Abstract
“Overcasting” technique is used to produce bimetallic magnesium/aluminum (Mg/Al) structures where lightweight Mg can be cast onto solid Al substrates. An inherent difficulty in creating strong Mg/Al interfacial bonding is the natural oxide film on the solid Al surfaces, which reduces the wettability between molten Mg and Al substrates during the casting process. In the paper, an “electropolishing + anodizing” surface treatment has been developed to disrupt the oxide film on a dilute Al-0.08 wt pct Ga alloy, improving the metallurgical bonding between molten Mg and Al substrates in the bimetallic experiments carried out in a high-vacuum test apparatus. The test results provided valuable information of the interfacial phenomena of the Mg/Al bimetallic samples. The results show significantly improved metallurgical bonding in the bimetallic samples with “electropolishing + anodizing” surface treatment and Ga alloying. It is recommended to adjust the pre-heating temperature and time of the Al substrates and the Mg melt temperature to control the interfacial reactions for optimum interfacial properties in the actual overcasting processes.
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Notes
All composition in wt pct except otherwise stated.
References
A.I. Taub, P.E. Krajewski, A.A. Luo and J.N. Owens: JOM, 2007, vol. 59, pp. 48–57.
K.J.M. Papis, J.F. Löffler and P.J. Uggowitzer: Mater. Sci. Eng. A, 2010, vol. 5279, pp. 2274–79.
M. Hoeschl, W. Wagener, and J. Wolf: SAE Technical Paper 2006-01-0069, SAE International, Warrendale, PA, 2006.
L.M. Zhao and Z.D. Zhang: Scripta Mater., 2008, vol.58, pp. 283–6.
E. Hajjari, M. Divandari, S.H. Razavi, S.M. Emami, T. Homma and S. Kamado: Mater. Sci., 2011, vol. 46, pp. 6491–99.
A.A. Luo and A.K. Sachdev: in Proceedings of the 115th Metalcasting Congress, Paper 11-081, American Foundry Society, Schaumburg, IL, April 5–8, 2011.
Y.Q. Chen, H. Zhang, A.A. Luo, A.K. Sachdev, G. Xu and D. Chen: Mater. Sci. Eng., 2012, vol. 1, pp.1–4.
G. Xu, A.A. Luo, Y.Q. Chen and A.K. Sachdev: Mater. Sci. Eng. A, 2013, vol. 595, pp. 154–8.
A. Pakes, G.E. Thompson, P. Skeldon and P.C. Morgan: Corros. Sci., 2003, vol. 45, pp. 1275–87.
N. Margadant, P. Skeldon, M. Textor, G.E. Thompson, J. Wan, H. Habazakic, K. Shimizud, N.D. Spencer and G.C. Wood: Corros. Sci., 2000, vol. 42, pp. 405–19.
M. Textor, M. Amstutz: Anal. Chim. Acta, 1994, vol. 297, pp.15–26.
J. Tan, K. Nisancioglu: Corros. Sci., 2013, vol. 76, pp. 219–30.
J. Tan, J.C. Walmsley, B. Holme, H. Nordmark, K. Nisancioglu: Corros. Sci., 2013, vol.68, pp.204–13.
H. Habazaki, H. Konno, K. Shimizu, S. Nagata, P. Skeldon and G.E. Thompson: Corros. Sci., 2004, vol.46, pp. 2041–53.
I. Felhosi, H. Habazaki, K. Shimizu, P. Skeldon, G.E. Thompson, G.C. Wood and X. Zhou: Corros. Sci.,1988, vol.40,pp.2125–39.
Y. Ma, X. Zhou, G.E. Thompson and P. Skeldon: Corros. Sci., 2013, vol.66, pp.292–9.
M. Pinnel, J. Bennett: J. Mater. Sci., 1973, vol. 8, pp.1189–93.
J.L. Murray: in Al-Mg (Aluminum-Magnesium), Binary Alloy Phase Diagrams, vol. 1, 2nd ed., T.B. Massalski, ed., 1990, pp. 169–71.
Y. Liu, F. Colin, P. Skeldon, G.E. Thompson, X. Zhou, H. Habazaki and K. Shimizu: Corros. Sci., 2003, vol. 15, pp. 1539–44.
Y.S. Sato, A. Shiota, H. Kokawa, K. Okamoto, Q. Yang and C. Kim: Sci. Technol. Weld. Join., 2010, vol. 15, pp. 319–24.
Acknowledgments
This work was partly supported by the General Motors Global Research and Development (GM R&D), Warren, MI. The authors would like to acknowledge the encouragements and technical discussions with Dr. Anil Sachdev of GM R&D.
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Manuscript submitted April 28, 2014.
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Zhang, H., Chen, Y. & Luo, A.A. Improved Interfacial Bonding in Magnesium/Aluminum Overcasting Systems by Aluminum Surface Treatments. Metall Mater Trans B 45, 2495–2503 (2014). https://doi.org/10.1007/s11663-014-0140-x
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DOI: https://doi.org/10.1007/s11663-014-0140-x