Skip to main content
SpringerLink
Log in

Synthesis, characterization and isotherm studies of new composite sorbents

  • Published:
Bulletin of Materials Science Aims and scope Submit manuscript

Abstract

With different methods, different molar ratios and different surfactants have been investigated to reach the optimum conditions for synthesized zirconium tungstate (Zr(IV)W). Zr(IV)W with different molar ratios of o-toluidine was synthesized to reach the optimum conditions for poly-o-toluidine zirconium tungstate (POTZr(IV)W). POTZr(IV)W with different molar ratios of tungstate was used to achieve the optimum conditions for poly-o-toluidine Zr(IV) tungstophosphate (POTZr(IV)WP). The Na+ capacity for all the prepared materials was investigated in order to determine the best ion exchanger towards the absorbed ions. The chemical and physical properties of materials were determined. Sorption isotherm studies of La3+, Ce3+, Nd3+ and Sm3+ ions were performed at different reaction temperatures and analysed by Langmuir, Freundlich, Dubinin–Raduchkivich and Temkin isotherm models. Thermodynamic parameters such as ΔG°, ΔH° and ΔS° were determined and found to be endothermic and spontaneous in nature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10
Figure 11
Figure 12
Figure 13
Figure 14
Figure 15

Similar content being viewed by others

References

  1. Veliscek-Carolan J, Hanley T L and Luca V 2014 Sep. Purif. Technol. 129 150

    Article  Google Scholar 

  2. Justyna J, Dorota K, Hubicki and Zbigniew 2010, Can. J. Chem. 88 540

    Article  Google Scholar 

  3. Demirbas A, Pehlivan E, Gode F, Altun T and Arslan G 2005 J. Colloid. Interf. Sci. 282 20

    Article  Google Scholar 

  4. Siddiqui W A, Khana S A and Inamuddin 2007, J. Colloid. Surf. A 295 193

    Article  Google Scholar 

  5. El-Naggar I, Zakaria E and Ali I 2004 Sep. Purif. Technol. 39 4

    Google Scholar 

  6. Ali I, Zakaria E and El-Naggar I 2004 Arab. J. Nucl. Sci. Technol. 37 31

    Google Scholar 

  7. Zakaria E, Ali I and Aly H 2004 Adsorption 10 45

    Article  Google Scholar 

  8. Varshney K G, Rafiquee M Z A and Somya A 2008 Colloid. Surf. A 317 400

    Article  Google Scholar 

  9. El-Naggar I M, Zakaria E S, Ali I M, Khalil M and El-Shahat M F 2012 Arab. J. Chem. 5 109

    Article  Google Scholar 

  10. El-Naggar I M, Zakaria E S, Ali I M, Khalil M and El-Shahat M F 2012 J. Environ. Radioactiv. 112 108

    Article  Google Scholar 

  11. El-Naggar I M, Zakaria E S, Ali I M, Khalil M and El-Shahat M F 2012 Adv. Chem. Eng. Sci. 2 166

    Article  Google Scholar 

  12. Topp N E and Pepper K W 1949 J. Chem. Soc. 3299

  13. Abd El-Latif M M and Elkady M F 2011 Desalination 271 41

  14. Khan A A and Inamuddin 2006, React. Funct. Polym. 66 1649

    Article  Google Scholar 

  15. Nabi S A, Akhtar A, Khan Md D A and Khan M A 2014 Desalination 340 73

    Article  Google Scholar 

  16. Ali I 2004 J. Radioanal. Nucl. Chem. 260 149

    Article  Google Scholar 

  17. Rao C N R 1963 Chemical applications of infrared spectroscopy (NY: Academic Press) p 355

  18. Rao C N R 1963 Chemical applications of infrared spectroscopy (NY: Academic Press) p 250

  19. Davis M 1963 Infrared spectroscopy and molecular structure (Amsterdam: Elsevier Publishing Co.) p 318

  20. Miller F A and Wilkins C H 1952 Anal. Chem. 24 1253

    Article  Google Scholar 

  21. Rao C N R 1963 Chemical applications of infrared spectroscopy (NY: Academic Press) p 353

  22. Khan A A and Akhtar T 2009 Electrochimica Acta 54 3320

    Article  Google Scholar 

  23. Chabukswar V S, Bhavsar and Horne A 2011 Chem. Technol. 5 37

    Google Scholar 

  24. Kulkarni M V and Viswanath A K 2004 Eur. Polym. J. 40 379

    Article  Google Scholar 

  25. Abdiryim T, Xiao-Gang Z and Jamal R 2005 J. Appl. Polym. Sci. 96 1630

    Article  Google Scholar 

  26. Kulkarni M V, Viswanath A K and Mulik U P 2005 Mater. Chem. Phys. 89 1

    Article  Google Scholar 

  27. Fujita I, Ishiguchi M, Shiota H, Danj T and Kosai K 1992 J. Appl. Polym. Sci. 44 987

    Article  Google Scholar 

  28. Ali I M, Kotp Y H and Elnaggar I M 2010 Desalination 259 228

    Article  Google Scholar 

  29. Khan A A, Inamuddin and Alam M M 2005 Mater. Res. Bull. 40 289

    Article  Google Scholar 

  30. Alberti G, Torracca E and Conte A 1966 J. Inorg. Nucl. Chem. 28 607

    Article  Google Scholar 

  31. Vasiliu S, Bunia I, Racovita S and Neagu V 2011 Carbohyd. Polym. 85 376

    Article  Google Scholar 

  32. Ibrahim H S, Jamil T S and Hegazy E Z 2010 J. Hazard. Mater. 182 842

    Article  Google Scholar 

  33. Ali I M, Zakaria E S, Ibrahim M M and El-Naggar I M 2008 Polyhedron 27 429

    Article  Google Scholar 

  34. Weber T W and Chakravot R K 1974 AIChE J. 20 228

    Article  Google Scholar 

  35. Freundlich H M F 1906 Z. Phys. Chem. 57 385

    Google Scholar 

  36. Khalil M 2012 Chemical studies on poly aniline titanotungstate as a new composite cation exchanger and its analytical applications for removal of cesium from aqueous solution, Ain Shams University, Cairo, Egypt

  37. Dubinin M M, Zaverina E D and Radushkevich L I V 1947 Russ. J. Phys. Chem. A 21 1351

    Google Scholar 

  38. Chabani M, Amrane A and Bensmaili A 2006 Chem. Eng. J. 125 111

    Article  Google Scholar 

  39. Temkin M I and Pyzhev V 1940 Acta Phys.-Chim. USSR 12 327

    Google Scholar 

  40. Sheha R R and Metwally E 2007 J. Hazard. Mater. 143 354

    Article  Google Scholar 

  41. Smith J M and Van Ness H C 1987 Introduction to chemical engineering thermodynamics, 4th edn (Singapore: McGraw-Hill)

    Google Scholar 

  42. Zakaria E S, Ali I M and El-Naggar I M 2002 Colloid. Surf. A 210 33

    Article  Google Scholar 

  43. Zakaria E S, Ali I M and Aly H F 2009 J. Colloid. Interf. Sci. 338 346

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Atomic Energy Authority, Hot Labs Center, Cairo, 13759, Egypt

    E S ZAKARIA, I M ALI, M KHALIL & A EL-TANTAWY

  2. Faculty of Science, Chemistry Department, Benha University, Benha, 13518, Egypt

    T Y MOHAMED

Authors
  1. E S ZAKARIA
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I M ALI
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M KHALIL
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T Y MOHAMED
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A EL-TANTAWY
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M KHALIL.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

ZAKARIA, E.S., ALI, I.M., KHALIL, M. et al. Synthesis, characterization and isotherm studies of new composite sorbents. Bull Mater Sci 39, 1709–1724 (2016). https://doi.org/10.1007/s12034-016-1321-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12034-016-1321-9

Keywords

Search

Navigation