Abstract
Inorganic fouling on the membrane surface is one of the major prevalent issues affecting the performance and cost of reverse osmosis system. Chemical dosage is a widely adopted method for the inhibition of inorganic scale on the membrane surface. In this study, CO2 was used to control inorganic scale formation on surface of reverse osmosis (RO) membrane in wastewater reclamation. The pH of influent could be lowered by purging CO2. It caused an increase in solubility of inorganic salts in water resulting in discharge of principle ions in concentrate stream. A pilot plant study was conducted with four different RO modules including control, with dosage of antiscalant, with purging CO2 and with co-addition of antiscalant and CO2. The effectiveness of CO2 purging was assessed on the basis of operational analysis, in-line analysis and morphological results. Ryznar stability index was used to determine the scaling potential of system. The examined data indicated that CO2 purging was successful to inhibit scale formation on the membrane surface. Moreover, CO2 was found more eco-friendly than antiscalant, as no by-products were generated in concentrate stream.
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References
Al-Amoudi A, Lovitt RW (2007) Fouling strategies and the cleaning system of NF membranes and factors affecting cleaning efficiency. J Memb Sci 303:4–28. doi:10.1016/j.memsci.2007.06.002
Andritsos N, Karabelas AJ, Koutsoukos PG (1997) Morphology and structure of CaCO3 scale layers formed under isothermal flow conditions. Langmuir 7463:2873–2879
Antony A, Low JH, Gray S et al (2011) Scale formation and control in high pressure membrane water treatment systems: a review. J Memb Sci 383:1–16. doi:10.1016/j.memsci.2011.08.054
APHA/AWWA/WEF (2012) Standard Methods for the Examination of Water and Wastewater.
Bartels CR, Wilf M, Andes K, Iong J (2005) Design considerations for wastewater treatment by reverse osmosis. Water Sci Technol 51:473–482
Filloux E, Wang J, Pidou M et al (2015) Biofouling and scaling control of reverse osmosis membrane using one-step cleaning-potential of acidified nitrite solution as an agent. J Memb Sci 495:276–283. doi:10.1016/j.memsci.2015.08.034
Fritzmann C, Löwenberg J, Wintgens T, Melin T (2007) State-of-the-art of reverse osmosis desalination. Desalination 216:1–76. doi:10.1016/j.desal.2006.12.009
Ghaffour N, Missimer TM, Amy GL (2013) Technical review and evaluation of the economics of water desalination: current and future challenges for better water supply sustainability. Desalination 309:197–207. doi:10.1016/j.desal.2012.10.015
Greenberg G, Hasson D, Semiat R (2005) Limits of RO recovery imposed by calcium phosphate precipitation. Desalination 183:273–288. doi:10.1016/j.desal.2005.04.026
Greenlee LF, Lawler DF, Freeman BD et al (2009) Reverse osmosis desalination: water sources, technology, and today’s challenges. Water Res 43:2317–2348. doi:10.1016/j.watres.2009.03.010
Greenlee LF, Testa F, Lawler DF et al (2010) The effect of antiscalant addition on calcium carbonate precipitation for a simplified synthetic brackish water reverse osmosis concentrate. Water Res 44:2957–2969. doi:10.1016/j.watres.2010.02.024
Harris J (2012) Handbook basics of reverse osmosis. Puretec, California
Hart PW, Colson GW, Burris J (2011) Application of carbon dioxide to reduce water-side lime scale in heat exchangers. J Sci Technol For Prod Process 1:67–70
Hoek EMV, Kim AS, Elimelech M (2002) Influence of crossflow membrane filter geometry and shear rate on colloidal fouling in reverse osmosis and nanofiltration separations. Environ Eng Sci 19:357–372. doi:10.1089/109287502320963364
Holloway RW, Miller-Robbie L, Patel M et al (2016) Life-cycle assessment of two potable water reuse technologies: MF/RO/UV-AOP treatment and hybrid osmotic membrane bioreactors. J Memb Sci 507:165–178. doi:10.1016/j.memsci.2016.01.045
Joss A, Baenninger C, Foa P et al (2011) Water reuse: >90% water yield in MBR/RO through concentrate recycling and CO2 addition as scaling control. Water Res 45:6141–6151. doi:10.1016/j.watres.2011.09.011
Kitamura M (2001) Crystallization and transformation mechanism of calcium carbonate polymorphs and the effect of magnesium ion. J Colloid Interface Sci 236:318–327. doi:10.1006/jcis.2000.7398
Kucera J (2014) Desalination: water from water.
Lee S, Cho J, Elimelech M (2004) Influence of colloidal fouling and feed water recovery on salt rejection of RO and NF membranes. Desalination 160:1–12. doi:10.1016/S0011-9164(04)90013-6
Lee S, Kim J, Lee CH (1999) Analysis of CaSO4 scale formation mechanism in various nanofiltration modules. J Memb Sci 163:63–74. doi:10.1016/S0376-7388(99)00156-8
Ma W, Zhao Y, Wang L (2007) The pretreatment with enhanced coagulation and a UF membrane for seawater desalination with reverse osmosis. Desalination 203:256–259. doi:10.1016/j.desal.2006.02.020
Miller DJ, Kasemset S, Paul DR, Freeman BD (2014) Comparison of membrane fouling at constant flux and constant transmembrane pressure conditions. J Memb Sci 454:505–515. doi:10.1016/j.memsci.2013.12.027
Miller FA, Wilkins CH (1952) Infrared spectra and characteristic frequencies of inorganic ions. Anal Chem 24:1253–1294. doi:10.1021/ac60068a007
Montgomery MA, Elimelech M (2007) Water and sanitation in developing countries: including health in the equation. Environ Sci Technol 41:17–24. doi:10.1021/es072435t
Ngene IS, Lammertink RGH, Kemperman AJB et al (2010) CO2 nucleation in membrane spacer channels remove biofilms and fouling deposits. Ind Eng Chem Res 49:10034–10039. doi:10.1021/ie1011245
Okazaki M, KIMURA S (1984) Scale formation on reverse-osmosis membranes. J Chem Eng JAPAN 17:145–151. doi:10.1252/jcej.17.145
Partlan E (2013) Dissolved carbon dioxide for scale removal in reverse osmosis. Clemson University
Pervov AG (1991) Scale formation prognosis and cleaning procedure schedules in reverse osmosis systems operation. Desalination 83:77–118. doi:10.1016/0011-9164(91)85087-B
Pontié M, Rapenne S, Thekkedath A et al (2005) Tools for membrane autopsies and antifouling strategies in seawater feeds: a review. Desalination 181:75–90. doi:10.1016/j.desal.2005.01.013
Prihasto N, Liu QF, Kim SH (2009) Pre-treatment strategies for seawater desalination by reverse osmosis system. Desalination 249:308–316. doi:10.1016/j.desal.2008.09.010
Pype ML, Lawrence MG, Keller J, Gernjak W (2016) Reverse osmosis integrity monitoring in water reuse: the challenge to verify virus removal—a review. Water Res 98:384–395. doi:10.1016/j.watres.2016.04.040
Raffin M, Germain E, Judd S (2012) Assessment of fouling of an RO process dedicated to indirect potable reuse. Desalin Water Treat 40:302–308. doi:10.1080/19443994.2012.671171
Reig FB, Adelantado JVG, Moya Moreno MCM (2002) FTIR quantitative analysis of calcium carbonate (calcite) and silica (quartz) mixtures using the constant ratio method. Application to geological samples Talanta 58:811–821. doi:10.1016/S0039-9140(02)00372-7
Seidel A, Waypa JJ, Elimelech M (2001) Role of charge (Donnan) exclusion in removal of arsenic from water by a negatively charged porous nanofiltration membrane. Environ Eng Sci 18:105–113. doi:10.1089/10928750151132311
Shih WY, Rahardianto A, Lee RW, Cohen Y (2005) Morphometric characterization of calcium sulfate dihydrate (gypsum) scale on reverse osmosis membranes. J Memb Sci 252:253–263. doi:10.1016/j.memsci.2004.12.023
Shirazi S, Lin CJ, Chen D (2010) Inorganic fouling of pressure-driven membrane processes—a critical review. Desalination 250:236–248. doi:10.1016/j.desal.2009.02.056
Tang F, Hu HY, Sun LJ et al (2016) Fouling characteristics of reverse osmosis membranes at different positions of a full-scale plant for municipal wastewater reclamation. Water Res 90:329–336. doi:10.1016/j.watres.2015.12.028
Tharamapalan J, Duranceau SJ (2014) Canary in a membrane plant: a sentinel against membrane scaling. J Am Water Works Assoc 106:67–75. doi:10.5942/jawwa.2014.106.0004
Tzotzi C, Pahiadaki T, Yiantsios SG et al (2007) A study of CaCO3 scale formation and inhibition in RO and NF membrane processes. J Memb Sci 296:171–184. doi:10.1016/j.memsci.2007.03.031
Yao CL, Qi CX, Zhu JM, Xu WH (2010) Unusual morphology of calcium carbonate controlled by amino acids in agarose gel. J Chil Chem Soc 55:270–273. doi:10.4067/S0717-97072010000200028
Zach-Maor A, Semiat R, Rahardianto A et al (2008) Diagnostic analysis of RO desalting treated wastewater. Desalination 230:239–247. doi:10.1016/j.desal.2007.11.028
Zeiher EHK, Ho B, Williams KD (2003) Novel antiscalant dosing control. Desalination 157:209–216. doi:10.1016/S0011-9164(03)00400-4
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This research was supported by 2015 Joint Lab supporting Program of Ministry of Trade, Industry and Energy (MOTIE), Korea (Project no. N0001672).
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Shahid, M.K., Pyo, M. & Choi, YG. Inorganic fouling control in reverse osmosis wastewater reclamation by purging carbon dioxide. Environ Sci Pollut Res 26, 1094–1102 (2019). https://doi.org/10.1007/s11356-017-9008-3
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DOI: https://doi.org/10.1007/s11356-017-9008-3