Skip to main content
Log in

Temporal and spatial variations in hydro-geochemistry of cave percolation water and their implications for four caves in Guizhou, China

  • Published:
Chinese Journal of Geochemistry Aims and scope Submit manuscript

Abstract

Soil water and cave drip water from four cave systems in Guizhou, Southwest China, were monitored and sampled monthly from April 2003 to May 2004 to understand spatio-temporal variations in hydro-geochemistry of cave percolation water. The results indicated that among the 5 drip water sites from the Liangfeng Cave (LFC), there were no significant differences among the hydro-geochemical parameters. In the Xiniu Cave (XNC), the drip rates were variable and responded quickly to precipitation events in the 3# (No. 3) drip site with variable water head; both bulk and variation in drip rates were smaller in the 2# with constant water head. However, in the Qixing Cave (QXC) and Jiangjun Cave (JJC), drip rates, concentrations of major ions and saturation index for calcite (SIC) were smaller, and Mg/Ca ratios in Group I (1#, 2#, 6#, 7# and 8# in the QXC; 2# and 3# in the JJC) were larger than those in Group II (3#, 4#, 5# and 9# in the QXC; 1# and 4# in the JJC). These differences might be the result of different hydrogeological processes above the caves, which are divided into five categories based on hydro-geochemistry data. The formation of some proxies in speleothem, such as Mg/Ca, is likely to be affected by those processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Baker A. and Bradley C. (2010) Modern stalagmite δ18O: Instrumental calibration and forward modelling [J]. Global and Planetary Change. 71, 201–206.

    Article  Google Scholar 

  • Baldini J.U.L., McDermott F., and Fairchild I.J. (2006) Spatial variability in cave drip water hydrochemistry: Implications for stalagmite paleoclimate records [J]. Chemical Geology. 235, 390–404.

    Article  Google Scholar 

  • Bradley C., Baker A., Jex C.N. et al. (2010) Hydrological uncertainties in the modelling of cave drip-water δ18O and the implications for stalagmite palaeoclimate reconstructions [J]. Quaternary Science Reviews. 29, 2201–2214.

    Article  Google Scholar 

  • Bureau of Geology and Mineral Resources of Guizhou Province of China (1987) Regional Geology of Guizhou Province [R]. Geological Publishing House, Beijing (in Chinese).

    Google Scholar 

  • Dreybrodt W. (1988) Processes in Karst Systems, Physics, Chemistry, and Geology [M]. New York, NY (USA), Springer-Verlag.

    Google Scholar 

  • Dykoski C.A., Edwards R.L., Cheng H. et al. (2005) A high-resolution, absolute-dated Holocene and deglacial Asian monsoon record from Dongge Cave, China [J]. Earth and Planetary Science Letters. 233, 71–86.

    Article  Google Scholar 

  • Fairchild I.J., Borsato A., Tooth A.F. et al. (2000) Controls on trace element (Sr-Mg) compositions of carbonate cave waters: Implications for speleothem climatic records [J]. Chemical Geology. 166, 255–269.

    Article  Google Scholar 

  • Fairchild I.J. and Treble P.C. (2009) Trace elements in speleothems as recorders of environmental change [J]. Quaternary Science Reviews. 28, 449–468.

    Article  Google Scholar 

  • Fairchild I.J., Tuckwell G.W., Baker A. et al. (2006) Modelling of dripwater hydrology and hydrogeochemistry in a weakly karstified aquifer (Bath, UK): Implications for climate change studies [J]. Journal of Hydrology. 321, 213–231.

    Article  Google Scholar 

  • Ford D.C. and Williams, P. (2007) Karst Hydrogeology and Geomorphology [M]. New York, John Wiley and Sons.

    Google Scholar 

  • Gascoyne M. (1983) Trace-element partition coefficients in the calcite-water system and their paleoclimatic significance in cave studies [J]. Journal of Hydrology. 61, 213–222.

    Article  Google Scholar 

  • He Yaoqi, Wang Yongjin, Kong Xinggong et al. (2005) High resolution stalagmite δ18O records over the past 1000 years from Dongge Cave in Guizhou [J]. Chinese Science Bulletin. 50, 1003–1008.

    Article  Google Scholar 

  • Huang Y. and Fairchild I.J. (2001) Partitioning of Sr2+ and Mg2+ into calcite under karst-analogue experimental conditions [J]. Geochimica et Cosmochimica Acta. 65, 47–62.

    Article  Google Scholar 

  • Karmann I., Cruz Jr F.W., Viana Jr O. et al. (2007) Climate influence on geochemistry parameters of waters from Santana-Perolas cave system, Brazil [J]. Chemical Geology. 244, 232–247.

    Article  Google Scholar 

  • Kelly M.J., Edwards R.L., Cheng H. et al. (2006) High resolution characterization of the Asian Monsoon between 146000 and 99000 years B.P. from Dongge Cave, China and global correlation of events surrounding Termination II [J]. Palaeogeography, Palaeoclimatology, Palaeoecology. 236, 20–38.

    Article  Google Scholar 

  • Lambert W.J. and Aharon P. (2010) Oxygen and hydrogen isotopes of rainfall and dripwater at DeSoto Caverns (Alabama, USA): Key to understanding past variability of moisture transport from the Gulf of Mexico [J]. Geochimica et Cosmochimica Acta. 74, 846–861.

    Article  Google Scholar 

  • Lambert W.J. and Aharon P. (2011) Controls on dissolved inorganic carbon and δ13C in cave waters from DeSoto Caverns: Implications for speleothem δ13C assessments [J]. Geochimica et Cosmochimica Acta. 75, 753–768.

    Article  Google Scholar 

  • Linge H., Lauritzen S.E., Lundberg J. et al. (2001) Stable isotope stratigraphy of Holocene speleothems: Examples from a cave system in Rana, northern Norway [J]. Palaeogeography, Palaeoclimatology, Palaeoecology. 167, 209–224.

    Article  Google Scholar 

  • McDonald J. and Drysdale R. (2007) Hydrology of cave drip waters at varying bedrock depths from a karst system in southeastern Australia [J]. Hydrological Processes. 21, 1737–1748.

    Article  Google Scholar 

  • McDonald J., Drysdale R., Hill D. et al. (2007) The hydrochemical response of cave drip waters to sub-annual and inter-annual climate variability, Wombeyan Caves, SE Australia [J]. Chemical Geology. 244, 605–623.

    Article  Google Scholar 

  • Serefiddin F., Schwarcz H.P., Ford D.C. et al. (2004) Late Pleistocene paleoclimate in the Black Hills of South Dakota from isotope records in speleothems [J]. Palaeogeography, Palaeoclimatology, Palaeoecology. 203, 1–17.

    Article  Google Scholar 

  • Spötl C., Fairchild I.J., and Tooth A.F. (2005) Cave air control on dripwater geochemistry, Obir Caves (Austria): Implications for speleothem deposition in dynamically ventilated caves [J]. Geochimica et Cosmochimica Acta. 69, 2451–2468.

    Article  Google Scholar 

  • Tooth A.F. and Fairchild I.J. (2003) Soil and karst aquifer hydrological controls on the geochemical evolution of speleothem-forming drip waters, Crag Cave, Southwest Ireland [J]. Journal of Hydrology. 273, 51–68.

    Article  Google Scholar 

  • Wang Y., Cheng H., Edwards R.L. et al. (2005) The Holocene Asian Monsoon: Links to solar changes and North Atlantic climate [J]. Science. 308, 854–857.

    Article  Google Scholar 

  • Wang Zhaorong, Peng Zicheng, Ni Shoubin et al. (1999) Progress in spelean stalagmite paleoclimatology and chronology [J]. Chinese Journal of Geochemistry. 18, 25–29.

    Article  Google Scholar 

  • Wang Zhaorong, Yuan Daoxian, Lin Yushi et al. (2001) High-resolution dating of stalagmites and reconstruction of paleo-environments [J]. Chinese Journal of Geochemistry. 20, 282–288.

    Article  Google Scholar 

  • Xie Xingneng, Wang Shijie, Zhou Yunchao et al. (2008) Three-dimensional fluorescence spectral characteristics of dissolved organic carbon in cave drip waters and their responses to environment changes: Four cave systems as an example in Guizhou Province, China [J]. Chinese Science Bulletin. 53, 884–889.

    Article  Google Scholar 

  • Yuan D., Cheng H., Edwards R.L. et al. (2004) Timing, Duration, and Transitions of the Last Interglacial Asian Monsoon [J]. Science. 304, 575–578.

    Article  Google Scholar 

  • Zhou Yunchao, Wang Shijie, Xie Xingneng et al. (2005) Significance and dynamics of drip water responding to rainfall in four caves of Guizhou, China [J]. Chinese Science Bulletin. 50, 154–161.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shijie Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Luo, W., Wang, S., Xie, X. et al. Temporal and spatial variations in hydro-geochemistry of cave percolation water and their implications for four caves in Guizhou, China. Chin. J. Geochem. 32, 119–129 (2013). https://doi.org/10.1007/s11631-013-0614-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11631-013-0614-6

Key words

Navigation