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Effect of Self-Assemblies on the Dynamics of the Briggs–Rauscher Reaction

  • Original Article
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Journal of Surfactants and Detergents

Abstract

The study involves the dynamic evolution of the Briggs–Rauscher (BR) reaction in the presence of various surfactants—SDS (sodium dodecyl sulphate) as anionic, CTAB (cetyl trimethylammonium bromide) as cationic and TritonX-100 [4-(1,1,3,3-(tetramethylbutyl) phenyl polyethylene glycol] as a neutral one in single as well as mixed mode conditions (SDS + TX-100 and CTAB + TX-100). The reaction has been monitored potentiometrically at 30 °C under CSTR conditions. These surfactants affect the reaction dynamics to an extent which depends on the nature and concentration of the surfactant and the formation of their self-assemblies. The experimental findings indicate that the oscillatory behavior of the BR reaction in the presence of surfactants is due to the efficacy of organized surfactant assemblies to selectively distribute the key species involved in the reaction, and their interaction with the counter ions in cases of ionic micelles. The study reveals that the evolution of oscillatory behavior is a characteristic feature of the surfactant.

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Acknowledgements

The authors acknowledge the support from SERB Govt. of India in the form of Major Research Project No. SB/S1/PC-23/2014 sanctioned on 20 August 2015 and to DST-FIST Funding to the department. The authors also acknowledge the Head, Department of Chemistry, for infrastructural facilities used for carrying out this work. The authors also declare that they have no conflict of interest with anybody regarding this work.

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Authors and Affiliations

  1. Department of Chemistry, University of Kashmir, Srinagar, Jammu and Kashmir, 190006, India

    Nisar Ahmad Dar, G. M. Peerzada, Nadeem Bashir, Shagufta Rashid, Sna Rashid & Showket Ahmad Akhoon

  2. Department of Chemistry, Govt. College for Women Nawakadal, Srinagar, Jammu and Kashmir, 190002, India

    Nadeem Bashir

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  1. Nisar Ahmad Dar
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  2. G. M. Peerzada
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Correspondence to Nadeem Bashir.

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Dar, N.A., Peerzada, G.M., Bashir, N. et al. Effect of Self-Assemblies on the Dynamics of the Briggs–Rauscher Reaction. J Surfact Deterg 20, 913–921 (2017). https://doi.org/10.1007/s11743-017-1956-6

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  • DOI: https://doi.org/10.1007/s11743-017-1956-6

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