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Polyvinylpyrrolidone/graphene oxide thin films coated on quartz crystal microbalance electrode for NH3 detection at room temperature

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Abstract

In this paper, composite film based on polyvinylpyrrolidone (PVP)/graphene oxide (GO) was fabricated by spray method on AT-cut 9.986 MHz quartz crystal microbalance (QCM) for NH3 sensing. The thin films were characterized by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR) and ultraviolet-visible spectroscopy (UV-VIS) to investigate the morphologies and the composition contents, respectively. The experimental results reveal that PVP/GO based sensor holds higher sensitivity, larger responsiveness and smaller baseline drift than those based on pure PVP at room temperature. Besides, the prepared sensor exhibits greater response to NH3 than other gases such as CO, CO2 and NO2 at the same concentration. The good linearity, reproducibility and stability demonstrate the practicability of PVP/GO hybrid film in detecting NH3.

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References

  1. Yoo K P, Kwon K H, Min N K, et al. Effects of O2, plasma treatment on NH3, sensing characteristics of multiwall carbon nanotube/polyaniline composite films. Sensor Actuat B-Chem, 2009, 143: 333–340

    Article  Google Scholar 

  2. Shao F, Fan J D, Hernández-Ramírez F, et al. NH3 sensing with self-assembled ZnO-nanowire µHP sensors in isothermal and temperature- pulsed mode. Sensor Actuat B-Chem, 2016, 226: 110–117

    Article  Google Scholar 

  3. Chen T Y, Chen H I, Hsu C S, et al. Characteristics of ZnO nanorods- based ammonia gas sensors with a cross-linked configuration. Sensor Actuat B-Chem, 2015, 221: 491–498

    Article  Google Scholar 

  4. Xu S, Kan K, Yang Y, et al. Enhanced NH3, gas sensing performance based on electrospun alkaline-earth metals composited SnO2, nanofibers. J Alloys Compd, 2015, 618: 240–247

    Article  Google Scholar 

  5. Shahabuddin M, Sharma A, Kumar J, et al. Metal clusters activated SnO2 thin film for low level detection of NH3 gas. Sensor Actuat B-Chem, 2014, 194: 410–418

    Article  Google Scholar 

  6. Wang L, Pfeifer J, Balázsi C, et al. Synthesis and sensing properties to NH3 of hexagonal WO3 metastable nanopowders. Mater Manuf Process, 2007, 22: 773–776

    Article  Google Scholar 

  7. Nguyen D D, Dang D V, Nguyen D C. Hydrothermal synthesis and NH3 gas sensing property of WO3 nanorods at low temperature. Adv Nat Sci Nanosci Nanotechnol, 2015, 6: 035006

    Article  Google Scholar 

  8. Ji X, Banks C E, Compton R G. The electrochemical oxidation of ammonia at boron-doped diamond electrodes exhibits analytically useful signals in aqueous solutions. Analyst, 2005, 130: 1345–1347

    Article  Google Scholar 

  9. Connolly E J, Timmer B, Pham H T M, et al. A porous SiC ammonia sensor. Sensor Actuat B-Chem, 2005, 109: 44–46

    Article  Google Scholar 

  10. Tai H, Xu X, Ye Z, et al. P-P heterojunction sensor of self-assembled polyaniline nano-thin film/microstructure silicon array for NH3 detection. Cheml Phys Lett, 2015, 621: 58–64

    Article  Google Scholar 

  11. Abdulla S, Mathew T L, Pullithadathil B. Highly sensitive, room temperature gas sensor based on polyaniline-multiwalled carbon nanotubes (PANI/MWCNTs) nanocomposite for trace-level ammonia detection. Sensor Actuat B-Chem, 2015, 221: 1523–1534

    Article  Google Scholar 

  12. Tiwari D C, Atri P, Sharma R. Sensitive detection of ammonia by reduced graphene oxide/polypyrrole nanocomposites. Synthetic Met, 2015, 203: 228–234

    Article  Google Scholar 

  13. Konkayan S, Chanthaanont P, Prissanaroon W, et al. Ammonia sensing and electrical properties based on composite of poly (3-thiopheneacetic acid) and zeolite Y. Mater Technol, 2013, 28: 332–338

    Article  Google Scholar 

  14. Tai H, Jiang Y, Xie G, et al. Preparation, characterization and comparative NH3-sensing characteristic studies of PANI/inorganic oxides nanocomposite thin films. J Mater Sci Technol, 2010, 26: 605–613

    Article  Google Scholar 

  15. Li L, He S, Liu M, et al. Three-dimensional mesoporous graphene aerogel-supported SnO2 nanocrystals for high-performance NO2 gas sensing at low temperature. Anal Chem, 2015, 87: 1638–45

    Article  Google Scholar 

  16. Li L, Liu M, He S, et al. Freestanding 3D mesoporous CO3O4@carbon foam nanostructures for ethanol gas sensing. Anal Chem, 2014, 86: 7996–8002

    Article  Google Scholar 

  17. Chen Y, Xie G, Xie T, et al. Thin film transistors based on poly (3-hexylthiophene)/[6,6]-phenyl C61 butyric acid methyl ester hetero-junction for ammonia detection. Chem Phys Lett, 2015, 638: 87–93

    Article  Google Scholar 

  18. Basu S, Bhattacharyya P. Recent developments on graphene and graphene oxide based solid state gas sensors. Sensor Actuat B-Chem, 2012, 173: 1–21

    Article  Google Scholar 

  19. Zhang R, Chen W. Fe3C-functionalized 3D nitrogen-doped carbon structures for electrochemical detection of hydrogen peroxide. Sci Bull, 2015, 60: 522–531

    Article  Google Scholar 

  20. Zhang R, Sun C L, Lu Y J, et al. Graphene nanoribbon-supported PtPd concave nanocubes for electrochemical detection of TNT with high sensitivity and selectivity. Anal Chem, 2015, 87: 12262–12269

    Article  Google Scholar 

  21. Varghese S S, Lonkar S, Singh K K, et al. Recent advances in graphene based gas sensors. Sensor Actuat B-Chem, 2015, 218: 160–183

    Article  Google Scholar 

  22. Hu R, Zhang K, Fan G, et al. Development of a high-sensitivity plasticizer sensor based on a quartz crystal microbalance modified with a nanostructured nickel hydroxide film. Meas Sci Technol, 2015, 26, doi: 10.1088/0957-0233/26/5/055102

    Google Scholar 

  23. Pejcic B, Crooke E, Doherty C M, et al. The impact of water and hydrocarbon concentration on the sensitivity of a polymer-based quartz crystal microbalance sensor for organic compounds. Anal Chim Acta, 2011, 703: 70–79

    Article  Google Scholar 

  24. Pejcic B, Crooke E, Boyd L, et al. Using plasticizers to control the hydrocarbon selectivity of a poly (methyl methacrylate)-coated quartz crystal microbalance sensor. Anal Chem, 2012, 84: 8564–8570

    Article  Google Scholar 

  25. Mirmohseni A, Oladegaragoze A. Construction of a sensor for determination of ammonia and aliphatic amines using polyvinylpyrrolidone coated quartz crystal microbalance. Sensor Actuat B-Chem, 2003, 89: 164–172

    Article  Google Scholar 

  26. Choi J, Lee J, Choi J, et al. Electrospun PEDOT: PSS/PVP nanofibers as the chemiresistor in chemical vapour sensing. Synthetic Met, 2010, 160: 1415–1421

    Article  Google Scholar 

  27. Tang H, Yan M, Ma X, et al. Gas sensing behavior of polyvinylpyrrolidone- modified ZnO nanoparticles for trimethylamine. Sensor Actuat B-Chem, 2006, 113: 324–328

    Article  Google Scholar 

  28. He X, Arsat R, Sadek A Z, et al. Electrospun PVP fibers and gas sensing properties of PVP/36 YX LiTaO3 SAW device. Sensor Actuat B-Chem, 2010, 145: 674–679

    Article  Google Scholar 

  29. Wu M, Xie G Z, Zhou Y, et al. A PVP-based quartz crystal microbalance sensor for H2S detection. Appl Mech Mater, 2014, 651: 191–194

    Article  Google Scholar 

  30. Xie G Z, Kang T, Zhou Y, et al. QCM sensors based on PEI films for CO2 detection. J Electron Sci Technol, 2015, 2: 181–187

    Google Scholar 

  31. Borodko Y, Habas S E, Koebel M, et al. Probing the interaction of poly(vinylpyrrolidone) with platinum nanocrystals by UV-Raman and FTIR. J Phys Chem B, 2006, 110: 23052–9

    Article  Google Scholar 

  32. Huang J, Zhou Y, Xie T. Polyvinylpyrrolidone/reduced graphene oxide nanocomposites thin films coated on quartz crystal microbalance for NO2 detection at room temperature. In: Proceedings of the 2014 International Symposium on Advanced Optical Manufacturing and Testing Technologies. Harbin: SPIE, 2014. 92850B-92850B-6

    Google Scholar 

  33. Li X, Chen X, Yao Y, et al. High-stability quartz crystal microbalance ammonia sensor utilizing graphene oxide isolation layer. Sensor Actuat B-Chem, 2014, 196: 183–188

    Article  Google Scholar 

  34. Ling W, Ran Y, Huan W, et al. High-selective and sensitive voltammetric sensor for butylated hydroxyanisole based on AuNPs-PVPgraphene nanocomposites. Talanta, 2015, 138: 169–175

    Article  Google Scholar 

  35. Ballantine D S, Rose S L, Grate J W, et al. Correlation of surface acoustic wave device coating responses with solubility properties and chemical structure using pattern recognition. Anal Chem, 1986, 58: 3058–3066

    Article  Google Scholar 

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Correspondence to GuangZhong Xie or YuanJie Su.

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Ma, X., Xie, G., Su, Y. et al. Polyvinylpyrrolidone/graphene oxide thin films coated on quartz crystal microbalance electrode for NH3 detection at room temperature. Sci. China Technol. Sci. 59, 1377–1382 (2016). https://doi.org/10.1007/s11431-016-0281-7

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  • DOI: https://doi.org/10.1007/s11431-016-0281-7

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