Abstract
LiV1-xMnxOPO4 (0 ≤ x ≤ 0.2) cathode materials have been first synthesized by substituting V4+ in β-LiVOPO4 with Mn4+ ion using a common solid-state method. Effects of Mn doping on the structures, morphology, and electrochemical properties of β-LiVOPO4 were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS), and various electrochemical methods such as galvanostatic charge–discharge tests, cyclic voltammograms (CV), and electrochemistry impedance spectroscopy (EIS) as well. Of the compositions investigated, the LiV0.96Mn0.04OPO4 materials present the best electrochemical characteristics with the first discharge capacity of 150.0 and 148.7 mAh/g kept after 30 cycles at 0.2 C, while the value for β-LiVOPO4 is only 135.5 and 123.6 mAh/g, respectively. It is clearly demonstrated that the improvement in electrochemical properties of β-LiVOPO4 may be a result from the reduced charge transfer resistance, the increased lithium-ion diffusion, and phase conversion due to Mn doping.
Similar content being viewed by others
References
Padhi AK, Nanjundaswamy KS, Goodenough JB (1997) J Electrochem Soc 144(4):1188–1194
Saravanan K, Lee HS, Kuezma M, Vittal JJ, Balaya P (2011) J Mater Chem 21(27):10042–10050
Harrison KL, Bridges CA, Segre CU, Varnado JRCD, Applestone D, Bielawski CW, Paranthaman M, Manthiram A (2014) Chem Mater 26(12):3849–3861
Chen Z, Chen Q, Chen L, Zhang R, Zhou H, Chernova NA, Whittingham MS (2013) J Electrochem Soc 160(10):A1777–A1780
Bianchini M, Ateba-Mba JM, Dagault P, Bogdan E, Carlier D, Suard E, Masquelier C, Croguennec L (2014) J Mater Chem A 2(26):10182–10192
Barker J, Saidi MY, Swoye JL (2004) J Electrochem Soc 151(6):A796–A800
Shahul-Hameed A, Nagarathinam M, Reddy MV, Chowdarib VR, VittaL JJ (2012) J Mater Chem 22(15):7206–7213
Tang A, Shen J, Hu Y, Xu G, He D, Yi Q, Peng R (2014) J Electrochem Soc 161(1):A10–A13
Lii KH, Li CH, Cheng CY, Wang SL (1991) J Solid State Chem 95:352–359
Nagamine K, Honma T, Komatsu T (2008) J Am Ceram Soc 91(12):3920–3925
Bustam MA, Man Z, Maitra S, Ishihara T (2013) Trans Indian Ceramic Soc 72(2):108–112
Azmi BM, Ishihara T, Nishiguchi H, Takita YJ (2005) J Power Sources 146(1-2):525–528
He ZQ, Zhang LL, Xiong LZ, Tang AP, Chen S, Wu XM, Liu JB, Huang KL (2008) Chinese J Inorganic Chem 24(2):303–306 (in Chinese)
Yang Y, Fang H, Zheng J, Li L, Li G, Yan G (2008) Solid State Sci 10(10):1292–1298
Chen Z, Chen Q, Chen L (2014) Chinese J Nonferrous Metals 24(5):1306–1310 (in Chinese)
Ling C, Zhang Rand Mizuno F (2014) J Mater Chemistry A 2:12330–12339
Bustam MA, Ishihara T, Takita HY (2005) Ionics 11(5-6):402–405
Ramos-barrado JR, Criado C, Rodriguez-castellon E, Olivera-pasto RP, Jimenez-lopez A (1997) Solid State Ionics 97(1-4):213–216
Harrison KL, Manthiram A (2013) Chem Mater 25(9):1751–1760
Xiong LZ, He ZQ (2010) Acta Phys -Chim Sin 26(3):573–577
Ren MM, Zhou Z, Su LW, Gao XP (2009) J Power Sources 189(1):786–789
Huang H, Yin SC, Nazar LF (2001) Electrochem Solid-State Lett 4(10):A170–172
Yamada A, Kudo Y, Liu KY (2001) J Electrochem Soc 148(7):A747–754
He ZQ, Liang K, Xiong LZ (2011) Materials Rev 25(4):61–64 (in Chinese)
Luo S, Tian Y, Li H, Shi K, Tang Z, Zhang Z (2010) J Rare Earths 28(3):439–442
Wang M, Cheng YB, Wu F, Su YF, Chen L, Wang DL (2010) Electrochim Acta 55(28):8815–8820
Sun H, Chen Y, Xu C, Zhu D, Huang LJ (2012) J Solid State Electrochem 16(3):1247–1254
Li N, An R, Su Y, Wu F, Bao L, Chen L, Zheng Y, Shou H, Chen S (2013) J Mater Chemistry A 1(34):9760–9767
Yang Z, Jiang Y, Kim JH, Wu Y, Li G, Huang Y (2014) Electrochim Acta 117:76–83
Wang L, Yang L, Gong L, Jiang X, Yuan K, Hu Z (2011) Electrochim Acta 56(20):6906–6911
Idota Y, Kubota T, Matsufuji A, Maekawa Y, Miyasaka T (1997) Science 276(5317):1395–1397
Badway F, Plitz I, Grugeon S, Laruelle S, Dolle M, Gozdz AS, Tarascon JM (2002) Electrochem Solid-State Lett 5(6):A115–A118
Silversmit G, Depla D, Poelman H, Marin GB, De Gryse R (2004) J Electron Spectrosc Relat Phenom 135(2-3):167–175
Zhu Y, Weimin L, Li H, Wan H (2007) J Catal 46(2):382–389
Chung SY, Bloking JT, Chiang YM (2002) Nat Mater 1(2):123–128
Wang CW, Ma XL, Cheng JG, Zhou LQ, Sun JT, Zhou YH (2006) Solid State Ionics 177(11-12):1027–1031
Chen CH, Liu J, Amine K (2001) J Power Sources 96(2):321–328
Levi MD, Gamolsky K, Aurbach D, Heider U, Oesten R (2000) Electrochim Acta 45(11):1781–1789
Chen GY, Wilcox JD, Richardson TJ (2008) Electrochem Solid-State Lett 11:A190
Wang DY, Ouyang CY, Drezen T, Exnar I, Kay A, Kwon NH, Gouerec P, Miners JH, Wang MK, Gratzel M (2010) J Electrochem Soc 157:A225
Wang YR, Chen YF, Cheng SQ, He LN (2011) Korean J Chem Eng 28:964
Shiratsuchi T, Okada S, Doi T, Yamaki JI (2009) Electrochim Acta 54:3145
Bakenov Z, Taniguchi I (2010) J Electrochem Soc 157:A430
Wu F, Wang L, Wu C, Bai Y (2009) Electrochim Acta 54(20):4613–4619
Bard AJ, Faulkner LR (2001) Electrochemical Methods. Fundamentals and Applications, 2nd edn. Wiley, New York
Acknowledgments
This work was supported by the National Natural Science Foundation of China (51262008, 51202087, 51364009, 51472107), Natural Science Foundation of Hunan Province, China (12JJ2005, 14JJ4048), the Research Foundation of Education Bureau of Hunan Province, China (13 K094), the Planned Science and Technology Project of Hunan Province, China (2012GK2017), the Construct Program of the Key Discipline in Hunan Province, China (JSU0713), and the Aid Program for Science and Technology Innovative Research Team in Higher Education Institutions of Hunan Province ([2014]207).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Xiong, L., Wang, Y., Wu, Y. et al. Enhanced electrochemical performance of manganese-doped β-LiVOPO4 cathode materials for lithium-ion batteries. Ionics 21, 2471–2476 (2015). https://doi.org/10.1007/s11581-015-1436-9
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11581-015-1436-9