Abstract
In this study, a new surface pre-treatment technique has been developed to improve the durability of the ultra-thin tetrahedral amorphous carbon (ta-C) coating for magnetic tape drive read/write heads. In this technique, prior to the deposition of an 8-nm ta-C overcoat, a 2-nm thin TiN interlayer was deposited on the heads surface and bombarded with energetic Ar+ and C+ ions. X-ray photo-electron spectroscopy results revealed that this surface pre-treatment technique would lead to the formation of an atomically mixed (AlTi)N x C y interlayer which can chemically bond the interlayer to the overcoat and substrate. The effect of this atomically mixed interlayer on the wear resistance of the ta-C coating was investigated using ball-on-flat tests as well as a functional tape drive tester. According to the ball-on-flat test results, the application of the (AlTi)N x C y interlayer was able to improve the wear life of the ta-C overcoat by up to 3.3 times as compared to that of the conventional ta-C coating. The results of the wear tests in a real head/tape interface were in agreement with the ball-on-flat results, and showed that while the conventional ta-C film was completely removed from the head surface, the ta-C film with (AlTi)N x C y was able to protect the head surface for wear tests of about 1.6 million meters.
Similar content being viewed by others
References
Dee, R.H.: Magnetic tape for data storage: an enduring technology. Proc. IEEE 96(11), 1775–1785 (2008)
Information Storage Industry Consortium (INSIC), International Magnetic Tape Storage Roadmap, Broomfield, Colorado (2011)
Robertson, J.: Amorphous carbon. Adv. Phys. 35(4), 317–374 (1986)
Robertson, J.: Properties of diamond-like carbon. Surf. Coat. Technol. 50(3), 185–203 (1992)
Rismani, E., et al.: Effect of pre-treatment of the substrate surface by energetic C+ ion bombardment on structure and nano-tribological characteristics of ultra-thin tetrahedral amorphous carbon (ta-C) protective coatings. J. Phys. D Appl. Phys. 44(11), 115502 (2011)
Rismani, E., Sinha, S.K., Yang, H., Bhatia, C.S.: Effect of pretreatment of Si interlayer by energetic C+ ions on the improved nanotribological properties of magnetic head overcoat. J. Appl. Phys. 111(8), 084902–084910 (2012)
Rismani, E., Sinha, S.K., Yang, H., Tripathy, S., Bhatia, C.S.: Development of a ta-C wear resistant coating with composite interlayer for recording heads of magnetic tape drives. Tribol. Lett. 46(3), 221–232 (2012)
Avelar-Batista, J.C., Spain, E., Fuentes, G.G., Sola, A., Rodriguez, R., Housden, J.: Triode plasma nitriding and PVD coating: a successful pre-treatment combination to improve the wear resistance of DLC coatings on Ti6Al4V alloy. Surf. Coat. Technol. 201(7), 4335–4340 (2006)
Anders, A.: Cathodic arcs: from fractal spots to energetic condensation. Springer Science, New York (2008)
Anders, S., Anders, A., Brown, I.G., Wei, B., Komvopoulos, K., Ager, J.W., Yu, K.M.: Effect of vacuum arc deposition parameters on the properties of amorphous carbon thin films. Surf. Coat. Technol. 68–69, 388–393 (1994)
Logothetidis, S., Meletis, E.I., Stergioudis, G., Adjaottor, A.A.: Room temperature oxidation behavior of TiN thin films. Thin Solid Films 338(1–2), 304–313 (1999)
Pharr, G.M., et al.: Hardness, elastic modulus, and structure of very hard carbon films produced by cathodic-arc deposition with substrate pulse biasing. Appl. Phys. Lett. 68(6), 779–781 (1996)
Robertson, J.: Requirements of ultrathin carbon coatings for magnetic storage technology. Tribol. Int. 36(4–6), 405–415 (2003)
Ziegler, J.F., Biersack, J.P., Liimark, V.: The Stopping and Range of Ions in Solids. Pergamon, New York (1985)
Wan, D., Komvopoulos, K.: Effect of low-pressure plasma discharge conditions on the thickness and roughness of ultrathin films of amorphous carbon. J. Appl. Phys. 100(6), 063307-7 (2006)
Hassan, M., Rawat, R.S., Lee, P., Hassan, S.M., Qayyum, A., Ahmad, R., Murtaza, G., Zakaullah, M.: Synthesis of nanocrystalline multiphase titanium oxycarbide TiC x O y thin films by UNU/ICTP and NX2 plasma focus devices. Appl. Phys. A Mater. Sci. Process. 90(4), 669–677 (2008)
Phase, D.M., Vasant, S.: In situ photoelectron spectroscopy study of TiCxNy films synthesized through reactive ion beam mixing. J. Phys. D Appl. Phys. 37(12), 1696 (2004)
Bertoncello, R., Casagrande, A., Casarin, M., Glisenti, A., Lanzoni, E., Mirenghi, L., Tondello, E.: Tin, Tic and Ti(C, N) film characterization and its relationship to tribological behaviour. Surf. Interface Anal. 18(7), 525–531 (1992)
Schüler, A., Oelhafen, P.: Titanium aluminum nitride (Ti–Al–N) films were deposited by reactive magnetron cosputtering. Phys. Rev. B 63(11), 115413 (2001)
Strydom, I., Hofmann, S.: The contribution of characteristic energy losses in the core-level X-ray photoelectron spectroscopy peaks of TiN and (Ti, Al)N studied by electron energy loss spectroscopy and X-ray photoelectron spectroscopy. J. Electron Spectrosc. Relat. Phenom. 56(2), 85–103 (1991)
Bhushan, B.: Chemical, mechanical and tribological characterization of ultra-thin and hard amorphous carbon coatings as thin as 3.5 nm: recent developments. Diam. Relat. Mater. 8(11), 1985–2015 (1999)
Scott, W.W., Bhushan, B., Lakshmikumaran, A.V.: Ultrathin diamond-like carbon coatings used for reduction of pole tip recession in magnetic tape heads. J. Appl. Phys. 87(9), 6182–6184 (2000)
Robertson, J.: Diamond-like amorphous carbon. Mater. Sci. Eng. R Rep. 37(4–6), 129–281 (2002)
Komvopoulos, K.: Finite element analysis of a layered elastic solid in normal contact with a rigid surface. J. Tribol. 110(3), 477–485 (1988)
Komvopoulos, K.: Elastic-plastic finite element analysis of indented layered media. J. Tribol. 111(3), 430–439 (1989)
Kral, E.R., Komvopoulos, K.: Three-dimensional finite element analysis of surface deformation and stresses in an elastic-plastic layered medium subjected to indentation and sliding contact loading. J. Appl. Mech. 63(2), 365–375 (1996)
Kral, E.R., Komvopoulos, K.: Three-dimensional finite element analysis of subsurface stresses and shakedown due to repeated sliding on a layered medium. J. Appl. Mech. 63(4), 967–973 (1996)
Acknowledgments
This research was partly funded by the Information Storage Industry Consortium (INSIC) TAPE Program and the Singapore NRF under CRP Award No. NRF-CRP 4-2008-6. The authors thank Dr. Robert Raymond of Oracle America Inc. for providing the heads and Mr. Douglas Johnson of Imation Corp. for providing the SDS tape transport system.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rismani, E., Yeo, R., Sinha, S.K. et al. Developing an (Al,Ti)N x C y Interlayer to Improve the Durability of the ta-C Coating on Magnetic Recording Heads. Tribol Lett 50, 233–243 (2013). https://doi.org/10.1007/s11249-013-0115-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11249-013-0115-0