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Self-Coupling of Secondary Alcohols and α-Alkylation of Methyl Ketones with Secondary Alcohols by Pt/CeO2 Catalyst

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Abstract

Transition metal-loaded metal oxides are tested for C–C self-coupling of 2-octanol to a higher ketone at 140 °C. Among various catalysts, Pt/CeO2 shows the highest activity and shows good reusability. Pt/CeO2 is effective for the self-coupling of various aliphatic secondary alcohols and α-alkylation of methyl ketones with aliphatic secondary alcohols. A possible reaction mechanism is discussed.

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Acknowledgments

This work was supported by a MEXT program “Elements Strategy Initiative to Form Core Research Center” (since 2012), Japan.

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Authors and Affiliations

  1. Catalysis Research Center, Hokkaido University, N-21, W-10, Sapporo, 001-0021, Japan

    Chandan Chaudhari & Ken-ichi Shimizu

  2. Elements Strategy Initiative for Catalysts and Batteries, Kyoto University, Katsura, Kyoto, 615-8520, Japan

    S. M. A. Hakim Siddiki & Ken-ichi Shimizu

Authors
  1. Chandan Chaudhari
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  2. S. M. A. Hakim Siddiki
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  3. Ken-ichi Shimizu
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Correspondence to Ken-ichi Shimizu.

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Chaudhari, C., Siddiki, S.M.A.H. & Shimizu, Ki. Self-Coupling of Secondary Alcohols and α-Alkylation of Methyl Ketones with Secondary Alcohols by Pt/CeO2 Catalyst. Top Catal 57, 1042–1048 (2014). https://doi.org/10.1007/s11244-014-0268-6

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  • DOI: https://doi.org/10.1007/s11244-014-0268-6

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