Abstract
We prepared polyvinylchloride based nanocomposite heterogeneous cation exchange membranes by solution casting technique using cation exchange resin powder as functional groups agent and tetrahydrofuran as solvent. Silver nanoparticles were also used as fillers in membrane fabrication. The effect of silver nanoparticles concentration in casting solution on membrane physico/chemical and antibacterial characteristics was studied. The SEM images showed compact structure for the modified membranes. X-ray diffraction results also revealed that membrane crystallinity was clearly changed by increase of nanoparticle concentration. Membrane selectivity and transport number were enhanced initially by increase in nanoparticle content up to 4%wt in prepared membrane, and then showed decreasing trend by more increase in additive concentration from 4 to 8%wt. Selectivity and transport number were enhanced another time by further increase in nanoparticle loading ratio from 8 to 16%wt. Opposite trend was found for the membranes’ average grain size by variation in additive content. Ionic flux was also clearly enhanced by using Ag nanoparticles in membrane matrix. Moreover, modified membranes showed good ability in decrease of Escherichia coli growth rate.
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R. K. Nagarale, G. S. Gohil, V. K. Shahi, G. S. Trivedi and R. Rangarajan, J. Colloid Interface Sci., 277, 162 (2004).
S. M. Hosseini, S. S. Madaeni and A. R. Khodabakhshi, Sep. Sci. Technol., 45, 2308 (2010).
T. Xu, J. Membr. Sci., 263, 1 (2005).
K. Hideo, K. Tsuzura and H. Shimizu, Ion exchange membranes, in: K. Dorfner (Ed.), Ion Exchangers, Walter de Gruyter, Berlin (1991).
H. Strathmann, Electrodialysis and related processes, in: R.D. Noble, S. A. Stern (Eds.), Membrane Separation Technology-Principles and Applications, Elsevier Science B.V., 214 (1995).
M. Juda and W. A. McRac, J. Am. Chem. Soc., 72, 1044 (1950).
A.G. Winger, G.W. Bodamer and R. Kunin, J. Electrochem. Soc., 100, 178 (1953).
G. Pourcelly and C. Gavach, Electrodialysis water splitting-application of electrodialysis with bipolar membranes, in: A. J. B. Kemperman (Ed.), Handbook on Bipolar Membrane Technology, Twente University Press, Enschede, 17 (2000).
T. Xu, Desalination, 140, 247 (2001).
G. Daufin, J. P. Escudier, H. Carrere, S. Berot, L. Fillaudeau and M. Decloux, Food and Bioproducts Processing, 79, 89 (2001).
T. Tarvainen, B. Svarfvar, S. Akerman, J. Savolainen, M. Karhu, P. Paronen and K. Jarvinen, Biomaterials, 20, 2177 (1999).
Y. H. Kim and S. H. Moon, J. Chem. Technol. Biotechnol., 76, 169 (2001).
G. Saracco, Annali di Chimica, 93, 817 (2003).
L. Bazinet, F. Lamarche and D. Ippersiel, Trends in Food Sci. Technol., 9, 107 (1998).
T. Xu, Resour. Conserv. Recycl., 37, 1 (2002).
S. Hirose, A. Shimizu and T. Nose, J. Appl. Polym. Sci., 23, 3193 (1979).
S. Hirose and E. Yasukawa, J. Appl. Polym. Sci., 26, 1039 (1981).
O. Hiroshi, R. Kazuhiko and U. Tadashi, J. Membr. Sci., 83, 199 (1993).
M. Bodzek and K. Konieczny, J. Membr. Sci., 61, 131 (1991).
R. Varma, The medical relevance of PVC, Medical Device & Diagnostic Industry, 19 (2007).
S. M. Hosseini, S. S. Madaeni, A. R. Khodabakhshi and A. Zendehnam, J. Membr. Sci., 365, 438 (2010).
J.M. Thomassin, J. Kollar, G. Caldarella, A. Germain, R. Jerome and C. Detrembleur, J. Membr. Sci., 303, 252 (2007).
S. M. Hosseini, S. S. Madaeni and A. R. Khodabakhshi, J. Appl. Polym. Sci., 118, 3371 (2010).
S. Pourjafar, A. Rahimpour and M. Jahanshahi, J. Ind. Eng. Chem., 18, 1398 (2012).
M. Bellantone, N. J. Coleman and L. L. Hench, J. Biomed. Mater. Res., 51, 484 (2000).
S. H. Jeong, S.Y. Yeo and S. C. Yi, J. Mater. Sci., 40, 5407 (2005).
Y. L. Wang, Y. Z. Wan, X. H. Dong, G. X. Cheng, H.M. Tao and T. Y. Wen, Carbon, 36, 1567 (1998).
V. K. Shahi, G. S. Trivedi, S. K. Thampy and R. Rangarajan, J. Colloid Interface Sci., 262, 566 (2003).
G. S. Gohil, V.K. Shahi and R. Rangarajan, J. Membr. Sci., 240, 211 (2004).
A. Zendehnam, M. Arabzadegan, S.M. Hosseini, N. Robatmili and S. S. Madaeni, Korean J. Chem. Eng., 30(6), 1265 (2013).
A. Elshabini and F. D Barlow, Thin film technology Handbook, McGraw-Hill (1997).
D. K. Reily, A. T. Pavia and P.G. Beatty, American J. Medicine, 97/6, 509 (1994).
A. Sirinivasan, T. Karchmer, A. Richards, X. Song and T. M. Perl, Infection Control and Hospital Epidemiology, 27, 38 (2006).
S. M. Hosseini, S. S. Madaeni and A. R. Khodabakhshi, J. Membr. Sci., 362, 550 (2010).
X. Li, Z. Wang, H. Lu, C. Zhao, H. Na and C. Zhao, J. Membr. Sci., 254, 147 (2005).
L. Erertovr, Physics of thin films, 2nd Ed., Plenum Press (1986).
V. K. Shahi, S. K. Thampy and R. Rangarajan, J. Membr. Sci., 158, 77 (1999).
J. Kerres, W. Cui, R. Disson and W. Neubrand, J. Membr. Sci., 139, 211 (1998).
D. R. Lide, CRC Handbook of chemistry and physics, CRC Press, 87th Ed., 2006–2007.
R. K. Nagarale, V.K. Shahi, S. K. Thampy and R. Rangarajan, React. Funct. Polym., 61, 131 (2004).
M. S. Kang, Y. J. Choi, I. J. Choi, T. H. Yoon and S.H. Moon, J. Membr. Sci., 216, 39 (2003).
H. Lin and B.D. Freeman, J. Mol. Struct., 739, 74 (2005).
A. Ebadi Amooghin, H. R. Sanaeepur, A.R. Moghadassi, A. Kargari, D. Ghanbari and Z. Sheikhi Mehrabadi, Sep. Sci. Technol., 45, 1385 (2010).
K. Vasilev, J. Cook and H. J. Griesser, Expert Review of Medical Devices, 6/5, 553 (2009).
S. Y. Park and J. Choi, Environ. Eng. Res., 15(1), 23 (2010).
I. Sondi and B. S. Sondi, J. Colloid Interface Sci., 275, 177 (2004).
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Zarrinkhameh, M., Zendehnam, A. & Hosseini, S.M. Preparation and characterization of nanocomposite heterogeneous cation exchange membranes modified by silver nanoparticles. Korean J. Chem. Eng. 31, 1187–1193 (2014). https://doi.org/10.1007/s11814-014-0051-1
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DOI: https://doi.org/10.1007/s11814-014-0051-1