Skip to main content
Log in

Effect of oil replenishment during deep-fat frying of frozen foods in sunflower oil and high-oleic acid sunflower oil

  • Published:
Journal of the American Oil Chemists' Society

Abstract

Frying stability of sunflower oil (SO) with 23% oleic acid and 61% linoleic acid, and of high-oleic acid sunflower oil (HOSO) with 74% oleic acid and 13% linoleic acid was studied during 20 discontinuous deep-fat fryings of various frozen foods, with or without frequent replenishment of the used oil with fresh oil. Alterations of both oils were measured by column, gas-liquid and high-performance size-exclusion chromatography. Total polar content and compounds, related to thermoxidative changes, and diacylglycerides, related to hydrolytic changes, increased in all oils during frying but reached higher levels in SO than in HOSO. Nevertheless, the increased levels of diacylglycerides observed may result from the frozen potatoes prefried in palm oil. Oleic acid in HOSO and linoleic acid in SO significantly decreased, but the fatty acid modifications that occurred during the repeated fryings were not only related to thermoxidative alteration but also to interactions between the bath oil and the fat in the fried products. Data from this study also indicated that HOSO performed more satisfactorily than SO in repeated fryings of frozen foods. Moreover, frequent addition of fresh oil throughout the deep-frying process minimized thermoxidative and hydrolytic changes in the frying oils and extended the frying life of the oils.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Friedman, B., New Control of Frying Process Provides Major Reduction of Oil in Food, in Fat and Cholesterol Reduced Foods: Technologies and Strategies, edited by C. Haberstroh, and C.E. Morris, Gulf Publishing Co., Houston, Texas, 1988, pp. 141–152.

    Google Scholar 

  2. Cuesta, C., F.J. Sánchez-Muniz, C. Garrido-Polonio, S. López-Varela, and R. Arroyo, Thermoxidative and Hydrolytic Changes in Sunflower Oil Used in Fryings with a Fast Turnover of Fresh Oil, J. Am. Oil Chem. Soc. 70:1069–1073 (1993).

    Article  CAS  Google Scholar 

  3. Sánchez-Muniz, F.J., C. Cuesta, and C. Garrido-Polonio, Sunflower Oil Used for Frying: Combination of Column, Gas and High-Performance Size-Exclusion Chromatography for Its Evaluation, Ibid.:235–240 (1993).

    Article  Google Scholar 

  4. Thompson, L.U., and R. Aust, Lipid Changes in French Fries Heated Oils During Commercial Deep Frying and Their Nutritional and Toxicological Implications, Can. Inst. Food Sci. Technol. 16:246–253 (1983).

    CAS  Google Scholar 

  5. Sánchez-Muniz, F.J., C. Cuesta, S. López-Varela, M.C. Garrido-Polonio, and R. Arroyo, Evaluation of the Thermal Oxidation Rate of Sunflower Oil Using Various Frying Methods, in Proceedings of World Conference on Oilseed and Technology and Utilization, edited by T.H. Applewhite, American Oil Chemists’ Society, Champaign, 1993, pp. 448–452.

    Google Scholar 

  6. Arroyo, R., C. Cuesta, J.M. Sánchez-Montero, and F.J. Sánchez-Muniz, High-Performance Size Exclusion Chromatography of Palm Olein Used for Frying, Fat Sci. Technol. 97:292–296 (1995).

    CAS  Google Scholar 

  7. Keijbets, M.J.H., G. Ebbenhorst-Seller, and J. Ruisch, Suitability of Hydrogenated Soybean Oils for Prefrying of Deep-Frozen French Fries, J. Am. Oil Chem. Soc. 62:720–724 (1985).

    CAS  Google Scholar 

  8. Cuesta, C., F.J. Sánchez-Muniz, A. Rodríguez, and G. Varela, Alteraciones Fisicoquímicas de un Aceite de Oliva Empleado en Frituras Repetidas y Su Incidencia Sobre la Lipoproteinemia de Ratas. Rev. Esp. Fisiol. 43:51–56 (1987).

    PubMed  CAS  Google Scholar 

  9. Billek, G., Heated Oils—Chemistry and Nutritional Aspects, Nut. Metab. 24:200–210 (1980).

    CAS  Google Scholar 

  10. Gupta, M.K., Designing Frying Fat, in Proceedings of World Conference on Oilseed and Technology and Utilization, edited by T.H. Applewhite, American Oil Chemists’ Society, Champaign, 1993, pp. 204–208.

    Google Scholar 

  11. Nestel, P., P. Clifton, and M. Noakes, Effects of Increasing Dietary Palmitoleic Acid Compared with Palmitic and Oleic Acids on Plasma Lipids of Hypercholesterolemic Men, J. Lipid Res. 35:656–662 (1994).

    PubMed  CAS  Google Scholar 

  12. Berger, K.G., Problems and Opportunities in Market Development of Oils, in Fats for the Future, edited by R.C. Cambie, Ellis Horwood Ltd., Chichester, England, 1989, pp. 217–232.

    Google Scholar 

  13. Cuesta, C., F.J. Sánchez-Muniz, and A. Romero, Use of Domestic Fryer Among University Students Families. Preliminary Data, in 2nd International Symposium on Frying of Foods, January 25–26, 1996, Madrid, Spain.

  14. International Union of Pure and Applied Chemistry, in Standard of Methods for the Analysis of Oils, Fats and Derivatives, edited by C. Paquot and A. Hautfenne, Blackwell Scientific Publications, Oxford, 1987, Method 2.301.

    Google Scholar 

  15. Waltking, A.E., and H. Wessels, Chromatographic Separation of Polar and Nonpolar Components of Frying Fats, J. Assoc. Off. Anal. Chem. 64:1329–1330 (1981).

    CAS  Google Scholar 

  16. Dobarganes, M.C., M.C. Pérez-Camino, and R. Gutiérrez González-Quijano, Métodos Analíticos de Aplicación en Grasas Calentadas. I. Determinación de Esteres Metílicos No Alterados, Grasas y Aceites, 35:172–177 (1984).

    CAS  Google Scholar 

  17. Perrin, J.L., F. Rodero, and A. Prevost, Dosage Rapid des Polymers de Triglycerides par Chromatographie d’Exclusion. I. Aspects Qualitatif, Rev. Franç. Corps Gras. 31:131–133 (1984).

    CAS  Google Scholar 

  18. Dobarganes M.C., M.C. Pérez-Camino, and G. Márquez-Ruíz. High-Performance Size-Exclusion Chromatography of Polar Compounds in Heated and Nonheated Fats, Fat. Sci. Technol. 90:308–311 (1988).

    CAS  Google Scholar 

  19. Christopoulou, C., and E.G. Perkins, High-Performance Size-Exclusion Chromatography of Monomer, Dimer and Trimer Mixtures, J. Am. Oil Chem. Soc. 66:1338–1343 (1989).

    Article  CAS  Google Scholar 

  20. Arroyo, R., C. Cuesta, C. Garrido-Polonio, S. López-Varela, and F.J. Sánchez-Muniz, High-Performance Size-Exclusion Chromatographic Studies on Polar Components Formed in Sunflower Oil Used For Frying, Ibid.:557–563 (1992).

    CAS  Google Scholar 

  21. Frankel, E., Review. Recent Advances in Lipid Oxidation, J. Sci. Food Agric. 54:495–511 (1991).

    Article  CAS  Google Scholar 

  22. Pérez-Camino, M.C., G. Márquez-Ruiz, M.V. Ruiz-Méndez, and M.C. Dobarganes, Lipid Changes During Frying of Frozen Prefried Foods, J. Food Sci. 56:1644–1650 (1991).

    Article  Google Scholar 

  23. Sebedio, J.L., A. Bonpunt, A. Grandgirard, and J. Prevost, Deep Fat Frying of Frozen Prefried French Fries: Influence of the Amount of Linolenic Acid in the Frying Medium, J. Agric. Food Chem. 38:1862–1867 (1990).

    Article  CAS  Google Scholar 

  24. Castang, J., Etude sur les Huiles de Friture. Caractères Analytiques et Projet de Règlementation, Ann. Falsif. Expert. Chim. 74:701–708 (1981).

    CAS  Google Scholar 

  25. Meyer, V.H., Eine Neve Und Einfache Schellmethode zur Erfassung des Oxidativien Zersetzungsgrades Thermisch Belasteter Fette, Fette Seifen. Anstrichm. 81:524–533 (1979).

    Google Scholar 

  26. Romero, A., F.J. Sánchez-Muniz, and C. Cuesta, High-Performance Size-Exclusion Chromatographic Studies on a High-Oleic Sunflower Oil During Potato Frying, J. Am. Chem. Soc. 72:1513–1517 (1995).

    Article  CAS  Google Scholar 

  27. Kupranycz, D.B., M.A. Amer, and B.E. Baker, Effects of Thermal Oxidation on the Constitution of Butterfat, Butterfat Fractions and Certain Vegetable Oils, Ibid.:332–337 (1986).

    CAS  Google Scholar 

  28. Billek, G., Heated Fats in Diet, in The Role of Fats in Human Nutrition, edited by F.B. Padley, and J. Podmore (in collaboration with J.P. Brun, R. Burt, and B.W. Nicols), Ellis Horwood Ltd., Chichester, England, 1985, pp. 163–172.

    Google Scholar 

  29. Gutiérrez-González Quijano, R., and M.C. Dobarganes, Analytical Procedures for the Evaluation of Used Frying Fats, in Frying of Food, Principles, Changes, New Approaches, edited by G. Varela, A.E. Bender, and I.D. Morton, Ellis Horwood Ltd., Chichester, England, 1988, pp. 141–154.

    Google Scholar 

  30. Pozo-Díez, R.M., T.A. Masoud-Musa, M.C. Pérez-Camino, and M.C. Dobarganes, Intercambio Lipídico durante la Fritura de Patatas Prefritas Congeladas en Aceite de Girasol Alto Oleico, Grasas y Aceites 46:85–91 (1995).

    Google Scholar 

  31. Rodríguez, A., C. Cuesta, F.J. Sánchez-Muniz, and G. Varela. Estudio de las Alteraciones en Grasas Producidas por Frituras e Incidencia de su Administración sobre el Peso e Ingesta, Ibid.:22–28 (1984).

    Google Scholar 

  32. Guillaumin, R., Kinetics of Fat Penetration in Food, in Frying of Food, Principles, Changes, New Approaches, edited by G. Varela, A.E. Bender, and I.D. Morton, Ellis Horwood Ltd., Chichester, 1988, pp. 544–549.

    Google Scholar 

  33. Nawar, W.W., Chemical Changes in Lipids Produced by Thermal Processing, J. Chem. Educ. 61:299–302 (1984).

    Article  CAS  Google Scholar 

  34. González-Muñoz, M.J., C. Tulasne, R. Arroyo, and F.J. Sánchez-Muniz, Digestibility and Absorption Coefficients of Palm Olein. Relationships with Thermal Oxidation Induced by Potato Frying, Fett/Lipid, 98:104–108 (1996).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Carmen Cuesta.

About this article

Cite this article

Romero, A., Cuesta, C. & Sánchez-Muniz, F.J. Effect of oil replenishment during deep-fat frying of frozen foods in sunflower oil and high-oleic acid sunflower oil. J Amer Oil Chem Soc 75, 161–167 (1998). https://doi.org/10.1007/s11746-998-0028-5

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11746-998-0028-5

Key words

Navigation