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Influence of Applied Voltage and Film-Formation Time on Microstructure and Corrosion Resistance of Coatings Formed on Mg-Zn-Zr-Ca Bio-magnesium Alloy

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Abstract

The influence of applied voltage and film-formation time on the microstructure and corrosion resistance of coatings formed on a Mg-Zn-Zr-Ca novel bio-magnesium alloy has been investigated by micro-arc oxidation (MAO) treatment. Phase composition and microstructure of as-coated samples were analyzed by the x-ray diffraction, energy dispersive x-ray spectroscopy and scanning electron microscopy. And the porosity and average of micro-pore aperture of the surface on ceramic coatings were analyzed by general image software. Corrosion microstructure of as-coated samples was caught by a microscope digital camera. The long-term corrosion resistance of as-coated samples was tested in simulated body fluid for 30 days. The results showed that the milky white smooth ceramic coating formed on the Mg-Zn-Zr-Ca novel bio-magnesium alloy was a compound of MgO, Mg2SiO4 and MgSiO3, and its corrosion resistance was significantly improved compared with that of the magnesium substrate. In addition, when the MAO applied voltage were 450 V and 500 V and film-formation time were 9 min and 11 min, the surface micro-morphology and the corrosion resistance of as-coated samples were relatively improved. The results provided a theoretical foundation for the application of the Mg-Zn-Zr-Ca novel bio-magnesium alloy in biomedicine.

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Acknowledgment

The authors are grateful for the financial support from the Key Project of the Natural Science Foundation of Heilongjiang Province (ZD 201202).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Harbin University of Science and Technology, 4# Linyuan Road, Xiangfang District, Harbin, 150040, China

    Yu Yandong, Kuang Shuzhen & Li Jie

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  1. Yu Yandong
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  2. Kuang Shuzhen
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  3. Li Jie
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Correspondence to Yu Yandong.

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Yandong, Y., Shuzhen, K. & Jie, L. Influence of Applied Voltage and Film-Formation Time on Microstructure and Corrosion Resistance of Coatings Formed on Mg-Zn-Zr-Ca Bio-magnesium Alloy. JOM 67, 2133–2144 (2015). https://doi.org/10.1007/s11837-015-1528-z

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  • DOI: https://doi.org/10.1007/s11837-015-1528-z

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