Skip to main content
Log in

Processing vegetable oils using nonporous denser polymeric composite membranes

  • Review
  • Published:
Journal of the American Oil Chemists' Society

Abstract

Membrane processing offers several advantages over conventional processes for edible oil refining. In recent years, processing solvent-extracted, screw-pressed, and used frying oils using nonporous denser polymeric composite membranes without pretreatment and addition of chemicals has been extensively investigated. In the present review, results obtained with real and model systems have been summarized and a comprehensive explanation is provided on the mechanism of rejection and differential permeation of oil constituents. Phospholipid-TG and pigment-TG systems are construed as conventional solute-solvent systems, and tocopherol-TG and FFA-TG systems are treated as liquid mixtures exhibiting differential permeability. Dense membrane theory appears more applicable than the reverse osmosis theory in qualitatively explaining the differential permeability of liquid constituents of the oil. Membrane processing of oils appears to have the potential to be a one-step process, especially for screw-pressed oils, in producing a premium-quality product. However, the development of suitable membranes that enable higher fluxes is necessary for industrial adoption of this technology.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Young, F.V.K., C. Poot, E. Biernoth, N. Krog, N.G.J. Davidson, and F.D. Gunstone, Processing of Fats and Oils, in The Lipid Handbook, 2nd edn., edited by F.D. Gunstone, J.L. Harwood, and F.B. Padley, Chapman & Hall, London, 1994, pp. 249–276.

    Google Scholar 

  2. Cheryan, M., Ultrafiltration and Microfiltration Handbook, Technomic, Lancaster, PA, 1998, pp. 406–413.

    Google Scholar 

  3. Gupta, A.K.S., Process for Refining Crude Glyceride Oils by Membrane Filtration, U.S. Patent 4,062,882 (1977).

  4. Iwama, A., New Process for Purifying Soybean Oil by Membrane Separation and Economical Evaluation of the Process, J. Am. Oil Chem. Soc. 64:1258 (1987).

    Google Scholar 

  5. Koseoglu, S.S., K.C. Rhee, and E.W. Lusas, Membrane Processing of Crude Vegetable Oils: Laboratory Scale Membrane Degumming, Refining and Bleaching, in Proceedings of the World Conference on Edible Fats and Oils Processing: Basic Principles and Modern Practices, edited by D.R. Erickson, American Oil Chemists' Society, Champaign, 1990, pp. 182–188.

    Google Scholar 

  6. Keurentjes, J.T.F., G.I. Doornbusch, and K. van't Riet, The Removal of Fatty Acids from Edible Oil: Removal of the Dispersed Phase of Water-in-Oil Dispersions by a Hydrophilic Membrane, Sep. Sci. Technol. 26:409–423 (1991).

    CAS  Google Scholar 

  7. Keurenties, J.T.F., J.T.M. Sluijs, R.-J.H. Franssen and K. van't Riet, Extraction and Fractionation of Fatty Acids from Oil Using an Ultrafiltration Membrane, Ind. Eng. Chem. Res. 31:581–587 (1992).

    Article  Google Scholar 

  8. Raman, L.P., M. Cheryan, and N. Rajagopalan, Deacidification of Soybean Oil by Membrane Technology, J. Am. Oil Chem. Soc. 73:219–224 (1996).

    Article  CAS  Google Scholar 

  9. Krishna Kumar, N.S., and D.N. Bhowmick, Separation of Fatty Acids/Triacylglycerol by Membranes, ——Ibid. 73:399–401 (1996).

    Article  Google Scholar 

  10. Kale, V., S.P.R. Katikaneni, and M. Cheryan, Deacidifying Rice Bran Oil by Solvent Extraction and Membrane Technology, ——Ibid. 76:723–727 (1999).

    CAS  Google Scholar 

  11. Lin, N., K.C. Rhee, and S.S. Koseoglu, Bench-Scale Membrane Degumming of Crude Vegetable Oil: Process Optimization, J. Membrane Sci. 134:101–108 (1997).

    Article  CAS  Google Scholar 

  12. Pioch, D., C. Largueze, J. Graille, H. Ajana, and J. Rouviere, Towards an Efficient Membrane Based Vegetable Oils Refining, Ind. Crops Prod. 7:83–89 (1998).

    Article  CAS  Google Scholar 

  13. Zhang, S.Q., O. Kutowy, and A. Kumar, Application of Ultrafiltration Membranes in Refining of Crude Vegetable Oils, in Proceedings of the 8th Annual Meeting of North American Membrane Society, Ottawa, Canada, 1996, p. 95.

  14. Kondal Reddy, K., R. Subramanian, T. Kawakatsu, and M. Nakajima, Decolorization of Vegetable Oils by Membrane Processing, Eur. Food Res. Technol. 213:212–218 (2001).

    Article  Google Scholar 

  15. Subramanian, R., and M. Nakajima, Membrane Degumming of Crude Soybean and Rapeseed Oils, J. Am. Oil Chem. Soc. 74:971–975 (1997).

    CAS  Google Scholar 

  16. Subramanian, R., A. Yasui, and M. Nakajima, Removal of Nonhydratable Phosphatide from Vegetable Oils Using Polymeric Membranes, in Proceedings of 7th International Congress on Engineering and Food, edited by R. Jowitt, Sheffield Academic Press, Sheffield, United Kingdom, 1997, pp. L37-L40.

    Google Scholar 

  17. Subramanian, R., M. Nakajima, and T. Kawakatsu, Processing of Vegetable Oils Using Polymeric Composite Membranes, J. Food Eng. 38:41–56 (1998).

    Article  Google Scholar 

  18. Subramanian, R., M. Nakajima, T. Kimura, and T. Maekawa, Membrane Process for Premium Quality Expeller-Pressed Vegetable Oils, Food Res. Int. 31:587–593 (1998).

    Article  CAS  Google Scholar 

  19. Subramanian, R., K.E. Nandini, P.M. Sheila, A.G. Gopalakrishna, K.S.M.S. Raghavarao, M. Nakajima, T. Kimura, and T. Maekawa, Membrane Processing of Used Frying Oils, J. Am. Oil Chem. Soc. 77:323–328 (2000).

    CAS  Google Scholar 

  20. Subramanian, R., S. Ichikawa, M. Nakajima, T. Kimura, and T. Maekawa, Characterization of Phospholipid Reverse Micelles in Relation to Membrane Processing of Vegetable Oils, Eur. J. Lipid Sci. Technol. 103:93–97 (2001).

    Article  CAS  Google Scholar 

  21. Subramanian, R., H. Nabetani, M. Nakajima, S. Ichikawa, T. Kimura, and T. Maekawa, Rejection of Carotenoids in Oil Systems by a Nonporous Polymeric Composite Membrane, J. Am. Oil Chem. Soc. 78:803–807 (2001).

    CAS  Google Scholar 

  22. Subramanian, R., K.S.M.S. Raghavarao, H. Nabetani, M. Nakajima, T. Kimura, and T. Maekawa, Differential Permeation of Oil Constituents in Nonporous Polymeric Membranes, J. Membr. Sci. 187:57–69 (2001).

    Article  CAS  Google Scholar 

  23. Subramanian, R., K.S.M.S. Raghavarao, M. Nakajima, H. Nabetani, T. Yamaguchi, and T. Kimura, Application of Dense Membrane Theory for Differential Permeation of Vegetable Oil Constituents, J. Food Eng. 60:249–256 (2003).

    Article  Google Scholar 

  24. Honma, S., Melanoidines, in Shin-Shokuhinbunsekiho (in Japanese), Japanese Society for Food Science and Technology, Kourin, Tokyo, Japan, 1996, pp. 679–688.

    Google Scholar 

  25. Bockisch, M., Fats and Oils Handbook, AOCS Press, Champaign, 1998, pp. 53–120.

    Google Scholar 

  26. Mulder, M.H.V., Basic Principles in Membrane Technology, Kluwer Academic, Dordrecht, The Netherlands, 1991, pp. 210–415.

    Google Scholar 

  27. Humphrey, J.L., and G.E. Keller, Membrane Processes, in Separation Process Technology, McGraw-Hill, New York, 1997, pp. 225–287.

    Google Scholar 

  28. Lee, B.-C., and R.P. Danner, Prediction of Polymer-Solvent Phase Equilibria by a Modified Group-Contribution EOS, AIChE J. 42:837–849 (1996).

    Article  CAS  Google Scholar 

  29. Kedam, O., and A. Katchalsky, Thermodynamic Analysis of the Permeability of Biological Membranes to Non-electrolytes, Biochim. Biophys. Acta 27:229–246 (1958).

    Article  Google Scholar 

  30. Kanamoto, R., Y. Wada, G. Miyajima, and M. Kito, Phospholipid-Phospholipid Interaction in Soybean Oil, J. Am. Oil Chem. Soc. 58:1050–1053 (1981).

    CAS  Google Scholar 

  31. Ishigami, Y., Y. Gama, Y. Sano, S. Lang, and F. Wagner, Interfacial and Micellar Behavior of Glucose Lipid, Biotechnol. Lett. 16:593–598 (1994).

    Article  CAS  Google Scholar 

  32. Monma, M., J. Terao, M. Ito, M. Saito, and K. Chikuni, Carotenoid Components in Soybean Seeds Varying with Seed Color and Maturation Stage, Biosci. Biotechnol. Biochem. 58:926–930 (1994).

    Article  CAS  Google Scholar 

  33. McCabe, W.L., J.C. Smith, and P. Harriott, Unit Operations of Chemical Engineering, 5th edn., McGraw-Hill, New York, 1993, pp. 838–881.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. Subramanian.

About this article

Cite this article

Subramanian, R., Nakajima, M., Raghavarao, K.S.M.S. et al. Processing vegetable oils using nonporous denser polymeric composite membranes. J Amer Oil Chem Soc 81, 313–322 (2004). https://doi.org/10.1007/s11746-004-0901-z

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11746-004-0901-z

Key Words

Navigation