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State of the Art and Perspectives in the “Molecular Approach” Towards Well-Defined Heterogeneous Catalysts

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Abstract

Molecular understanding of heterogeneous catalysts is a key step towards their rational development since catalysis is a molecular phenomenon. Here we describe our efforts towards molecularly defined heterogeneous catalysts through the anchoring of molecular precursors on solid supports and our approaches towards bridging the gap between well-defined and industrial catalysts.

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References

  1. van Leeuwen PWNM, Chadwick JC (2011) Homogeneous Catalysts Activity—Stability—Deactivation. Wiley-VCH, Weinheim

    Book  Google Scholar 

  2. Ballard DGH (1973) Adv Catal 23:263

    CAS  Google Scholar 

  3. Yermakov YI (1981) Stud Surf Sci Catal 7:57

    Article  Google Scholar 

  4. Burwell RL (1984) J Catal 86:301

    Article  CAS  Google Scholar 

  5. Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis, 231 (1988). NATO Advanced Science Institutes Series, Series C; Mathematical and Physical Sciences

  6. Copéret C, Chabanas M, Petroff Saint-Arroman R, Basset JM (2003) Angew Chem Int Ed 42:156

    Article  Google Scholar 

  7. Wegener SL, Marks TJ, Stair PC (2011) Acc Chem Res 45:206

    Article  CAS  Google Scholar 

  8. Thomas JM, Raja R, Lewis DW (2005) Angew Chem Int Ed 44:6456

    Article  CAS  Google Scholar 

  9. Tada M, Iwasawa Y (2007) Coord Chem Rev 251:2702

    Article  CAS  Google Scholar 

  10. Liang Y, Anwander R (2013) Dalton Trans 42:12521

    Article  CAS  Google Scholar 

  11. Guzman J, Gates BC (2003) Dalton Trans 17:3303

    Article  CAS  Google Scholar 

  12. Beale AM, Weckhuysen BM (2010) Phys Chem Chem Phys 12:5562

    Article  CAS  Google Scholar 

  13. Lesage A (2010) Phys Chem Chem Phys 12:5502

    Google Scholar 

  14. Blanc F, Copéret C, Lesage A, Emsley L (2008) Chem Soc Rev 37:518

    Article  CAS  Google Scholar 

  15. Conley MP, Copéret C (2012) Chimia 66:752

    Article  CAS  Google Scholar 

  16. Sautet P, Delbecq F (2010) Chem Rev 110:1788

    Article  CAS  Google Scholar 

  17. Rascon F, Wischert R, Copéret C (2010) Chem Sci 2:1449

    Article  CAS  Google Scholar 

  18. Schrock RR (2006) Angew Chem Int Ed 45:3748

    Article  CAS  Google Scholar 

  19. Grubbs RH (2006) Angew Chem Int Ed 45:3760

    Article  CAS  Google Scholar 

  20. Chabanas M, Baudouin A, Copéret C, Basset J-M (2001) J Am Chem Soc 123:2062

    Article  CAS  Google Scholar 

  21. Chabanas M, Copéret C, Basset J-M (2001) Chem Eur J 9:971

    Article  Google Scholar 

  22. Solans-Monfort X, Clot E, Copéret C, Eisenstein O (2005) J Am Chem Soc 127:14015

    Article  CAS  Google Scholar 

  23. Poater A, Solans-Monfort X, Clot E, Copéret C, Eisenstein O (2007) J Am Chem Soc 129:8207

    Article  CAS  Google Scholar 

  24. Blanc F, Berthoud R, Salameh A, Basset J-M, Copéret C, Singh R, Schrock RR (2007) J Am Chem Soc 129:8434

    Article  CAS  Google Scholar 

  25. Copéret C (2007) Dalton Trans 47:5498

    Article  CAS  Google Scholar 

  26. Jiang AJ, Simpson JH, Mueller P, Schrock RR (2009) J Am Chem Soc 131:7770

    Article  CAS  Google Scholar 

  27. Jiang AJ, Zhao Y, Schrock RR, Hoveyda AH (2009) J Am Chem Soc 131:16630

    Article  CAS  Google Scholar 

  28. Marinescu SC, Schrock RR, Mueller P, Hoveyda AH (2009) J Am Chem Soc 131:10840

    Article  CAS  Google Scholar 

  29. Malcolmson SJ, Meek SJ, Sattely ES, Schrock RR, Hoveyda AH (2008) Nature 456:933

    Article  CAS  Google Scholar 

  30. Hoveyda AH, Zhugralin AR (2007) Nature 450:243

    Article  CAS  Google Scholar 

  31. Wischert R, Laurent P, Copéret C, Delbecq F, Sautet P (2012) J Am Chem Soc 134:14430

    Article  CAS  Google Scholar 

  32. Zagdoun A, Rossini AJ, Gajan D, Bourdolle A, Ouari O, Rosay M, Maas WE, Tordo P, Lelli M, Emsley L, Lesage A, Copéret C (2012) Chem Comm 48:654

    Article  CAS  Google Scholar 

  33. Wischert R, Copéret C, Delbecq F, Sautet P (2011) Chem Comm 47:4890

    Article  CAS  Google Scholar 

  34. Wischert R, Copéret C, Delbecq F, Sautet P (2011) Angew Chem Int Ed 50:3202

    Article  CAS  Google Scholar 

  35. Joubert J, Delbecq F, Sautet P, Roux EL, Taoufik M, Thieuleux C, Blanc F, Copéret C, Thivolle-Cazat J, Basset J-M (2006) J Am Chem Soc 128:9157

    Article  CAS  Google Scholar 

  36. Salameh A, Joubert J, Baudouin A, Lukens W, Delbecq F, Sautet P, Basset J-M, Copéret C (2007) Angew Chem Int Ed 46:3870

    Article  CAS  Google Scholar 

  37. Salameh A, Baudouin A, Soulivong D, Boehm V, Roeper M, Basset J-M, Copéret C (2008) J Catal 253:180

    Article  CAS  Google Scholar 

  38. Blanc F, Copéret C, Thivolle-Cazat J, Basset J-M, Lesage A, Emsley L, Sinha A, Schrock RR (2006) Angew Chem Int Ed 45:1216

    Article  CAS  Google Scholar 

  39. Copéret C, Maury O, Thivolle-Cazat J, Basset J-M (2001) Angew Chem Int Ed 40:2331

    Article  Google Scholar 

  40. Blanc F, Thivolle-Cazat J, Basset J-M, Copéret C (2008) Chem Eur J 14:9030

    Article  CAS  Google Scholar 

  41. Vidal V, Théolier A, Thivolle-Cazat J, Basset J-M, Corker J (1996) J Am Chem Soc 118:4595

    Article  CAS  Google Scholar 

  42. Chabanas M, Vidal V, Copéret C, Thivolle-Cazat J, Basset J-M (2000) Angew Chem Int Ed 39:1962

    Article  CAS  Google Scholar 

  43. Lecuyer C, Quignard F, Choplin A, Olivier D, Basset J-M (1991) Angew Chem Int Ed 30:1660

    Article  Google Scholar 

  44. Vidal V, Théolier A, Thivolle-Cazat J, Basset J-M (1997) Science 276:99

    Article  CAS  Google Scholar 

  45. Thieuleux C, Maraval A, Veyre L, Copéret C, Soulivong D, Basset J-M, Sunley GJ (2007) Angew Chem Int Ed 46:2288

    Article  CAS  Google Scholar 

  46. Basset J-M, Copéret C, Soulivong D, Taoufik M, Thivolle-Cazat J (2010) Acc Chem Res 43:323

    Article  CAS  Google Scholar 

  47. Copéret C (2010) Chem Rev 110:656

    Article  CAS  Google Scholar 

  48. Soulivong D, Copéret C, Thivolle-Cazat J, Basset J-M, Maunders BM, Pardy RBA, Sunley GJ (2004) Angew Chem Int Ed 43:5366

    Article  CAS  Google Scholar 

  49. Soulivong D, Norsic S, Taoufik M, Copéret C, Thivolle-Cazat J, Chakka S, Basset J-M (2008) J Am Chem Soc 130:5044

    Article  CAS  Google Scholar 

  50. Diaz U, Brunel D, Corma A (2013) Chem Soc Rev 42:4083

    Article  CAS  Google Scholar 

  51. Brunel D, Bellocq N, Sutra P, Cauvel A, Lasperas M, Moreau P, Di Renzo F, Galarneau A, Fajula F (1998) Coord Chem Rev 178:1085

    Article  Google Scholar 

  52. Hoffmann F, Cornelius M, Morell J, Fröba M (2006) Angew Chem Int Ed 45:3216

    Article  CAS  Google Scholar 

  53. Corriu RJP, Mehdi A, Reye C (2005) J Mater Chem 15:4285

    Article  CAS  Google Scholar 

  54. Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Science 279:548

    Article  CAS  Google Scholar 

  55. Gajan D, Schwarzwälder M, Conley MP, Gruening WR, Rossini AJ, Zagdoun A, Lelli M, Yulikov M, Jeschke G, Sauvée C, Ouari O, Tordo P, Veyre L, Lesage A, Thieuleux C, Emsley L, Copéret C (2013) J Am Chem Soc 135(41):15459–15466. doi:10.1021/ja405822h

    Article  CAS  Google Scholar 

  56. Margelefsky EL, Zeidan RK, Davis ME (2008) Chem Soc Rev 37:1118

    Article  CAS  Google Scholar 

  57. Bass JD, Anderson SL, Katz A (2003) Angew Chem Int Ed 42:5219

    Article  CAS  Google Scholar 

  58. Gonzalez-Arellano C, Corma A, Iglesias M, Sanchez F (2005) Chem Comm 27:3451

    Article  CAS  Google Scholar 

  59. Brunelli NA, Venkatasubbaiah K, Jones CW (2012) Chem Mater 24:2433

    Article  CAS  Google Scholar 

  60. Maishal TK, Alauzun J, Basset J-M, Copéret C, Corriu RJP, Jeanneau E, Mehdi A, Reyé C, Veyre L, Thieuleux C (2008) Angew Chem Int Ed 47:8654

    Article  CAS  Google Scholar 

  61. Karamé I, Boualleg M, Camus J-M, Maishal TK, Alauzun J, Basset J-M, Copéret C, Corriu RJP, Jeanneau E, Mehdi A, Reyé C, Veyre L, Thieuleux C (2009) Chem Eur J 15:11820

    Article  CAS  Google Scholar 

  62. Samantaray MK, Alauzun J, Gajan D, Kavitake S, Mehdi A, Veyre L, Lelli M, Lesage A, Emsley L, Copéret C, Thieuleux C (2013) J Am Chem Soc 135:3193

    Article  CAS  Google Scholar 

  63. Baffert M, Maishal TK, Mathey L, Copéret C, Thieuleux C (2011) Chem Sus Chem 4:1762

    Article  CAS  Google Scholar 

  64. Conley MP, Drost RM, Baffert M, Gajan D, Elsevier C, Franks WT, Oschkinat H, Veyre L, Zagdoun A, Rossini AJ, Lelli M, Lesage A, Casano G, Ouari O, Tordo P, Emsley L, Copéret C, Thieuleux C (2013) Chem Eur J 19:12234

    Article  CAS  Google Scholar 

  65. Kahn ML, Glaria A, Pages C, Monge M, Saint Macary L, Maisonnat A, Chaudret B (2009) J Mater Chem 19:4044

    Article  CAS  Google Scholar 

  66. Berthoud R, Délichére P, Gajan D, Lukens W, Pelzer K, Basset J-M, Candy J-P, Copéret C (2008) J Catal 260:387

    Article  CAS  Google Scholar 

  67. Low JE, Foelske-Schmitz A, Krumeich F, Worle M, Baudouin D, Rascon F, Copéret C (2013) Dalton Trans 42:12620

    Article  CAS  Google Scholar 

  68. Laurent P, Veyre L, Thieuleux C, Donet S, Copéret C (2013) Dalton Trans 42:238

    Article  CAS  Google Scholar 

  69. Choi YS, Moschetta EG, Miller JT, Fasulo M, McMurdo MJ, Rioux RM, Tilley TD (2011) ACS Catal 1:1166

    Article  CAS  Google Scholar 

  70. Bonati MLM, Douglas TM, Gaemers S, Guo N (2012) Organometallics 31:5243

    Article  CAS  Google Scholar 

  71. Gajan D, Guillois K, Delichère P, Basset J-M, Candy J-P, Caps V, Copéret C, Lesage A, Emsley L (2009) J Am Chem Soc 131:14667

    Article  CAS  Google Scholar 

  72. Becerra LR, Gerfen GJ, Temkin RJ, Singel DJ, Griffin RG (1993) Phys Rev Lett 71:3561

    Article  CAS  Google Scholar 

  73. Rosay M, Tometich L, Pawsey S, Bader R, Schauwecker R, Blank M, Borchard PM, Cauffman SR, Felch KL, Weber RT, Temkin RJ, Griffin RG, Maas WE (2010) Phys Chem Chem Phys 12:5850

    Article  CAS  Google Scholar 

  74. Lesage A, Lelli M, Gajan D, Caporini MA, Vitzthum V, Miéville P, Alauzun J, Roussey A, Thieuleux C, Mehdi A, Bodenhausen G, Copéret C, Emsley L (2010) J Am Chem Soc 132:15459

    Article  CAS  Google Scholar 

  75. Lelli M, Gajan D, Lesage A, Caporini MA, Vitzthum V, Miéville P, Héroguel F, Rascon F, Roussey A, Thieuleux C, Boualleg M, Veyre L, Bodenhausen G, Copéret C, Emsley L (2011) J Am Chem Soc 133:2104

    Article  CAS  Google Scholar 

  76. Zagdoun A, Casano G, Ouari O, Lapadula G, Rossini AJ, Lelli M, Baffert M, Gajan D, Veyre L, Maas WE, Rosay M, Weber RT, Thieuleux C, Copéret C, Lesage A, Tordo P, Emsley L (2011) J Am Chem Soc 134:2284

    Article  CAS  Google Scholar 

  77. Vitzthum V, Mieville P, Carnevale D, Caporini MA, Gajan D, Copéret C, Lelli M, Zagdoun A, Rossini AJ, Lesage A, Emsley L, Bodenhausen G (2012) Chem Comm 48:1988

    Article  CAS  Google Scholar 

  78. Song C, Hu KN, Joo CG, Swager TM, Griffin RG (2006) J Am Chem Soc 128:11385

    Article  CAS  Google Scholar 

  79. Zagdoun A, Casano G, Ouari O, Schwarzwälder M, Rossini AJ, Aussenac F, Yulikov M, Jeschke G, Copéret C, Lesage A, Tordo P, Emsley L (2013) J Am Chem Soc 135(34):12790–12797. doi:10.1021/ja405813t

    Article  CAS  Google Scholar 

  80. Lee D, Takahashi H, Thankamony ASL, Dacquin J-P, Bardet M, Lafon O, Paepe G (2012) J Am Chem Soc 134:18491

    Article  CAS  Google Scholar 

  81. Lafon O, Rosay M, Aussenac F, Lu X, Trébosc J, Cristini O, Kinowski C, Touati N, Vezin H, Amoureux J-P (2011) Angew Chem Int Ed 50:8367

    Article  CAS  Google Scholar 

  82. Gruning WR, Rossini AJ, Zagdoun A, Gajan D, Lesage A, Emsley L, Copéret C (2013) Phys Chem Chem Phys 15:13270

    Article  CAS  Google Scholar 

  83. Jezequel M, Dufaud V, Ruiz-Garcia MJ, Carrillo-Hermosilla F, Neugebauer U, Niccolai GP, Lefebvre F, Bayard F, Corker J, Fiddy S, Evans J, Broyer J-P, Malinge J, Basset J-M (2001) J Am Chem Soc 123:3520

    Article  CAS  Google Scholar 

  84. Millot N, Soignier S, Santini CC, Baudouin A, Basset J-M (2006) J Am Chem Soc 128:9361

    Article  CAS  Google Scholar 

  85. Kim SH, Somorjai GA (2006) Proc Nat Acad Sci 103:15289

    Article  CAS  Google Scholar 

  86. Kaminsky W, Poly J (2004) Sci A 42:3911

    CAS  Google Scholar 

  87. Williams LA, Marks TJ (2011) ACS Catal 1:238

    Article  CAS  Google Scholar 

  88. Seenivasan K, Gallo E, Piovano A, Vitillo JG, Sommazzi A, Bordiga S, Lamberti C, Glatzel P, Groppo E (2013) Dalton Trans 42:12706

    Article  CAS  Google Scholar 

  89. Gallo E, Lamberti C, Glatzel P (2011) Phys Chem Chem Phys 13:19409

    Article  CAS  Google Scholar 

  90. Grau E, Lesage A, Norsic S, Copéret C, Monteil V, Sautet P (2012) ACS Catal 3:52

    Article  CAS  Google Scholar 

  91. McDaniel MP (2010) Adv Catal 53:123

    CAS  Google Scholar 

  92. Groppo E, Estephane J, Lamberti C, Spoto G, Zecchina A (2007) Catal Today 126:228

    Article  CAS  Google Scholar 

  93. Groppo E, Lamberti C, Bordiga S, Spoto G, Zecchina A (2005) Chem Rev 105:115

    Article  CAS  Google Scholar 

  94. Bordiga S, Groppo E, Agostini G, van Bokhoven JA, Lamberti C (2013) Chem Rev 113:1736

    Article  CAS  Google Scholar 

  95. Theopold KH (1998) Eur J Inorg Chem 1:15

    Article  Google Scholar 

  96. MacAdams LA, Buffone GP, Incarvito CD, Rheingold AL, Theopold KH (2005) J Am Chem Soc 127:1082

    Article  CAS  Google Scholar 

  97. Conley MP, Delley MF, Siddiqi G, Lapadula G, Norsic S, Monteil V, Safonova OV, Copéret C (2014) Angew Chem Int Ed Engl 53(7):1872–1876

    Article  CAS  Google Scholar 

  98. Cavani F, Teles JH (2009) Chem Sus Chem 2:508

    Article  CAS  Google Scholar 

  99. Mania P, Verel R, Jenny F, Hammond C, Hermans I (2013) Chem Eur J 19:9849

    Article  CAS  Google Scholar 

  100. Mutin PH, Vioux A (2009) Chem Mater 21:582

    Article  CAS  Google Scholar 

  101. Fujdala KL, Tilley TD (2003) J Catal 216:265

    Article  CAS  Google Scholar 

  102. Wang C, Liu D, Lin W (2013) J Am Chem Soc 135(36):13222–13234. doi:10.1021/ja308229p

    Article  CAS  Google Scholar 

  103. Waki M, Mizoshita N, Tani T, Inagaki S (2011) Angew Chem Int Ed 50:11667

    Article  CAS  Google Scholar 

  104. Inagaki S, Guan S, Ohsuna T, Terasaki O (2002) Nature 416:304

    Article  CAS  Google Scholar 

  105. An K, Somorjai GA (2012) Chem Cat Chem 4:1512

    CAS  Google Scholar 

  106. Cormary B, Dumestre F, Liakakos N, Soulantica K, Chaudret B (2013) Dalton Trans 42:12546

    Article  CAS  Google Scholar 

  107. Corma A, Garcia H (2008) Chem Soc Rev 37:2096

    Article  CAS  Google Scholar 

  108. Baudouin D, Szeto KC, Laurent P, De Mallmann A, Fenet B, Veyre L, Rodemerck U, Copéret C, Thieuleux C (2012) J Am Chem Soc 134:20624

    Article  CAS  Google Scholar 

  109. Boualleg M, Norsic S, Baudouin D, Sayah R, Quadrelli EA, Basset J-M, Candy JP, Delichere P, Pelzer K, Veyre L, Thieuleux C (2011) J Catal 284:184

    Article  CAS  Google Scholar 

  110. Arnal PM, Comotti M, Schuth F (2012) Angew Chem Int Ed 45:8224

    Article  Google Scholar 

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Conley, M.P., Copéret, C. State of the Art and Perspectives in the “Molecular Approach” Towards Well-Defined Heterogeneous Catalysts. Top Catal 57, 843–851 (2014). https://doi.org/10.1007/s11244-014-0245-0

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