Abstract
Chocolate model systems were designed with high-melting fat (cocoa butter stearin, CB-S) mixed with low-melting fats (sunflower oil, canola oil, cottonseed oil, peanut oil) to give 45, 55, and 65 % solid fat content (SFC). Defatted cocoa powder provided a 50 % particulate level in the model chocolates. The effects of SFC, low-melting fat type and storage temperature fluctuation frequency on bloom whiteness were investigated. Both SFC and storage condition had significant influences on bloom whiteness (p < 0.0001), although the type of low-melting fat did not (p = 0.1223). Increasing the SFC significantly reduced bloom formation, as did more rapid temperature fluctuations.
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References
Lonchampt P, Hartel RW (2004) Fat bloom in chocolate and compound coatings. Eur J Lipid Sci Technol 106:241–274
Sato K, Koyano T (2001) Crystallization properties of cocoa butter. In: Garti N, Sato K (eds) Crystallization processes in fats and lipids systems. Marcel Dekker, New York, pp 429–456
Sonwai S, Rousseau D (2006) Structure evolution and bloom formation in tempered cocoa butter during long-term storage. Eur J Lipid Sci Technol 108:735–745
Bricknell J, Hartel RW (1998) Relation of fat bloom in chocolate to polymorphic transition of cocoa butter. J Am Oil Chem Soc 75:1609–1615
Paulicka FR (1973) Phase behavior of cocoa butter extenders. Chem Ind 17:835–839
Given P, Wheele E, Noll G, Finley J (1989) Physical–chemical behavior of confectionery fats. J Dispersion Sci Technol 10:505–530
Hartel RW (1999) Chocolate: fat bloom during storage. Manuf Confect 79:89–99
Matsuda H, Yamaguchi M, Arima H (2001) Separation and crystallization of oleaginous constituents in cosmetics: sweating and blooming. In: Garti N, Sato K (eds) Crystallization processes in fats and lipid systems. Marcel Dekker, New York, pp 485–504
Ali A, Selamat J, Che Man YB, Suria AM (2001) Effect of storage temperature on texture, polymorphic structure, bloom formation and sensory attributes of filled dark chocolate. Food Chem 72(4):491–497
Smith KW, Cain FW, Talbot G (2007) Effect of nut oil migration on polymorphic transformation in a model system. Food Chem 102:656–663
Sahari MA, Zarringhlami S, Barzegar M, Hamidi-Esfehani Z (2013) Fat bloom and polymorphism in chocolate prepared with modified tea seed oil. J Tea Sci Res 3(1):1–6
Ransom-Painter KL, Williams SD, Hartel RW (1997) Incorporation of milk fat and milk fat fractions into compound coatings made from palm kernel oil. J Dairy Sci 80:2237–2248
Walter P, Cornillon P (2001) Influence of thermal conditions and presence of additives on fat bloom in chocolate. J Am Oil Chem Soc 78:927–932
Quevedo R, Brown C, Bouchon P, Aguilera JM (2005) Surface roughness during storage of chocolate: fractal analysis and possible mechanisms. J Am Oil Chem Soc 82(6):457–462
IUPAC (1987) Standard methods for the analysis of oils, fats and derivatives, 7th edn, method 2.150. Blackwell Science, Oxford
Kleinert J (1970) Cocoa butter and chocolate: the correlation between tempering and structure. Rev Int Choc 25(11):386–399
Barna CM, Hartel RW, Metin S (1992) Incorporation of milk-fat fractions into milk chocolates. Manuf Confect 72:107–116
Zhou Y, Hartel RW (2006) Phase behavior of model lipid systems: solubility of high-melting fats in low-melting fats. J Am Oil Chem Soc 83(6):505–511
Bockisch M (1998) Fats and oils handbook. AOCS Press, Urbana
Weiss TJ (1983) Food oils and their uses, 2nd edn. AVI Publication Company Inc, Westport
Loisel C, Keller G, Lecq G, Bourgaux C, Ollivon M (1998) Phase transitions and polymorphism of cocoa butter. J Am Oil Chem Soc 75:425–439
Ziegler GR, Shetty A, Anantheswaran RC (2004) Nut oil migration through chocolate. Manuf Confect 84:118–126
Guiheneuf TM, Couzens PJ, Wille HJ, Hall LD (1997) Visualisation of liquid triacylglycerol migration in chocolate by magnetic resonance imaging. J Sci Food Agric 73:265–273
Aguilera JM, Michel M, Mayor G (2004) Fat migration in chocolate: diffusion or capillary flow in a particulate solid?—a hypothesis paper. J Food Sci 69(7):167–174
Timms RE (2003) Confectionery fats handbooks. The Oily Press, Bridgwater
Dahlenborg H, Millqvist-Fureby A, Bergenstahl B (2015) Effect of particle size in chocolate shell on oil migration and fat bloom development. J Food Eng 146:172–181
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Jin, J., Hartel, R.W. Accelerated Fat Bloom in Chocolate Model Systems: Solid Fat Content and Temperature Fluctuation Frequency. J Am Oil Chem Soc 92, 1473–1481 (2015). https://doi.org/10.1007/s11746-015-2709-1
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DOI: https://doi.org/10.1007/s11746-015-2709-1