Abstract
A detailed investigation of the early stages of secondary austenite precipitation in five duplex stainless steel (DSS) commercial alloys (UNS S32304, S32205, S32550, S32750, and S32760) has been conducted using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Based on this study, a model is proposed that describes the interaction betwee Cr2N and austenite (intergranular and intragranular) precipitation in these alloys. Depending on nitrogen availability and interface mobility, Cr2N precipitation along existing ferrire/austenite interfaces precedes intergranular secondary austenite growth. The low-energy interfaces formed between the Cr2N, the ferrite, and the austenite, along with the coupled diffusion processes, are the factors controlling this phase transformation. Finally, in the case of the intragranular nitrides, a mechanism is proposed whereby the nitrides serve as sites for heterogeneous nucleation of intragranular secondary austenite.
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J. Charles: Duplex Stainless Steels ’94, Proc. Conf., TWI, Glasgow, England, 1994, paper K1.
A.J. Ramirez: Ph.D. Thesis, University of São Paulo, São Paulo, Brazil, 2001, p. 241.
S. Hertzman, P.J. Ferreira, and B. Brolund: Metall. Mater. Trans. A, 1997, vol. 28A, pp. 277–85.
H.D. Solomon and T.M. Devine: Duplex Stainless Steels ’82, Proc. Conf., ASM, Metals Park, OH, 1983, pp. 693–756.
J. Charles: Duplex Stainless Steels ’91, Proc. Conf., Les Editions de Physique, Paris, France, 1991, pp. 3–48.
D.J. Kotecki: Weld. J., 1986, vol. 65 (10), pp. 273–278s.
L. Karlsson and S. Pak: Duplex Stainless Steels ’91, Proc. Conf., Les Editions de Physique, Paris, France, 1991, pp. 413–20.
A.J. Ramirez and S.D. Brandi: XXII Nat. Meeting of Welding Technology, Proc. Conf., ABS, São Paulo, Brazil, 1996, pp. 277–87.
S.D. Brandi and A.J. Ramirez: Duplex Stainless Steels ’97, Proc. Conf., KCI, Maastricht, The Netherlands, 1997, pp. 405–10.
H. Kokawa, E. Tsory, and T.H. North: Iron Steel Inst. Jpn. Int., 1995, vol. 35, pp. 1277–83.
H.L. Cao and S. Hertzman: Duplex Stainless Steels ’91, Proc. Conf., Les Editions de Physique, Paris, France, 1991, pp. 363–72.
H. Kajimura, K. Ogawa, and H. Nagano: Iron Steel Inst. Jpn. Int., 1991, vol. 31 (2), pp. 216–22.
H. Hoffmeister and G. Lothongkum: Duplex Stainless Steels ’94, Proc. Conf., TWI, Glasgow, England, 1994, paper No. 55.
Y. Komizo, K. Ogawa, and S. Azuma: Weld. Int., 1991, vol. 5 (4), pp. 277–82.
J.O. Nilson and A. Wilson: Mater. Sci. Technol., 1993, vol. 67 (5), pp. 545–54.
L. Van-Nassau, H. Meelsker, F. Neceen, and J. Hilkes: Duplex Stainless Steels ’97, Proc. Conf., KCI, Maastricht, The netherlands, 1997, pp. 17–28.
B.J. Ginn and T.G. Gooch: TWI Document No. IX-H-444-99-IX-1946-99, TWI, Cambridge, England, 1999, p. 9.
J.C. Lippold, I. Varol, and A. Baeslack, III: Weld. J., 1994, vol. 73 (4), pp. 75s-79s.
J.O. Nilsson, L. Karlsson, and J.O. Andersson: L’Acciaio Inossidabile, 1994, vol. 1, pp. 18–22.
J.O. Nilsson, P. Jonsson, and A. Wilson: Duplex Stainless Steels ’94, Proc. Conf., TWI, Glasgow, England, 1994, paper No. 39.
S. Atamert and J. E. King: Z. Metallkd., 1991, vol. 82 (3), pp. 230–39.
S.D. Brandi, J.C. Lippold, and W. Lin: Duplex Stainless Steels ’97, Proc. Conf., KCI, Maastricht, The Netherlands, 1997, pp. 411–18.
J.C. Lippold and A.M. Al-Rumaih: Duplex Stainless Steels ’97, Proc. Conf., KCI, Maastricht, The Netherlands, 1997, pp. 1005–10.
J.M. Nicholls: Duplex Stainless Steels ’94, Proc. Conf., TWI, Glasgow, England, 1994, paper No. KIII.
A.J. Ramirez, J.C. Lippold, and S.D. Brandi: Acta Microsc., 2001, vol. 1 (11), pp. 147–48.
K.A. Bywater and D.J. Dyson: Met. Sci., 1975, vol. 9, pp. 155–62.
S. Kobayashi, K. Nakai, and Y. Ohmori: Acta Mater., 2001, vol. 49, pp. 1891–902.
W. G. Burgers: Physica, 1934, vol. 1, pp. 561–86.
Monograph 25, 21, 63 (JCPDS No. 35-0803), National Bureau of Standards, 1984.
C.P. Serna: Master’s Dissertation, University of São Paulo, São Paulo, Brazil, 2001, p. 113.
G. Kurdjumov and G. Sachs: Z. Phys., 1930, vol. 64, pp. 325–43.
Z. Nishiyama: Sci. Rep. Res. Inst. Tōhoku Univ., 1934, vol. 23, p. 638.
G. Wassermann: Arch. Eisenhüten wes., 1933, vol. 16, p. 647.
D.B. Rayaprolu and A. Hendry: Mater. Sci. Technol., 1989, vol. 5 (4), pp. 328–32.
A.P. Sutton and R.W. Balluffi: Interfaces in Crystalline Materials, Oxford University Press, Oxford United Kingdom, 1995, pp. 598–654.
K.M. Lee, H.S. Cho, and D.C. Choi: J. Alloys Compounds, 1999, vol. 285, pp. 156–61.
T. Kuroda and F. Matsuda: Trans. JWRI, 1994, vol. 11 (3), pp. 205–11.
X. Zheng: Ph.D. Dissertation, Swiss Federal Institute of Technology, Zürich, 1991.
Y.N. Petrov, V.G. Gavriljuk, H. Berns, and C. Escher: Scripta Mater., 1999, vol. 40 (6), pp. 669–74.
E.A. Brandes and G.B. Brook: Smithells Metals Reference Book, 7th ed., Butterworth-Heinemann, Londons, 1992, pp. 13.1–13.119.
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Ramirez, A.J., Lippold, J.C. & Brandi, S.D. The relationship between chromium nitride and secondary austenite precipitation in duplex stainless steels. Metall Mater Trans A 34, 1575–1597 (2003). https://doi.org/10.1007/s11661-003-0304-9
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DOI: https://doi.org/10.1007/s11661-003-0304-9