Skip to main content
SpringerLink
Log in

Role of Lattice Oxygen in the Propane Combustion Over Pt/Yttria-Stabilized Zirconia : Isotopic Studies

  • Original Paper
  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Abstract

Nanoparticles of platinum were dispersed on an oxygen ionically conducting support, Yttria-Stabilized Zirconia (YSZ), on non-doped zirconia and on silica. The role of the support oxygen lattice in the mechanism of propane deep oxidation was investigated by using 18O2 Temperature-Programmed Desorption, catalytic activity measurements using isotopic oxygen, and isotopic exchange experiments. The results emphasize that the propane combustion mechanism on Pt/YSZ presents a different pathway compared with that involved on Pt/SiO2 and Pt/ZrO2 because, propane is preferentially oxidized by lattice YSZ oxygen species on Pt/YSZ. Strong Pt nanoparticles/YSZ interactions generate a promoted state similar to that observed on polarizations during electrochemical promotion of catalysis.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Vernoux P, Lizarraga L, Tsampas MN, Sapountzi FM, De Lucas-Consuegra A, Valverde JL, Souentie S, Vayenas CG, Tsiplakides D, Balomenou S, Baranova EA (2013) Chem Rev 113:8192–8260

    Article  CAS  Google Scholar 

  2. Vayenas CG, Bebelis S, Pliangos C, Brosda S, Tsiplakides D (2001) Electrochemical activation of catalysis: promotion: electrochemical promotion and metal-support interaction. Plenum Publishers, New York

    Google Scholar 

  3. Tsampas MN, Sapountzi FM, Boreave A, Vernoux P (2013) Electrochem Commun 26:13–16

    Article  CAS  Google Scholar 

  4. Fortunato MA, Aubert D, Capdeillayre C, Daniel C, Hadjar A, Princivalle A, Guizard C, Vernoux P (2011) Appl Catal A 403:18–24

    Article  CAS  Google Scholar 

  5. Katsaounis A, Nikopoulou Z, Verykios XE, Vayenas CG (2004) J Catal 222:192–196

    Article  CAS  Google Scholar 

  6. Vernoux P, Guth M, Li X (2009) Electrochem Solid State Lett 12:E9–E11

    Article  CAS  Google Scholar 

  7. Hwang CP, Yeh CT (1996) J Mol Catal A 112:295–302

    Article  CAS  Google Scholar 

  8. Li X, Gaillard F, Vernoux P (2007) Top Catal 44:391–398

    Article  CAS  Google Scholar 

  9. Adler SB (2004) Chem Rev 104:4791–4843

    Article  CAS  Google Scholar 

  10. Benard S, Retailleau L, Gaillard F, Vernoux P, Giroir-Fendler A (2005) Appl Catal B 55:11–21

    Article  CAS  Google Scholar 

  11. Steghuis AG, Van Ommen JG, Lercher JA (1998) Catal Today 46:91–97

    Article  CAS  Google Scholar 

  12. Zhu J, van Ommen JG, Bouwmeester HJM, Lefferts LJ (2005) J Catal 233:434–441

    Article  CAS  Google Scholar 

  13. Zhu J, Mujeebur Rahuman MSM, van Ommen JG, Lefferts L (2004) Appl Catal A 259:95–100

    Article  CAS  Google Scholar 

  14. Obeid E, Lizarraga L, Tsampas MN, Cordier A, Boréave A, Steil MC, Blanchard G, Pajot K (2014) J Catal 309:87–96

    Article  CAS  Google Scholar 

  15. Isaifan RJ, Baranova EA (2013) Electrochem Comm 27:164–167

    Article  CAS  Google Scholar 

  16. Vernoux P, Gaillard F, Bultel L, Siebert E, Primet M (2002) J Catal 205:412–421

    Article  Google Scholar 

  17. Lizarraga L, Guth M, Billard A, Vernoux P (2010) Catal Today 157:61–65

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Université de Lyon, Institut de Recherches sur la Catalyse et l’Environnement de Lyon, UMR 5256, CNRS, Université Claude Bernard Lyon 1, 2 avenue A. Einstein, 69626, Villeurbanne, France

    M. Alves Fortunato, M. N. Tsampas, F. M. Sapountzi & P. Vernoux

  2. Laboratoire de Synthèse et Fonctionnalisation de Céramiques UMR 3080, Saint-Gobain CREE, 550, Avenue Alphonse Jauffret, 84300, Cavaillon, France

    M. Alves Fortunato, A. Princivalle, C. Tardivat & C. Guizard

  3. Saint-Gobain CREE, 550 av A. Jauffret, 84306, Cavaillon, France

    C. Capdeillayre & N. Petigny

Authors
  1. M. Alves Fortunato
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Princivalle
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. C. Capdeillayre
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. Petigny
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. C. Tardivat
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. C. Guizard
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. M. N. Tsampas
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. F. M. Sapountzi
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. P. Vernoux
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. Vernoux.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fortunato, M.A., Princivalle, A., Capdeillayre, C. et al. Role of Lattice Oxygen in the Propane Combustion Over Pt/Yttria-Stabilized Zirconia : Isotopic Studies. Top Catal 57, 1277–1286 (2014). https://doi.org/10.1007/s11244-014-0293-5

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-014-0293-5

Keywords

Search

Navigation