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Catalytic Activities of Alcohol Transformations Over 8-Ring Zeolites

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Abstract

Aluminosilicate H/CHA and H/MTF zeolites show remarkably different catalytic activities in the methanol and ethanol transformations although they have similar pore size of 8-membered ring structures. Moreover, the produced ethylene is further converted on H/CHA, but H/MTF is not active for the ethylene transformation. The correlations between the distinct catalytic differences and their intrinsic structural properties, including topology and acidity, are discussed.

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Acknowledgements

The financial funding from Mitsubishi Chemical Company (MCC) is gratefully acknowledged.

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Authors and Affiliations

  1. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, 226-8503, Yokohama, Japan

    Qingjun Zhu, Junko N. Kondo & Takashi Tatsumi

  2. Division of Materials Science and Chemical Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, 240-8501, Yokohama, Japan

    Satoshi Inagaki

Authors
  1. Qingjun Zhu
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  2. Junko N. Kondo
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  3. Satoshi Inagaki
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  4. Takashi Tatsumi
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Correspondence to Takashi Tatsumi.

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Zhu, Q., Kondo, J.N., Inagaki, S. et al. Catalytic Activities of Alcohol Transformations Over 8-Ring Zeolites. Top Catal 52, 1272–1280 (2009). https://doi.org/10.1007/s11244-009-9272-7

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  • DOI: https://doi.org/10.1007/s11244-009-9272-7

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