Skip to main content
Log in

Developing an (Al,Ti)N x C y Interlayer to Improve the Durability of the ta-C Coating on Magnetic Recording Heads

  • Original Paper
  • Published:
Tribology Letters Aims and scope Submit manuscript

Abstract

In this study, a new surface pre-treatment technique has been developed to improve the durability of the ultra-thin tetrahedral amorphous carbon (ta-C) coating for magnetic tape drive read/write heads. In this technique, prior to the deposition of an 8-nm ta-C overcoat, a 2-nm thin TiN interlayer was deposited on the heads surface and bombarded with energetic Ar+ and C+ ions. X-ray photo-electron spectroscopy results revealed that this surface pre-treatment technique would lead to the formation of an atomically mixed (AlTi)N x C y interlayer which can chemically bond the interlayer to the overcoat and substrate. The effect of this atomically mixed interlayer on the wear resistance of the ta-C coating was investigated using ball-on-flat tests as well as a functional tape drive tester. According to the ball-on-flat test results, the application of the (AlTi)N x C y interlayer was able to improve the wear life of the ta-C overcoat by up to 3.3 times as compared to that of the conventional ta-C coating. The results of the wear tests in a real head/tape interface were in agreement with the ball-on-flat results, and showed that while the conventional ta-C film was completely removed from the head surface, the ta-C film with (AlTi)N x C y was able to protect the head surface for wear tests of about 1.6 million meters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Dee, R.H.: Magnetic tape for data storage: an enduring technology. Proc. IEEE 96(11), 1775–1785 (2008)

    Article  CAS  Google Scholar 

  2. Information Storage Industry Consortium (INSIC), International Magnetic Tape Storage Roadmap, Broomfield, Colorado (2011)

  3. Robertson, J.: Amorphous carbon. Adv. Phys. 35(4), 317–374 (1986)

    Article  CAS  Google Scholar 

  4. Robertson, J.: Properties of diamond-like carbon. Surf. Coat. Technol. 50(3), 185–203 (1992)

    Article  CAS  Google Scholar 

  5. Rismani, E., et al.: Effect of pre-treatment of the substrate surface by energetic C+ ion bombardment on structure and nano-tribological characteristics of ultra-thin tetrahedral amorphous carbon (ta-C) protective coatings. J. Phys. D Appl. Phys. 44(11), 115502 (2011)

    Article  Google Scholar 

  6. Rismani, E., Sinha, S.K., Yang, H., Bhatia, C.S.: Effect of pretreatment of Si interlayer by energetic C+ ions on the improved nanotribological properties of magnetic head overcoat. J. Appl. Phys. 111(8), 084902–084910 (2012)

    Article  Google Scholar 

  7. Rismani, E., Sinha, S.K., Yang, H., Tripathy, S., Bhatia, C.S.: Development of a ta-C wear resistant coating with composite interlayer for recording heads of magnetic tape drives. Tribol. Lett. 46(3), 221–232 (2012)

    Article  CAS  Google Scholar 

  8. Avelar-Batista, J.C., Spain, E., Fuentes, G.G., Sola, A., Rodriguez, R., Housden, J.: Triode plasma nitriding and PVD coating: a successful pre-treatment combination to improve the wear resistance of DLC coatings on Ti6Al4V alloy. Surf. Coat. Technol. 201(7), 4335–4340 (2006)

    Article  CAS  Google Scholar 

  9. Anders, A.: Cathodic arcs: from fractal spots to energetic condensation. Springer Science, New York (2008)

    Google Scholar 

  10. Anders, S., Anders, A., Brown, I.G., Wei, B., Komvopoulos, K., Ager, J.W., Yu, K.M.: Effect of vacuum arc deposition parameters on the properties of amorphous carbon thin films. Surf. Coat. Technol. 68–69, 388–393 (1994)

    Article  Google Scholar 

  11. Logothetidis, S., Meletis, E.I., Stergioudis, G., Adjaottor, A.A.: Room temperature oxidation behavior of TiN thin films. Thin Solid Films 338(1–2), 304–313 (1999)

    Article  CAS  Google Scholar 

  12. Pharr, G.M., et al.: Hardness, elastic modulus, and structure of very hard carbon films produced by cathodic-arc deposition with substrate pulse biasing. Appl. Phys. Lett. 68(6), 779–781 (1996)

    Article  CAS  Google Scholar 

  13. Robertson, J.: Requirements of ultrathin carbon coatings for magnetic storage technology. Tribol. Int. 36(4–6), 405–415 (2003)

    Article  CAS  Google Scholar 

  14. Ziegler, J.F., Biersack, J.P., Liimark, V.: The Stopping and Range of Ions in Solids. Pergamon, New York (1985)

  15. Wan, D., Komvopoulos, K.: Effect of low-pressure plasma discharge conditions on the thickness and roughness of ultrathin films of amorphous carbon. J. Appl. Phys. 100(6), 063307-7 (2006)

    Google Scholar 

  16. Hassan, M., Rawat, R.S., Lee, P., Hassan, S.M., Qayyum, A., Ahmad, R., Murtaza, G., Zakaullah, M.: Synthesis of nanocrystalline multiphase titanium oxycarbide TiC x O y thin films by UNU/ICTP and NX2 plasma focus devices. Appl. Phys. A Mater. Sci. Process. 90(4), 669–677 (2008)

    Article  CAS  Google Scholar 

  17. Phase, D.M., Vasant, S.: In situ photoelectron spectroscopy study of TiCxNy films synthesized through reactive ion beam mixing. J. Phys. D Appl. Phys. 37(12), 1696 (2004)

    Article  CAS  Google Scholar 

  18. Bertoncello, R., Casagrande, A., Casarin, M., Glisenti, A., Lanzoni, E., Mirenghi, L., Tondello, E.: Tin, Tic and Ti(C, N) film characterization and its relationship to tribological behaviour. Surf. Interface Anal. 18(7), 525–531 (1992)

    Article  CAS  Google Scholar 

  19. Schüler, A., Oelhafen, P.: Titanium aluminum nitride (Ti–Al–N) films were deposited by reactive magnetron cosputtering. Phys. Rev. B 63(11), 115413 (2001)

    Article  Google Scholar 

  20. Strydom, I., Hofmann, S.: The contribution of characteristic energy losses in the core-level X-ray photoelectron spectroscopy peaks of TiN and (Ti, Al)N studied by electron energy loss spectroscopy and X-ray photoelectron spectroscopy. J. Electron Spectrosc. Relat. Phenom. 56(2), 85–103 (1991)

    Article  CAS  Google Scholar 

  21. Bhushan, B.: Chemical, mechanical and tribological characterization of ultra-thin and hard amorphous carbon coatings as thin as 3.5 nm: recent developments. Diam. Relat. Mater. 8(11), 1985–2015 (1999)

    Article  CAS  Google Scholar 

  22. Scott, W.W., Bhushan, B., Lakshmikumaran, A.V.: Ultrathin diamond-like carbon coatings used for reduction of pole tip recession in magnetic tape heads. J. Appl. Phys. 87(9), 6182–6184 (2000)

    Article  CAS  Google Scholar 

  23. Robertson, J.: Diamond-like amorphous carbon. Mater. Sci. Eng. R Rep. 37(4–6), 129–281 (2002)

    Article  Google Scholar 

  24. Komvopoulos, K.: Finite element analysis of a layered elastic solid in normal contact with a rigid surface. J. Tribol. 110(3), 477–485 (1988)

    Article  Google Scholar 

  25. Komvopoulos, K.: Elastic-plastic finite element analysis of indented layered media. J. Tribol. 111(3), 430–439 (1989)

    Article  Google Scholar 

  26. Kral, E.R., Komvopoulos, K.: Three-dimensional finite element analysis of surface deformation and stresses in an elastic-plastic layered medium subjected to indentation and sliding contact loading. J. Appl. Mech. 63(2), 365–375 (1996)

    Article  Google Scholar 

  27. Kral, E.R., Komvopoulos, K.: Three-dimensional finite element analysis of subsurface stresses and shakedown due to repeated sliding on a layered medium. J. Appl. Mech. 63(4), 967–973 (1996)

    Article  Google Scholar 

Download references

Acknowledgments

This research was partly funded by the Information Storage Industry Consortium (INSIC) TAPE Program and the Singapore NRF under CRP Award No. NRF-CRP 4-2008-6. The authors thank Dr. Robert Raymond of Oracle America Inc. for providing the heads and Mr. Douglas Johnson of Imation Corp. for providing the SDS tape transport system.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Charanjit S. Bhatia.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rismani, E., Yeo, R., Sinha, S.K. et al. Developing an (Al,Ti)N x C y Interlayer to Improve the Durability of the ta-C Coating on Magnetic Recording Heads. Tribol Lett 50, 233–243 (2013). https://doi.org/10.1007/s11249-013-0115-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11249-013-0115-0

Keywords

Navigation