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Synthesis and Evaluation of a Novel Co-Initiator for Dentin Adhesives: Polymerization Kinetics and Leachables Study

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Abstract

A new tertiary amine co-initiator containing three methacrylate-urethane groups was synthesized for the application in dentin adhesives. The photopolymerization kinetics and leaching of unreacted components from methacrylate-based dental polymers formulated with this new co-initiator were determined. The newly synthesized co-initiator showed good chemical stability and decreased amine release from the initiator system. This study provides important information for the future development of biocompatible dentin adhesives/composites.

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Acknowledgements

This investigation was supported by Research Grant R01 DE022054 from the National Institute of Dental and Craniofacial Research, National Institutes of Health.

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Authors and Affiliations

  1. Bioengineering Research Center, School of Engineering, University of Kansas, Lawrence, KS, 66047-3729, USA

    Xueping Ge, Qiang Ye, Linyong Song & Paulette Spencer

  2. Department of Pharmaceutical Chemistry, University of Kansas, Lawrence, KS, 66047-3729, USA

    Jennifer S. Laurence

  3. Department of Mechanical Engineering, University of Kansas, Lawrence, KS, 66047-3729, USA

    Paulette Spencer

Authors
  1. Xueping Ge
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  2. Qiang Ye
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  3. Linyong Song
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  4. Jennifer S. Laurence
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  5. Paulette Spencer
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Corresponding author

Correspondence to Qiang Ye.

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Ge, X., Ye, Q., Song, L. et al. Synthesis and Evaluation of a Novel Co-Initiator for Dentin Adhesives: Polymerization Kinetics and Leachables Study. JOM 67, 796–803 (2015). https://doi.org/10.1007/s11837-015-1335-6

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  • DOI: https://doi.org/10.1007/s11837-015-1335-6

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