Skip to main content
Log in

Wear Behavior of (TiB2–TiC)–Ni/TiAl/Ti Gradient Materials Prepared by the FAPAS Process

  • Original Paper
  • Published:
Tribology Letters Aims and scope Submit manuscript

Abstract

(TiB2–TiC)–Ni/TiAl/Ti functionally gradient materials were prepared by field-activated pressure-assisted synthesis processes. (TiB2–TiC)–Ni composite ceramic, the top layer of the functional gradient materials, was prepared in situ by the combustion synthesis process using Ti and B4C powders as raw materials. Scanning electron microscope (SEM) images of the ceramic layer revealed that the TiB2 and TiC particles in the composite were fine and homogeneously dispersed in the Ni matrix. The friction and wear properties of the (TiB2–TiC)–Ni ceramic were evaluated by sliding against a GCr15 disk at temperatures from ambient up to 400 °C. The experimental results showed that the friction coefficient of the (TiB2–TiC)–Ni ceramic decreased with the increasing testing temperature, load, and sliding speed. However, the loss rate decreased at higher temperature and increased at higher load and higher sliding speed. The wear mechanisms of (TiB2–TiC)–Ni ceramic mainly depend upon thermal oxidation at higher temperature, load, and sliding speed. The worn topography and phase component of the worn surfaces were analyzed using SEM, energy dispersive spectroscopy, and X-ray diffraction. The oxide films of Fe2O3, TiO2, and B2O3 formed during the friction process play an important role in lubrication, which results in a smaller friction coefficient.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. Rebelo de Figueiredo, M., Muratore, C., Franz, R., Chromik, R.R., Wahl, K.J., Voevodin, A.A., O’Sullivan, M., Lechthaler, M., Mitterer, C.: In situ studies of TiC11−x N x hard coating tribology. Tribol. Lett. 40, 365–373 (2010)

    Article  CAS  Google Scholar 

  2. Shaha, K.P., Pei, Y.T., Martinez-Martinez, D., De Hosson, J.Th.M.: Influence of surface roughness on the transfer film formation and frictional behavior of TiC/a–C nanocomposite coatings. Tribol. Lett. 41, 97–101 (2011)

    Article  CAS  Google Scholar 

  3. Du, B., Wang, X., Zou, Z.: Microstructure and tribological behavior of laser in situ synthesized TiC-reinforced Fe-based composite coatings. Tribol. Lett. 43, 295–301 (2011)

    Article  CAS  Google Scholar 

  4. Kumar, S., Chakraborty, M., Subramanya Sarma, V., Murty, B.S.: Tensile and wear behaviour of in situ Al–7Si/TiB2 particulate composites. Wear 265, 134–142 (2008)

    Article  CAS  Google Scholar 

  5. Kumar, S., Subramanya Sarma, V., Murty, B.S.: High temperature wear behavior of Al–4Cu–TiB2 in situ composites. Wear 268, 1266–1274 (2010)

    Article  CAS  Google Scholar 

  6. Wang, X.H., Zhang, M., Du, B.S.: Fabrication in situ TiB2–TiC–Al2O3 multiple ceramic particles reinforced Fe-based composite coatings by gas tungsten arc welding. Tribol. Lett. 41, 171–176 (2011)

    Article  CAS  Google Scholar 

  7. Akhtar, F.: Microstructure evolution and wear properties of in situ synthesized TiB and TiC reinforced steel matrix composites. J. Alloys Compd. 459, 491–497 (2008)

    Article  CAS  Google Scholar 

  8. Zhang, X., Yang, J., Ma, J., Hao, J., Bi, Q., Liang, Y., Liu, W.: The tribological behaviour of Fe–28Al–5Cr/TiC under liquid paraffine lubrication. Tribol. Lett. 45, 109–116 (2012)

    Article  CAS  Google Scholar 

  9. Sun, G.J., Wu, S.J., Su, G.C.: Research on impact wear resistance of in situ reaction TiCp/Fe composite. Wear 269, 285–290 (2010)

    Article  CAS  Google Scholar 

  10. Vallauri, D., Atias Adrian, I.C., Chrysanthou, A.: TiC–TiB2 composites: a review of phase relationships, processing and properties. J. Eur. Ceram. Soc. 28, 1697–1713 (2008)

    Article  CAS  Google Scholar 

  11. Zou, B., Shen, P., Gao, Z., Jiang, Q.: Combustion synthesis of TiC x –TiB2 composites with hypoeutectic, eutectic and hypereutectic microstructures. J. Eur. Ceram. Soc. 28, 2275–2279 (2008)

    Article  CAS  Google Scholar 

  12. Zhao, H., Cheng, Y.B.: Formation of TiB2–TiC composites by reactive sintering. Ceram. Int. 25, 353–358 (1999)

    Article  CAS  Google Scholar 

  13. Zhao, Z., Zhang, L., Song, Y., Wang, W., Liu, H.: Microstructures and properties of large bulk solidified TiC–TiB2 composites prepared by combustion synthesis under high gravity. Scripta Mater. 61, 281–284 (2009)

    Article  CAS  Google Scholar 

  14. Wang, Z.T., Zhou, X.H., Zhao, G.G.: Microstructure and formation mechanism of in situ TiC–TiB2/Fe composite coating. Trans. Nonferr. Met. Soc. China 18, 831–835 (2008)

    Article  CAS  Google Scholar 

  15. Li, B., Liu, Y., Li, J., Cao, H., He, L.: Effect of sintering process on the microstructures and properties of in situ TiB2–TiC reinforced steel matrix composites produced by spark plasma sintering. J. Mater. Process. Technol. 210, 91–95 (2010)

    Article  CAS  Google Scholar 

  16. Xu, C.L., Wang, H.Y., Yang, Y.F., Jiang, Q.C.: Effect of Al–P–Ti–TiC–Nd2O3 modifier on the micro-structure and mechanical properties of hypereutectic Al-20 wt% Si alloy. Mater. Sci. Eng. A 452, 341–346 (2007)

    Article  Google Scholar 

  17. Chen, S.P., Meng, Q.S., Zhao, J.F., Munir, Z.A.: Synthesis and characterization of TiB2–Ni–Ni3Al–CrNi alloy graded material by field-activated combustion. J. Alloys Compd. 476, 889–893 (2009)

    Article  CAS  Google Scholar 

  18. Chen, S.P., Meng, Q.S., Liu, W., Munir, Z.A.: Titanium diboride–nickel graded materials prepared by field-activated, pressure-assisted synthesis process. J. Mater. Sci. 44, 1121–1126 (2009)

    Article  CAS  Google Scholar 

  19. He, L., Zhang, X., Tong, C.: Surface modification of pure titanium treated with B4C at high temperature. Surf. Coat. Technol. 200, 3016–3020 (2006)

    Article  CAS  Google Scholar 

  20. Oh, D.Y., Kim, H.C., Yoon, J.K., Shon, I.J.: Simultaneous synthesis and consolidation process of ultra-fine WSi2–SiC and its mechanical properties. J. Alloys Compd. 386, 270–275 (2005)

    Article  CAS  Google Scholar 

  21. Yang, Z.L., Ouyang, J.H., Liu, Z.G., Liang, X.S.: Wear mechanisms of TiN–TiB2 ceramic in sliding against alumina from room temperature to 700 °C. Ceram. Int. 36, 2129–2135 (2010)

    Article  CAS  Google Scholar 

  22. Jianxin, D., Wenlong, S., Hui, Z., Pei, Y., Aihua, L.: Friction and wear behaviors of the carbide tools embedded with solid lubricants in sliding wear tests and in dry cutting processes. Wear 270, 666–674 (2011)

    Article  Google Scholar 

  23. Li, Y., Zou, Z., Feng, T., Wang, X.: Oxidation resistance and phase constituents in the brazing interface of WC–TiC–Co hard alloys. J. Mater. Process. Technol. 122, 51–55 (2002)

    Article  CAS  Google Scholar 

  24. Liu, N., Xu, Y.D., Li, H., Chen, M.H., Zhou, J., Xie, F., Yang, H.D.: Cutting and wearing characteristics of TiC-based cermets cutters with nano-TiN addition. J. Mater. Process. Technol. 161, 478–484 (2005)

    Article  CAS  Google Scholar 

  25. Jianxin, D., Hui, Z., Ze, W., Yunsong, L., Youqiang, X., Shipeng, L.: Unlubricated friction and wear behaviors of Al2O3/TiC ceramic cutting tool materials from high temperature tribological tests. Int. J. Refract. Met. Hard Mater. 35, 17–26 (2012)

    Article  Google Scholar 

  26. Jerome, S., Ravisankar, B., Mahato, P.K., Natarajan, S.: Synthesis and evaluation of mechanical and high temperature tribological properties of in situ Al–TiC composites. Tribol. Int. 43, 2029–2036 (2010)

    Article  CAS  Google Scholar 

  27. Guo, C., Zhou, J., Zhao, J., Wang, L., Youjun, Y., Chen, J., Zhou, H.: Microstructure and tribological properties of a HfB2-containing Ni-based composite coating produced on a pure Ti substrate by laser cladding. Tribol. Lett. 44, 187–200 (2011)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This study was supported by projects of the National Science Foundation of China (No. 50975190), Shanxi Province Science Foundation for Youth and Young Scientists Fund of the National Natural Science Foundation of China (51101111).

Conflict of interest

None.

Ethical Standards

The study has been performed in accordance with the ethical standards laid down in the 1964 Declaration of Helsinki. All the authors agree to submit the paper to Tribology Letters.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Qingsen Meng.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hu, L., Chen, S., Xue, P. et al. Wear Behavior of (TiB2–TiC)–Ni/TiAl/Ti Gradient Materials Prepared by the FAPAS Process. Tribol Lett 49, 313–322 (2013). https://doi.org/10.1007/s11249-012-0070-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11249-012-0070-1

Keywords

Navigation