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Dissolutive Wetting and Spreading Phenomena Between Al2O3 Substrate and CaO-Al2O3 Liquid Slags

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Abstract

The wetting and spreading behavior are influenced by the dissolution reaction. The wetting and spreading behavior between CaO-Al2O3 slag and Al2O3 substrate were investigated using the dispensed drop technique and a high speed camera (1000 frame/s) at 1823 K (1550 °C) using saturated slag and non-saturated slag on Al2O3. The contact angle of the saturated slag and the non-saturated slag was not substantially different. The apparent height of the spreading droplet for the non-saturated slag was lower than that of the saturated slag due to the formation of a crater generated by the dissolution reaction. A spherical cap model is associated with crater formation was suggested by analyzing the spread droplet and a quenched sample. The spreading rate of the non-saturated slag was faster than that of the saturated slag due to convection. For the saturated slag, the experimental values are in good agreement with the De Gennes’s theoretical model. (Non-reactive viscous model) In contrast, the non-saturated slag curve shifts the experimental curve to correspond with the saturated slag curve.

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References

  1. S.H. Lee, C. Tse, K.W. Yi, P. Misra, V. Chevrier, C. Orrling, S. Sridhar and A.W. Cramb: J. Non-Crystalline Solids., 2001, vol. 282, pp. 41-48.

    Article  Google Scholar 

  2. P.A. Thornton: J. Mater. Sci., 1974, vol. 6, pp. 347-356.

    Article  Google Scholar 

  3. K.W. Lange: Int. Mater. Reviews, 1988, vol. 33, pp. 53-89.

    Article  Google Scholar 

  4. Ja-Yong CHOI and Hae-Geon LEE: ISIJ Int., 2003, vol. 43, no. 9, pp. 1348-1355.

    Article  Google Scholar 

  5. K. Nakashima, H. Naitou, M. Isomoto, M. Kishimoto and K. Mori: Tetsu-to-Hagané., 1992, vol. 78, pp. 1674-1682.

    Google Scholar 

  6. S. Sridhar and A. W. Cramb: Metall. Mater. Trans. B., 2000, vol. 31B, pp. 406-410.

    Article  Google Scholar 

  7. K. H. Sandhage and G. J. Yurek: J. Am. Ceram. Soc., 1990, vol. 73, pp. 3633-3642.

    Article  Google Scholar 

  8. K. H. Sandhage and G. J. Yurek: J. Am. Ceram. Soc., 1990, vol. 73, pp. 3643-3649.

    Article  Google Scholar 

  9. Y. Oishi, A. R. Cooper and W. D. Kingery: J. Am. Ceram. Soc., 1965, vol. 48, pp. 88-95.

    Article  Google Scholar 

  10. L. Bates: J. Am. Ceram. Soc., 1964, vol. 70, pp. C55-C57.

    Google Scholar 

  11. S. Taira, K. Nakashima and K. Mori: Tetsu-to-Hagané., 1995, vol. 81, pp. 16-21

    Google Scholar 

  12. A. R. Cooper, Jr. and W. D. Kingery: J. Am. Ceram. Soc., 1964, vol. 47, pp. 37-43.

    Article  Google Scholar 

  13. X. Yu, R. J. Pomfret and K. S. Coley: Metall. Mater. Trans. B., 1997, vol. 28B, pp. 275-279.

    Article  Google Scholar 

  14. S. Zhang, H. R. Rezaie, H. Sarpoolaky and W. E. Lee: J. Am. Ceram. Soc., 2000, vol. 83, pp. 897-903.

    Article  Google Scholar 

  15. Jiwon PARK, Kyuyong LEE, Jong-Jin PAK and Yongsug CHUNG: ISIJ Int., 2014, vol. 54, pp. 2059-2063.

    Article  Google Scholar 

  16. P. Protsenko, O. Kozlova, R. Voytovych and N. Eustathopoulos: J Mater Sci., 2008, vol. 43, pp. 5669-5671

    Article  Google Scholar 

  17. O. Kozlova, R. Voytovych, P. Protsenko and N. Eustathopoulos: J Mater Sci., 2010, vol. 45, pp. 2099-2105

    Article  Google Scholar 

  18. N. Eustathopoulos, M. G. Nicholas, and B. Drevet: Wettability at High Temperatures, vol. 3, pp. 62-75, Pergamon Materials Series., Pergamon, Oxford, 1999.

  19. Verein Deutscher Eisenhuttenleute: SLAG ATLAS, 2 nd Ed., STAHILEISEN, Germany, 1995.

    Google Scholar 

  20. Ting Wu, Shengping He, Yijie Liang and QianWang: J. Non-Crystalline Solids., 2015, vol. 411, pp. 145–151

    Article  Google Scholar 

  21. Ja-Yong CHOI and Hae-Geon LEE: ISIJ Int., 2002, vol. 42, no. 3, pp. 221–228

    Article  Google Scholar 

  22. S. Kim, K. Lee, Y. Chung: In Proceedings of Asia Steel International Conference, ASIC, 2015, pp. 408–409.

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Acknowledgment

This work was supported by the Industrial Strategic Technology Development Program (#10044705) funded by the Ministry of Trade, Industry & Energy of Korea.

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Authors and Affiliations

  1. Department of Advanced Materials Engineering, Korea Polytechnic University, Siheung, 429-793, Korea

    Seonjin Kim (Graduate Student) & Yongsug Chung (Professor)

  2. Department of Consilience, Korea Polytechnic University, Siheung, 429-793, Korea

    Kyuyong Lee (Professor)

Authors
  1. Seonjin Kim
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  2. Kyuyong Lee
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  3. Yongsug Chung
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Corresponding author

Correspondence to Yongsug Chung.

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Manuscript submitted November 10, 2015.

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Kim, S., Lee, K. & Chung, Y. Dissolutive Wetting and Spreading Phenomena Between Al2O3 Substrate and CaO-Al2O3 Liquid Slags. Metall Mater Trans B 47, 1209–1216 (2016). https://doi.org/10.1007/s11663-016-0587-z

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