Abstract
In this work, the silica/polyaniline (SiO2/PANI) and silica poly(3,4-ethylenedioxythiophene) (SiO2/PEDOT) core/shell composite nanoparticles were successfully synthesized by in situ chemical oxidative polymerization. The SiO2/PANI nanocomposite film was employed as the anodically coloring electrode, and the SiO2/PEDOT nanocomposite film was employed as the cathodically coloring electrode. A viscous gel electrolyte (GE) of polymethyl methacrylate (PMMA) and lithium perchlorate (LiClO4) dissolved in propylene carbonates was used in an electrochromic device (ECD). The architectural design of dual-type ECD was glass/indium tin oxide (ITO)/SiO2-PANI/GE/SiO2-PEDOT/ITO/glass. Compared with the single-type ECD based on SiO2/PANI and SiO2/PEDOT nanocomposite films, the dual-type ECD exhibited larger optical modulation, faster response speed, higher coloration efficiency and better cycling stability.
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08 October 2020
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Acknowledgments
The authors thank the National Natural Science Foundation of China (NSFC) (Nos. 51503134, 51721091 and 21876119) and Sichuan Province Science and Technology Foundation (No. 2017GZ0429) for the financial support. The authors would like to thank the analytical and testing center of Sichuan university, and we are grateful to Hui wang for the SEM images.
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Zhang, S., Hu, F., Chen, S. et al. A Dual-Type Electrochromic Device Based on Complementary Silica/Conducting Polymers Nanocomposite Films for Excellent Cycling Stability. J. Electron. Mater. 48, 4797–4805 (2019). https://doi.org/10.1007/s11664-019-07273-9
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DOI: https://doi.org/10.1007/s11664-019-07273-9