Abstract
Pure polystyrene-b-poly(ethylene-ran-butylene)-b-polystyrene (SEBS) was functionalized with amine moiety first through nitration, followed by reduction. The resulting amine modified SEBS was blended with various amounts of epoxy via in situ reactive approach. Thin blend films were initially cured at 120 °C for 30min and post cured at 180 °C for 2 h. These films were then analyzed for their mechanical, thermal and morphological profile. Optimum improvement in tensile strength, modulus and toughness was observed with different epoxy loading in the blends. These blends were found thermally stable up to 300 °C. The morphological studies indicated ample compatibility between the two components of blends.
Graphical abstract
Similar content being viewed by others
References
D. R. Paul and C. B. Bucknall, Polymer blends: Formulation and performance, Wiley, NY (2000).
T. Araki, Q. Tran-Cong and M. Shibayama, Structure and properties of multiphase polymeric materials, Marcel Dekker, NY (1998).
M. Xanthos, Reactive extrusion: Principles and practice, Hanser, NY (1994).
S.Y. Hobbs, M. E. J. Dekkers and V.H. Watkins, Polymer, 29, 1598 (1988).
W.T. Cheng, H. Keskkula and D.R. Paul, Polymer, 33, 1606 (1992).
H. F. Guo, S. Packirisamy, N.V. Gvozdic and D. J. Meier, Polymer, 38, 785 (1997).
H. F. Guo, N.V. Gvozdic and D. J. Meier, Polymer, 38, 4915 (1997).
A. N. Wilkinson, L. Laugel, M. L. Clemens, V. M. Harding and M. Marin, Polymer, 40, 4971 (1999).
J. Rosch and R. Mülhaupt, Polym. Bull., 32, 697 (1994).
S. Horiuchi, N. Matchariyakul, K. Yase and T. Kitano, Macromolecules, 30, 3664 (1997).
B. Ballauri, M. Trabuio and F. P. LaMantia, In: Recycling of PVC and mixed plastics, F. P. LaMantia (Ed.), Toronto: Chem. Tec., 77 (1996).
K. Heino, J. Kirjava, P. Hietaoja and J. Seppala, J. Appl. Polym. Sci., 65, 241 (1996).
C. P. Papadopoulou and N.K. Kalfoglou, Polymer, 41, 2543 (2000).
S. Shabbir, S. Zulfiqar, I. Lieberwirth, A. Kausar and M. I. Sarwar, Surf. Interface Anal., 40, 906 (2008).
C. A. May, Epoxy Resins, Chemistry and Technology, Marcel Dekker, NY (1988).
H. Lee and K. Neville, Handbook of Epoxy Resins, McGraw-Hill, NY (1990).
B. Ellis, Chemistry and technology of epoxy resins, Blackie Academic and Professional, Glasgow (1993).
Z. Chen, J. Yang, Q. Ni, S. Fu and Y. Huang, Polymer, 50, 4753 (2009).
M. A. Hillmyer, P.M. Lipic, D. A. Hajduk, K. Almdal and F. S. Bates, J. Am. Chem. Soc., 119, 2749 (1997).
P. M. Lipic, F. S. Bates and M. A. Hillmyer, J. Am. Chem. Soc., 120, 8963 (1998).
J.M. Dean, P. M. Lipic, R. B. Grubbs, R. F. Cook and F. S. Bates, J. Polym. Sci. Part B Polym. Phys., 39, 2996 (2001).
J.M. Dean, N. E. Verghese, H. Q. Pham and F. S. Bates, Macro-molecules, 36, 9267 (2003).
J.M. Dean, R. B. Grubbs, W. Saad, R. F. Cook and F. S. Bates, J. Polym. Sci. Part B Polym. Phys., 41, 2444 (2003).
J. Wu, Y. Thio and F. S. Bates, J. Polym. Sci. Part B Polym. Phys., 43, 1950 (2005).
A. Kausar, S. Zulfiqar, S. Shabbir, M. Ishaq and M. I. Sarwar, Polym. Bull., 59, 457 (2007).
S. Shabbir, S. Zulfiqar, Z. Ahmad and M. I. Sarwar, Polym. Eng. Sci., 48, 1793 (2008).
R. P. Singh, M. Zhang and D. Chan, J. Mater. Sci., 37, 781 (2002).
S. Zulfiqar, Z. Ahmad, M. Ishaq, S. Saeed and M. I. Sarwar, J. Mater. Sci., 42, 93 (2007).
J.R. Wünsch, Polystyrene: Synthesis, Production and Applications, iSmithers Rapra Publishing, Shropshire, 31 (2000).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Zulfiqar, S., Fatima, I. & Sarwar, M.I. Property profile of nanostructured blends of amine functionalized elastomer and epoxy. Korean J. Chem. Eng. 32, 191–198 (2015). https://doi.org/10.1007/s11814-014-0166-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-014-0166-4