Abstract
Novel mixed matrix polyvinylchloride-based electrodialysis heterogeneous cation-exchange membranes were prepared by casting technique. Ilmenite (FeTiO3) was employed as additive in membrane fabrication. The effect of additive concentration on electrochemical properties of membranes was studied. Water content was decreased slightly by increase of FeTiO3 concentration. Ion-exchange capacity was improved initially by increase in additive content to 16 wt.% and then showed decreasing trend by more additive loading. Membrane potential, transport number and selectivity were enhanced initially in NaCl solution by increase of FeTiO3 content up to 16 wt.% and then decreased by more additive loading. Increment of FeTiO3 concentration led to decrease of selectivity and transport number in BaCl2 solution. Permeability and flux were declined slightly by increase in additive content up to 8 wt.% and then began to increase sharply by more additive content from 8 to 16 wt.%. Permeability and flux were decreased again by more additive concentration from 16 to 32 wt.%. Electrodialysis experiment results in laboratory scale showed higher dialytic rate for modified membrane compared to pristine one. Membrane areal electrical resistance was declined by increase of additive concentration. Membranes exhibited higher selectivity and flux for monovalent ions compared to bivalent ones.
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Nagarale RK, Gohil GS, Shahi VK, Trivedi GS, Rangarajan R (2004) Preparation and electrochemical characterization of cation- and anion-exchange/polyaniline composite membranes. J Colloid Interface Sci 277:162–171
Kariduraganavar MY, Nagarale RK, Kittur AA, Kulkarni SS (2006) Ion-exchange membranes: preparative methods for electro-dialysis and fuel cell application. Desalination 197:225–246
Nagarale RK, Gohil GS, Shahi VK (2006) Recent developments on ion-exchange membranes and electro-membrane processes. Adv Colloid Interf Sci 119:97–130
Gohil GS, Binsu VV, Shahi VK (2006) Preparation and characterization of mono-valent ion selective polypyrrole composite ion-exchange membranes. J Membr Sci 280:210–218
Shahi VK, Thampy SK, Rangarajan R (1999) Studies on transport properties of surfactant immobilized anion-exchange membrane. J Membr Sci 158:77–83
Vyas PV, Ray P, Adhikary SK, Shah BG, Rangarajan R (2003) Studies of the effect of variation of blend ratio on permselectivity and heterogeneity of ion-exchange membranes. J Colloid Interface Sci 257:127–134
Volodina E, Pismenskaya N, Nikonenko V, Larchet C, Pourcelly G (2005) Ion transfer across ion-exchange membranes with homogeneous and heterogeneous surfaces. J Colloid Interface Sci 285:247–258
Nagarale RK, Shahi VK, Schubert R, Rangarajan R, Mehnert R (2004) Development of urethane acrylate composite ion-exchange membranes and their electrochemical characterization. J Colloid Interface Sci 270:446–454
Hwang GJ, Ohya H, Nagai T (1999) Ion exchange membrane based on block copolymers. Part III: preparation of cation exchange membrane. J Membr Sci 156:61–65
M' Bareck CO, Nguyen QT, Alexandre S, Zimmerlin I (2006) Fabrication of ion-exchange ultrafiltration membranes for water treatment I. Semi-interpenetrating polymer networks of polysulfone and poly (acrylic acid). J Membr Sci 278:10–18
Xu T (2005) Ion exchange membrane: state of their development and perspective. J Membr Sci 263:1–29
Elattar A, Elmidaoui A, Pismenskaia N, Gavach C, Pourcelly G (1998) Comparison of transport properties of monovalent anions through anion-exchange membranes. J Membr Sci 143:249–261
Schauer J, Brozova L (2005) Heterogeneous ion-exchange membranes based on sulfonated poly (1, 4-phenylene sulfide) and linear polyethylene: preparation, oxidation stability, methanol permeability and electrochemical properties. J Membr Sci 250:151–157
Koter S, Warszawski A (2000) Electro-membrane processes in environment protection. Pol J Environ Stud 9(1):45–56
Baker RW (2004) Membrane technology and applications, 2nd edn. John Wiley & Sons Ltd, England
Shahi VK, Trivedi GS, Thampy SK, Rangarajan R (2003) Studies on the electrochemical and permeation characteristic of asymmetric charged porous membranes. J Colloid Interface Sci 262:566–573
Gohil GS, Shahi VK, Rangarajan R (2004) Comparative studies on electrochemical characterization of homogeneous and heterogeneous type of ion-exchange membranes. J Membr Sci 240:211–219
Dlugolecki P, Anet B, Metz SJ, Nijmeijer K, Wessling M (2010) Transport limitations in ion exchange membranes at low salt concentrations. J Membr Sci 346:163–171
Kerres J, Cui W, Disson R, Neubrand W (1998) Development and characterization of crosslinked ionomer membranes based upon sulfinated and sulfonated PSU Crosslinked PSU blend membranes by disproportionation of sulfinic acid groups. J Membr Sci 139:211–225
Li X, Wang Z, Lu H, Zhao C, Na H, Zhao C (2005) Electrochemical properties of sulfonated PEEK used for ion exchange membranes. J Membr Sci 254:147–155
Hosseini SM, Madaeni SS, Heidari AR, Amirimehr A (2012) Preparation and characterization of ion-selective polyvinyl chloride based heterogeneous cation exchange membrane modified by magnetic iron-nickel oxide nanoparticles. Desalination 284:191–199
Balster J, Krupenko O, Punt I, Stamatialis DF, Wessling M (2005) Preparation and characterisation of monovalent ion selective cation exchange membranes based on sulphonated poly (ether ether keton). J Membr Sci 263:137–145
Hosseini SM, Madaeni SS, Khodabakhshi AR (2010) Preparation and characterization of ABS/HIPS heterogeneous cation exchange membranes with various blend ratios of polymer binder. J Membr Sci 351:178–188
Sata T (2004) Ion exchange membranes: preparation, characterization, modification and application. The Royal Society of Chemistry, Cambridge, United Kingdom
Hosseini SM, Madaeni SS, Khodabakhshi AR (2010) Preparation and characterization of ABS/HIPS heterogeneous anion exchange membrane filled with activated carbon. J Appl Polym Sci 118:3371–3383
Hosseini SM, Madaeni SS, Zendehnam A, Moghadassi AR, Khodabakhshi AR, Sanaeepur H (2013) Preparation and characterization of PVC based heterogeneous ion exchange membrane coated with Ag nanoparticles by (thermal-plasma) treatment assisted surface modification. J Ind Eng Chem 19:854–862
Sata T, Yang W (2002) Studies on cation-exchange membranes having permselectivity between cations in electro dialysis. J Membr Sci 206:31–60
Hosseini SM, Madaeni SS, Khodabakhshi AR (2010) Preparation and characterization of PC/SBR heterogeneous cation exchange membrane filled with carbon nano-tubes. J Membr Sci 362:550–559
Nagarale RK, Gohil GS, Shahi VK, Rangarajan R (2004) Preparation and electrochemical characterization of cation-exchange membranes with different functional groups. Colloid Surf A 251:133–140
P. Daraei, S. S. Madaeni, N. Ghaemi, E. Salehi, M. Khadivi, R. Moradian, B. Astinchap, Novel polyethersulfone nanocomposite membrane prepared by PANI/Fe3O4 nanoparticles with enhanced performance for Cu(II) removal from water, Journal of Membrane Science, Article in press, Corrected proof, Available online 18 May 2012
Ghaee A, Shariaty-Niassar M, Barzin J, Matsuura T (2010) Effects of chitosan membrane morphology on copper ion adsorption. Chem Eng J 165:46–55
Boricha AG, Murthy ZVP (2009) Acrylonitrile butadiene styrene/chitosan blend membranes: preparation, characterization and performance for the separation of heavy metals. J Membr Sci 339:239–249
Liu C, Bai R (2006) Adsorptive removal of copper ions with highly porous chitosan/ cellulose acetate blend hollow fiber membranes. J Membr Sci 284:313–322
Ng LY, Mohammad AW, Leo CP, Hilal N (2013) Polymeric membranes incorporated with metal/metal oxide nanoparticles: a comprehensive review. Desalination 308:15–33
Xu P, Zeng GM, Huang DL, Feng CL, Hu S, Zhao MH, Lai C, Wei Z, Huang C, Xie GX, Liu ZF (2012) Use of iron oxide nanomaterials in wastewater treatment: a review. Sci Total Environ 424:1–10
Wiks ES (2001) Industrial polymers handbook: products, processes, application. WILEY-VCH press, Germany
James E (1999) MARK, polymer data handbook. Oxford University Press, Inc., New York
Harper CA (1975) Handbook of plastic and elastomers. McGraw-Hill, New York
Fujii T, Yamashita M, Fujimori S, Saitoh Y, Nakamura T, Kobayashi K, Takada J (2007) Large magnetic polarization of Ti4+ ions in FeTiO3. J Magn Magn Mater 310:e555–e557
Raghavender AT, Hong NH, Lee KJ, Jung MH, Skoko Z, Vasilevskiy M, Cerqueira MF, Samantilleke AP (2013) Nano-ilmenite FeTiO3: synthesis and characterization. J Magn Magn Mater 331:129–132
Powell CE, Qiao GG (2006) Polymeric CO2/N2 gas separation membranes for the capture of carbon dioxide from power plant flue gases. J Membr Sci 279:1–49
Tanaka Y (2007) Ion exchange membranes: fundamentals and applications, membrane science and technology series, 12. Elsevier, Netherlands
Nagarale RK, Shahi VK, Thampy SK, Rangarajan R (2004) Studies on electrochemical characterization of polycarbonate and polysulfone based heterogeneous cation-exchange membranes. React Funct Polym 61:131–138
Nagarale RK, Shahi VK, Rangarajan R (2005) Preparation of polyvinyl alcohol-silica hybrid heterogeneous anion-exchange membranes by sol–gel method and their characterization. J Membr Sci 248:37–44
D.R. Lide, CRC Handbook of Chemistry and Physics, CRC press, 87th edition, 2006–2007
Długolecki P, Nymeijer K, Metz S, Wessling M (2008) Current status of ion exchange membranes for power generation from salinity gradients. J Membr Sci 319:214–222
Hosseini SM, Madaeni SS, Khodabakhshi AR (2010) Heterogeneous cation exchange membrane: preparation, characterization and comparison of transport properties of mono and bivalent cations. Sep Sci Technol 45:2308–2321
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The authors gratefully acknowledge Arak University for the financial support during this research.
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Hosseini, S.M., Hamidi, A.R., Moghadassi, A.R. et al. Fabrication of novel mixed matrix electrodialysis heterogeneous ion-exchange membranes modified by ilmenite (FeTiO3): electrochemical and ionic transport characteristics. Ionics 21, 437–447 (2015). https://doi.org/10.1007/s11581-014-1186-0
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DOI: https://doi.org/10.1007/s11581-014-1186-0