May 30
Mullen CA, Boateng AA, Goldberg NM, Lima IM, Laird DA, Hicks KB (2010) Bio-oil and bio-char production from corn cobs and stover by fast pyrolysis. Biomass Bioenergy 34:67–74
Agblevor FA, Beis S, Kim SS, Mante NO (2010) Biocrude oils from the fast pyrolysis of poultry litter and hardwood. Waste Manage 30:298–307
Czernik S, Bridgwater AV (2004) Overview of applications of biomass fast pyrolysis oil. Energy Fuels 18:590–598
Oasmaa A, Czernik S (1999) Fuel oil quality of biomass pyrolysis oils state of the art for the end users. Energy Fuels 13(4):914–921
Zhang R, Zhong Z, Huang Y (2009) Combustion characteristics and kinetics of bio-oil. Front Chem Eng China 3(2):119–124
Lehto J, Oasmaa A, Solantausta Y, Kyto M, Chiaramonti D (2013) Fuel oil quality and combustion of fast pyrolysis bio-oils. Espoo. VTT Technology 79. 87
Radlein D, Wang J, Yuan Y, Quignard A (2013) Methods of upgrading bio-oil to transportation grade hydrocarbon fuels. E U patent EP2638129 A2, filed September 12, 2011 and issued September 18
Schaberg PW (2005) Crude oil derived and gas-to-liquids diesel fuel blends. World Patent WO2005105961 A1, filed April 22, 2005 and issued November 10
Islam MR, Tushar MSHK, Haniu H (2008) Production of liquid fuels and chemicals from pyrolysis of Bangladeshi bicycle/rickshaw tire wastes. J Anal Appl Pyrolysis 82:96–109
Ates F, Putun E, Putun AE (2004) Fast pyrolysis of sesame stalk: yields and structural analysis of bio-oil. J Anal Appl Pyrolysis 71(2):779–790
Putun AE, Apaydın E, Putun E (2004) Rice straw as a bio-oil source via pyrolysis and steam pyrolysis. Energy 29(12–15):2171–2180
Sensoz S, Demiral I, Gercuel HF (2006) Olive bagasse (Olea europea L.) pyrolysis. Bioresour Technol 97(3):429–436
Silverstein RM, Bassler GC, Morrill TC (1991) Spectrometric identification of organic compounds. 5th Ed, John Wiley & Sons, Inc
Xu Y, Hu X, Li W, Shi Y (2011) Preparation and characterization of bio-oil from biomass, progress in biomass and bioenergy production, Dr. Shahid Shaukat (Ed.), ISBN: 978-953-307-491-7
Jone M, Fleming SA (2010) Organic chemistry. Norton, 4th edn. pp14–16
Acknowledgments
The authors are thankful to the Council of Scientific and Industrial Research (CSIR) for funding this work and Director, CSIR-North East Institute of Science and Technology (NEIST), Jorhat, Assam for providing facilities to complete this work.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Saikia, P., Gupta, U.N., Barman, R.S. et al. Production and Characterization of Bio-Oil Produced from Ipomoea carnea Bio-Weed. Bioenerg. Res. 8, 1212–1223 (2015). https://doi.org/10.1007/s12155-014-9561-2
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12155-014-9561-2