Abstract
Zr-based bulk metallic glasses have attracted extensive interest for structural applications due to their excellent glass-forming ability, superior mechanical properties, and unique thermal and corrosion properties. In this study, Zr65Al10Ni10Cu15 amorphous composites with a large fraction of amorphous phase were in situ synthesized by laser direct deposition. X-ray diffraction confirmed the existence of both amorphous and crystalline phases. Laser parameters were optimized in order to increase the fraction of amorphous phase. The microstructure analysis by scanning electron microscopy revealed the deposited structure was composed of periodically repeated amorphous and crystalline phases. Overlapping regions with nanoparticles aggregated were crystallized by laser reheating and remelting processes during subsequent laser scans. Vickers microhardness of the amorphous region showed around 35 pct higher than that of crystalline region. Average hardness obtained by a Rockwell macrohardness tester was very close to the microhardness of the amorphous region. The compression test showed that the fracture strain of Zr65Al10Ni10Cu15 amorphous composites was enhanced from less than 2 pct to as high as 5.7 pct, compared with fully amorphous metallic glass. Differential scanning calorimetry test results further revealed the amorphous structure and glass transition temperature T g was observed to be around 660 K (387 °C). In 3 mol/L NaCl solution, laser direct deposited amorphous composites exhibited distinctly improved corrosion resistance, compared with fully crystallized samples.
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W. Klement, R. H. Willens and P. O. L. Duwez, Nature, 1960, vol. 187, pp. 869–70.
R. H. Doremus, and G. H. Sigel: Glass science, Wiley, New York, 1994.
C. A. Schuh, T. C. Hufnagel and U. Ramamurty, Acta Mater., 2007, vol. 55, pp. 4067–4109.
A. J. Drehman, A. L. Greer and D. Turnbull, Appl. Phys. Lett., 1982, vol. 41, pp. 716–17.
A. Inoue, H. S. Chen, J. T. Krause, T. Masumoto and M. Hagiwara, J. Mater. Sci., 1983, vol. 18, pp. 2743–51.
A. Inoue, K. Kita, T. Zhang and T. Masumoto, Mater. Trans. JIM, 1989, vol. 30, pp. 722–25.
A. Inoue, A. Kato, T. Zhang, S. Kim and T. Masumoto, Mater. Trans. JIM, 1991, vol. 32, pp. 609–16.
A. Peker and W. L. Johnson, Appl. Phys. Lett., 1993, vol. 63, pp. 2342–44.
A. Inoue, N. Nishiyama, K. Amiya, T. Zhang and T. Masumoto, Mater. Lett., 1994, vol. 19, pp. 131–35.
H. Kim, J. Lee, S. Shin, H. Jeong, D. Kim and J. Bae, Intermet., 2004, vol. 12, pp. 1109–13.
Y. Yoshizawa, S. Oguma and K. Yamauchi, J. Appl. Phys., 1988, vol. 64, pp. 6044-6046.
A. Inoue, T. Nakamura, T. Sugita, T. Zhang and T. Masumoto, Mater. Trans. JIM, 1993, vol. 34, pp. 351–58.
A. Inoue and A. Takeuchi, Mater. Trans. JIM, 2002, vol. 43, pp. 1892–1906.
A. Inoue, T. Masumoto, T. Ekimoto, S. Furukawa, Y. Kuroda and H. Chen, Metall. Trans. A 1988, vol. 19, pp. 235–42.
Zheng B., Lin Y., Zhou Y., Lavernia E.J. (2009) Metall. Mater. Trans. B 40:995–1004.
Y. Wu, P. Lin, G. Xie, J. Hu and M. Cao, Mater. Sci. Eng.: A, 2006, vol. 430, pp. 34–39.
B. Zheng, D. Ashford, Y. Zhou, S. N. Mathaudhu, J.-P. Delplanque and E. J. Lavernia, Acta Mater., 2013, vol. 61, pp. 4414–28.
W. Wang, Adv. Mater., 2009, vol. 21, pp. 4524–44.
M. M. Trexler and N. N. Thadhani, Prog. Mater Sci., 2010, vol. 55, pp. 759–39.
A. Gebert, J. Eckert and L. Schultz, Acta Mater., 1998, vol. 46, pp. 5475–82.
M. Miller and P. Liaw: Bulk metallic glasses. Springer, 2008.
H. Kato, Y. Kawamura and A. Inoue, Mater. Trans. JIM, 1996, vol. 37, pp. 70–77.
K. M. Flores and R. H. Dauskardt, Intermet., 2004, vol. 12, pp. 1025–29.
C. Fan, D. Qiao, T. Wilson, H. Choo and P. K. Liaw, Mater. Sci. Eng.: A, 2006, vol. 431, pp. 158–65.
H. Fu, H. Zhang, H. Wang, Q. Zhang and Z. Hu, Scr. Mater., 2005, vol. 52, pp. 669–73.
Y. Li, S. Poon, G. Shiflet, J. Xu, D. Kim and J. Löffler, MRS Bull., 2007, vol. 32, pp. 624–28.
K. M. Flores, W. L. Johnson and R. H. Dauskardt, Scr. Mater., 2003, vol. 49, pp. 1181–87.
R. Narayan, P. Singh, D. Hofmann, N. Hutchinson, K. Flores and U. Ramamurty, Acta Mater., 2012, vol. 60, pp. 5089–5100.
J. G. Wang, D. Q. Zhao, M. X. Pan and W. H. Wang, Adv. Eng. Mater., 2008, vol. 10, pp. 46–50.
D. Granata, E. Fischer, V. Wessels and J. Löffler, Acta Mater., 2014, vol. 71, pp. 145–52.
Y. Zhang, W. Wang and A. Greer, Nat. Mater., 2006, vol. 5, pp. 857–60.
H. Sun and K. M. Flores, Intermet., 2013, vol. 43, pp. 53–59.
D. Carvalho, S. Cardoso and R. Vilar, Scr. Mater., 1997, vol. 37, pp. 523–27.
F. Audebert, R. Colaco, R. Vilar and H. Sirkin, Scr. Mater., 2003, vol. 48, pp. 281–86.
Y. Wang, G. Li, C. Wang, Y. Xia, B. Sandip and C. Dong, Surf. Coat. Technol., 2004, vol. 176, pp. 284–89.
T. Yue, Y. Su and H. Yang, Mater. Lett., 2007, vol. 61, pp. 209–12.
T. Yue and Y. Su, Appl. Surf. Sci., 2008, vol. 255, pp. 1692–98.
B. Zheng, Y. Zhou, J. Smugeresky and E. Lavernia, Metall. Mater. Trans. A, 2009, vol. 40, pp. 1235–45.
H. Sun and K. Flores, Metall. Mater. Trans. A, 2010, vol. 41, pp. 1752–57.
S. Katakam, V. Kumar, S. Santhanakrishnan, R. Rajamure, P. Samimi and N. B. Dahotre, Journal of Alloys and Compounds, 2014, vol. 604, pp. 266–72.
B. Zheng, Y. Zhou, J. Smugeresky, J. Schoenung and E. Lavernia, Metall. Mater. Trans. A, 2008, vol. 39, pp. 2228–36.
B. D. Cullity, S. R. Stock. Elements of X-Ray Diffraction, third ed. Prentice Hall Upper Saddle River, New Jersey, 2001.
G. Wang, S. Fang, X. Xiao, Q. Hua, J. Gu and Y. Dong, Mater. Sci. Eng. A, 2004, vol. 373, pp. 217–220.
W. D. Liu, K. X. Liu, X. X. Xia and W.H. Wang, J. Mater. Res., 2010, vol. 25, pp. 1230–34.
G. Xie, D. V. Louzguine-Luzgin, H. Kimura and A. Inoue, Mater. Trans., 2007, vol. 48, p. 1600.
R. D. Conner, R. B. Dandliker and W. L. Johnson, Acta Mater., 1998, vol. 46, pp. 6089–6102.
Y. H. Choi, R. D. Conner, F. Szuecs and W. L. Johnson, Acta Mater., 2002, vol. 50, pp. 2737–45.
K. Okazaki, W. Zhang and A. Inoue, Mater. Trans., 2006, vol. 47, pp. 2571–75.
Y. Xue, H. Cai, L. Wang, F. Wang and H. Zhang, Appl. Phys. Lett., 2007, vol. 90, p. 1901.
M. E. Siegrist and J. F. Löffler, Scr. Mater., 2007, vol. 56, pp. 1079–82.
T. C. Hufnagel, T. Jiao, Y. Li, L. Q. Xing and K. T. Ramesh, J. Mater. Res., 2002, vol. 17, pp. 1441–45.
Suryanarayana C., Inoue A. (2011) Bulk Metallic Glasses. CRC Press, Boca Raton
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Ye, X., Bae, H., Shin, Y.C. et al. In Situ Synthesis and Characterization of Zr-Based Amorphous Composite by Laser Direct Deposition. Metall Mater Trans A 46, 4316–4325 (2015). https://doi.org/10.1007/s11661-015-3047-5
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DOI: https://doi.org/10.1007/s11661-015-3047-5