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Complete oxidation of 1,2-dichlorobenzene over V2O5-TiO2 and MnO x -TiO2 aerogels

  • Catalysis, Reaction Engineering
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Abstract

Catalytic destruction of 1,2-dichlorobenzene was carried out over two types of aerogels, vanadia-titania and manganese oxide-titania. Reactions were performed in a plug flow reactor in the range of 150–600 °C. Both catalysts resulted in very high selectivity to carbon oxides and produced negligible amount of hydrocarbon byproducts. Over the vanadia-titania catalysts, the chlorinated compound was relatively more efficiently destructed at lower temperature, while selectivity towards carbon dioxide was much higher over manganese oxide-titania aerogel catalysts. Vanadiatitania catalysts, regardless of the preparation methods, showed a tendency to produce carbon monoxide with 35–45% selectivity throughout the reaction temperature range while manganese oxide-titania exhibited more than 90% CO2 selectivity at above 400 °C.

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Authors and Affiliations

  1. Coal Chemistry Research Project, Research Institute of Industrial Science and Technology, Pohang, Gyeongbuk, 790-330, Korea

    Jinsoon Choi

  2. Clean Energy Research Center, Korea Institute of Science and Technology, P. O. Box 131, Cheongryang, Seoul, 136-791, Korea

    Dong Jin Suh

Authors
  1. Jinsoon Choi
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  2. Dong Jin Suh
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Correspondence to Dong Jin Suh.

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Choi, J., Suh, D.J. Complete oxidation of 1,2-dichlorobenzene over V2O5-TiO2 and MnO x -TiO2 aerogels. Korean J. Chem. Eng. 31, 1773–1779 (2014). https://doi.org/10.1007/s11814-014-0128-x

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  • DOI: https://doi.org/10.1007/s11814-014-0128-x

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