Abstract
This paper presents test results concerning the selection of sodium salt for the technology of continuous modification of the EN AC-AlSi12 alloy, which is based on electrolysis of sodium salts, occurring directly in a crucible with liquid alloy. Sodium ions formed as a result of the sodium salt dissociation and the electrolysis are ‘transferred’ through walls of the retort made of solid electrolyte. Upon contact with the liquid alloy, which functions as a cathode, sodium ions are transformed into the atomic state, modifying the alloy. As a measure of the alloy modification extent, the obtained increase of the tensile strength R m and change of metallographic structure are used, confirming obtained modification effect of the investigated alloy.
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References
Pacz A 1921 US Patent No. 1387900
Pietrowski S 2001 Silumins (Łódź: Technical University Editorial) p 195
Fatahalla N, Hafız M and Abdulkhalek M 1999 J. Mater. Sci. 34 3555
Nogita K and Dahle A K 2001 Mater. Trans. 42 207
Hegde S and Prabhu K N 2008 J. Mater. Sci. 43 3009
Closset B and Gruzleski J E 1982 Metall. Trans. A 13 945
Gilbert J and Rooy E L 2004 Aluminum alloy castings: properties, processes and applications (OH, USA: ASM International) p 40
Nogita K, McDonald S D and Dahle A K 2004 Mater. Trans. 45 323
Krupiński M, Labisz K, Dobrzański L A and Rdzawski Z 2010 Arch. Foundry Eng. 10 79
Davis J R 1993 Aluminum and aluminum alloys (OH, USA: ASM International) p 223
Poniewierski Z 1989 Crystallization and properties of silumins (Warszawa: WNT) p 73
Wasilewski P 1993 Modification and its impact on structure and properties. Monography, solidification of metals and alloys (PAN Katowice) Vol. 21, p 106
Białobrzeski A, Dudek P, Fajkiel A, Leśniewski W et al 2006 Arch. Foundry 6 97
Białobrzeski A, Saja K and Leśniewski W 2007 Arch. Foundry Eng. 7 57
Yan X Y, Langberg D E and Rankin W J 1995 Metall. Mater. Trans. B 26 1005
Dunn B and Farrington G C 1980 Mater. Res. Bull. 15 1773
Wen Z, Cao J, Gu Z, Xu X, Zhang F and Lin Z 2008 J. Solid State Ionics 179 1697
Moseley P T, Bones R J, Teagle D A, Bellamy B A and Hawes R W M 1989 J. Electrochem. Soc. 136 1361
Lu X C, Xia G G, Lemmon J P and Yang Z G 2010 J. Power Sources 195 2431
May G J 1978 J. Power Sources 3 1
Sudworth J L 2001 J. Power Sources 100 149
Fray D J 2003 Metall. Mater. Trans. B 34 589
Fray D J 1977 Metall. Trans. B 8 153
Doughty G, Fray D J, Van Der Poorten C and DeKeyser J 1996 J. Solid State Ionics 86–88 193
Białobrzeski A 2007 Arch. Foundry Eng. 7 53
Sigworth G K 1983 AFS Trans. 91 7
Pan E N, Cherng Y G, Lin C A and Chiou H S 1994 AFS Trans. 70 609
Fredriksson H, Hillert M and Lange N 1973 J. Inst. Met. 101 285
Liu Q Y, Li Q C and Liu Q F 1991 Acta Metall. Mater. 39 2497
Rathoda H R and Manghani J V 2012 Int. J. Emerg. Trends Eng. Dev. 2 573
Brown J 1999 Foseco non-ferrous Foundryman’s handbook (UK: Butterworth-Heinemann) p 56
Mondolfo L F 1965 J. Austral. Inst. Met. 10 169
Lu S Z and Hellawell A 1987 Metall. Mater. Trans. A 18 1721
Onyia C, Okorie B, Neife S and Obayi C 2013 World J. Eng. Technol. 1 9
Jian X, Meek T and Han Q 2006 Scr. Mater. 54 893
Nafisi S and Ghomashchi R 2006 Mater. Sci. Eng. A 415 273
Liu L, Samuel A M, Samuel F H, Doty H W and Valtierra S 2004 J. Mater. Sci. 39 215
Zhang X H, Su G C, Ju C W, Wang W C and Yan W L 2010 Mater. Des. 31 4408
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The present work was performed within framework of Research Project no. 3 T08B 063 29 financed by the State Committee for Scientific Research (MNiSW).
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PEZDA, J., BIAŁOBRZESKI, A. Use of sodium salt electrolysis in the process of continuous modification of eutectic EN AC-AlSi 1 2 alloy. Bull Mater Sci 38, 373–377 (2015). https://doi.org/10.1007/s12034-015-0875-2
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DOI: https://doi.org/10.1007/s12034-015-0875-2