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Properties of Ethoxylated Castor Oil Acid Methyl Esters Prepared by Ethoxylation over an Alkaline Catalyst

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Journal of Surfactants and Detergents

Abstract

The synthesis and properties of ethoxylated castor oil acid methyl esters (ECAME) were investigated. Ethylene oxide (EO) can react directly with the ester group and hydroxyl group of castor oil acid methyl esters in the presence of an alkaline catalyst. ECAME with different average EO adduct numbers were synthesized and, through testing the degree of EO addition, it was found that only a few EO moieties (2–4) inserted into the hydroxyl group. In addition, the physicochemical properties of ECAME were studied. ECAME can be used as nonionic surfactants with good properties.

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References

  1. Sun YQ, Luo Y, Zhang GY, Tian CH, Liu GY, Zhang W (2003) A kind of catalyst for ethoxylation and its application. CN Patent 1451476A

  2. Bialowas E, Szymanowski J (2004) Catalysts for oxyethylation of alcohols and fatty acid methyl esters. Ind Eng Chem Res 43:6267–6280

    Article  CAS  Google Scholar 

  3. Li DZ, Sun YQ, Yang XQ, Luo Y, Tian CH (2005) Detection of ethylene oxide distribution in ethoxylated castor oil acid methyl esters. China Surfactant Deterg Cosmet 35:327–330

    CAS  Google Scholar 

  4. Hama I, Okamoto T, Nakamura H (1995) Preparation and properties of ethoxylated fatty methyl ester nonionics. J Am Oil Chem Soc 72:781–784

    Article  CAS  Google Scholar 

  5. Hama I, Okamoto T, HIdai E, Yamada K (1997) Direct ethoxylation of fatty methyl ester over Al-Mg composite oxide catalyst. J Am Oil Chem Soc 74:19–24

    Article  CAS  Google Scholar 

  6. Hama I, Sasamoto H, Okamoto T (1997) Influence of catalyst structure on direct ethoxylation of fatty methyl esters over Al-Mg composite oxide catalyst. J Am Oil Chem Soc 72:817–822

    Article  Google Scholar 

  7. Zhi LF, Li QX, Li YL, Song YB (2013) Synthesis, adsorption and aggregation properties of new saccharide-cationic surfactants. Colloids Surf A 436:684–692

    Article  CAS  Google Scholar 

  8. Zhi LF, Li QX, Li YL, Song YB, Li P (2013) Effect of borax on the solubility of dicephalic gluconamide-type surfactants. J Dispers Sci Technol 34:1535–1539

    Article  CAS  Google Scholar 

  9. Luo Y, Sun YQ, Tian CH, Liu GY, Zhang W (2001) Physical and chemical properties research of ethoxylated fatty methyl esters. China Surfactant Deterg Cosmet 5:5–7

    Google Scholar 

  10. Ma LJ, Zhou MX, Feng Y (2004) Analysis of fatty acid methyl ester ethoxylates by gas chromatography. Chin J Chromatogr 22:84–86

    CAS  Google Scholar 

  11. Negm NA, El-Farargy AF, Tawfik SM, Abdelnour AM, Hefni HH, Khowdiary MM (2013) Synthesis, surface and thermodynamic properties of substituted polytriethanolamine nonionic surfactants. J Surfact Deterg 16:333–342

    Article  CAS  Google Scholar 

  12. Zhang J, Shi DL, Gong XL, Zhu FM, Du M (2013) Inhibition performance of novel dissymmetric bisquaternary ammonium salt with an imidazoline ring and an ester group. J Surfact Deterg 16:3515–3522

    Google Scholar 

  13. Li YL, Li QX, Zhi LF, Zhang MH (2011) Synthesis, characterization and surface-activity of hydroxyethyl group-containing quaternary ammonium surfactants. J Surfact Deterg 14:529–533

    Article  CAS  Google Scholar 

  14. Song YB, Li QX, Li YL, Zhi LF (2013) Synthesis and prorerties of dicephalic cationic surfactants containing a quaternary ammonium and a guanidine group. J Surfact Deterg 16:71–76

    Article  CAS  Google Scholar 

  15. Eastoe J, Nave S, Downer A, Paul A, Rankin A, Tribe K (2000) Adsorption of ionic surfactants at the air-solution interface. Langmuir 16:4511–4518

    Article  CAS  Google Scholar 

  16. Luo RX, Liu PP, Chen YB (2013) Synthesis and properties of a hydrolysis resistant cationic tersiloxane surfactant. J Surfact Deterg 16:33–38

    Article  CAS  Google Scholar 

  17. Wang RT, Li YL, Li QX (2014) Physicochemical properties of quaternary ammonium surfactants with hydroxyethyl groups. Tenside Surfact Deterg 1:54–58

    Article  Google Scholar 

  18. Zhao JZ, Zhou M, Wang X, Yang Y (2014) Synthesis and surface active properties of dimeric gemini sulfonate surfactants. Tenside Surfact Deterg 1:26–30

    Article  Google Scholar 

Download references

Acknowledgments

The authors acknowledge the financial support by the National Science and Technology Support Project of International (No. 2013DFA42120), International Science and Technology Cooperative Project of Shanxi Province (No. 2013081019), and Natural Science and Technology Support Project of China (No. 2012BAD32B10).

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Correspondence to Yongqiang Sun.

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Zhang, Q., Sun, Y., Zhi, L. et al. Properties of Ethoxylated Castor Oil Acid Methyl Esters Prepared by Ethoxylation over an Alkaline Catalyst. J Surfact Deterg 18, 365–370 (2015). https://doi.org/10.1007/s11743-014-1657-3

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  • DOI: https://doi.org/10.1007/s11743-014-1657-3

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