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Reliability of the bromthymol blue method for color in virgin olive oils

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Journal of the American Oil Chemists' Society

Abstract

The bromthymol blue (BTB) method is currently used for the assessment of color in olive and seed oils by visual comparison with standard solutions. Two BTB scales were prepared with 2 yr difference and compared, and the recent one was used to analyze 502 virgin olive oil samples, obtained by the Abencor® technique reproducing the industrial procedure. The temporal chromatic degradation of the BTB samples after 2 yr [3.93 Commission Internationale de l’Eclairage (CIE) 1976-(L*a*b*) (CIELAB) units, on the average], as well as the small percentage of virgin olive oils matching the colors of the samples provided by the BTB scales (13.1% with a suprathreshold color tolerance of 1.52 CIELAB units), indicates the limitations of the BTB method. Linear regression models are proposed in order to compute with acceptable accuracy the BTB indices from chromaticparameters. The use of CIELAB for the specification and future studies on color in virgin olive oils is recommended.

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References

  1. Belbin, A.A., Color in Oils, INFORM 4:648–654 (1993).

    Google Scholar 

  2. Official Methods and Recommended Practices of the American Oil Chemists’ Society, AOCS Press, 4th edn., Champaign, 1993, Method Cc 13e-92.

  3. Official Methods and Recommended Practices of the American Oil Chemists’ Society, AOCS Press, 4th edn., Champaign, 1993, Method Td 1a-64.

  4. Official Methods and Recommended Practices of the American Oil Chemists’ Society, AOCS Press, 4th edn., Champaign, 1993, Method Cc 13b-45.

  5. Official Methods and Recommended Practices of the American Oil Chemists’ Society, American Oil Chemists’ Society, Champaign, 1989, Method Td 1b-64.

  6. Official Methods and Recommended Practices of the American Oil Chemists’ Society, American Oil Chemists’ Society, Champaign, 1989, Method Td 2a-64.

  7. Official Methods and Recommended Practices of the American Oil Chemists’ Society, American Oil Chemists’ Society, Champaign, 1989, Method Cc 13c-50.

  8. IUPAC, Spectrophotometric Determination of the Colour, in Standard Methods for the Analysis of Oils, Fats and Derivatives, Blackwell Scientific Publications, 7th edn., Oxford, 1987, 1992, Method 2.103.

  9. Berner, D., Color-in-Oils Study Results Are In, J. Am. Oil Chem. Soc. 66:313–315 (1989).

    Google Scholar 

  10. AENOR, Índice de Color ABT. Norma UNE 55021, Asociación Espańola de Normalización y Certificación, Madrid, 1997.

  11. Gutiérrez, R., and F. Gutiérrez, Método Rápido para Definir el Color de los Aceites de Oliva Vírgenes, Grasas Aceites 37:282–284 (1986).

    Google Scholar 

  12. Burón, I., A. Cruz, R. García, and M. Rubiño, El Color del Aceite de Oliva Virgen. Estudio Preliminar. IV Simposio Científico-Técnico Expoliva, Jaen, pp. 67–75 (1989).

  13. Billmeyer, F.W., and M. Saltzman, Principles of Color Technology, 2nd edn., Chapters 1, 2, 5, and 6, John Wiley & Sons, New York (1981).

    Google Scholar 

  14. Mínguez-Mosquera, M.I., L. Rejano-Navarro, B. Gandul-Rojas, A.H. Sánchez-Gómez, and J. Garrido-Fernández, Color-Pigment Correlation in Virgin Olive Oil, J. Am. Oil Chem. Soc. 68:332–336 (1991).

    Google Scholar 

  15. Brát, J., W. Zschau, and J. Zajíc, Korrelation der Farbcharakteristiken des Rapssamenöls, Fat Sci. Technol. 95:432–435 (1993).

    Google Scholar 

  16. Ayala, F., J.F. Echávarri, A.I. Negueruela, A. Cruz, and M.C. Fernández, Reconstrucción del Espectro de Aceites de Oliva Mediante Vectores Característicos. Aplicaciones Colorimétricas, III Congreso Nacional de Color, Jarandilla de la Vera (1997).

  17. Guillén, R., F. Yépez, F. Heredia, and M. Guzmán, Chromatic Parameters and Oxidation Indices for Edible Vegetable Oils Submitted to Thermal Oxidation, J. Sci. Food Agric. 54:619–633 (1991).

    Article  Google Scholar 

  18. Escolar, D., M.R. Haro, A. Saucedo, A. Jiménez, and J.A. Álvarez, Color Determination in Olive Oils, J. Am. Oil Chem. Soc. 71:1333–1337 (1994).

    Article  CAS  Google Scholar 

  19. Kuehni, R.G., Industrial Color Difference: Progress and Problems, Color Res. Appl. 15:261–265 (1990).

    Google Scholar 

  20. Komatsubara, H., and G. Kawakami, Research on the Application of Color-Difference Formulas to Industry, Stud. Color 35:6–20 (1988).

    Google Scholar 

  21. CIE Publication No. 15.2. Colorimetry (Technical Report). CIE Central Bureau, Vienna (1986).

  22. CIE Publication No. 116. Industrial Color-Difference Evaluation (Technical Report). CIE Central Bureau, Vienna (1995).

  23. Martínez, J.M., E. Muñoz, J. Alba, and A. Lanzón, Informe sobre Utilización del Analizador de Rendimientos “Abencor,” Grasas Aceites 26:379–385 (1975).

    Google Scholar 

  24. Melgosa, M., E. Hita, A.J. Poza, D.H. Alman, and R.S. Berns, Suprathreshold Color-Difference Ellipsoids for Surface Colors, Color Res Appl. 22:148–155 (1997).

    Article  Google Scholar 

  25. Fujii, E., H. Fujii, and T. Hisanaga, Evaluation of the Stability of Light Faded Images of Colour Xerography According to Colour Differences in CIELAB, J. Photograph. Sci. 36:87–91 (1988).

    CAS  Google Scholar 

  26. Salas, C., M. Melgosa, and E. Hita, Experimental Study on the Chromatic Degradation of Samples Obtained by a Colour Photocopy Process, Atti, Fond. Giorgio Ronchi 5:721–733 (1996).

    Google Scholar 

  27. Melgosa, M., M.M. Pérez, L. Jiménez del Barco, and E. Hita, A Test of TC1-29 Color-Difference Formula Using Some Classical Datasets (preliminary report), Proc. European Optical Society Annual Meeting, 3:37–38 (1993), edited by Departamento de Física Aplicada, Universidad de Zaragoza, Zaragoza, Spain.

    Google Scholar 

  28. Melgosa, M., J.J. Quesada, and E. Hita, Uniformity of Some Recent Colormetrics Tested with an Accurate Color-Difference Tolerance Dataset, Appl. Opt. 33:8069–8077 (1994).

    Article  Google Scholar 

  29. Witt, K., Parametric Effects on Surface Color-Difference Evaluation at Threshold, Color Res. Appl. 15:189–199 (1990).

    Google Scholar 

  30. Luo, M.R., and B. Rigg, Chromaticity-Discrimination Ellipses for Surface Colours, Ibid.:25–42 (1986).

    Google Scholar 

  31. Berns, R.S., D.H. Alman, L. Reniff, G.D. Snyder, and M.R. Balonon-Rosen, Visual Determination of Suprathreshold Color-Difference Tolerances Using Probit Analysis, Ibid.:297–316 (1991).

    Google Scholar 

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Correspondence to F. J. Heredia.

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Moyano, M.J., Melgosa, M., Alba, J. et al. Reliability of the bromthymol blue method for color in virgin olive oils. J Amer Oil Chem Soc 76, 687–692 (1999). https://doi.org/10.1007/s11746-999-0160-x

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  • DOI: https://doi.org/10.1007/s11746-999-0160-x

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