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Preparation, crystal structures and magnetic properties of hetero- and homo-metallic coordination polymers with triazacyclononane derivatives bearing propionic acid pendant arms

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Abstract

Two Cu(II)–Na(I) hetero-metallic coordination polymers [Cu2Na5(tacntp)2(H2O)9](ClO4)3·2H2O (1) and [Cu2Na5(tacntp)2(H2O)9](ClO4)3·2H2O (2) were constructed from Cu(II) salts and a trisubstituted N-propionic acid functionalized ligand, namely 1,4,7-triazacyclononane-1,4,7-tripropionic acid (tacntpH3). In complex 1, the Na+ ions act as nodes, being surrounded by six [Cu(tacntp)]− moieties resulting in a 2D coordination polymer. In complex 2, Na+ ions are bridged by pendant carboxylate groups and water ligands to give a 1D Na–O inorganic polymeric ribbon, which is expanded into a complicated 2D hetero-metallic array through the connecting [Cu(tacntp)]− units. The differences between the two structures are related to the amount of Na+ ions present in the reaction media. In further experiments, the trisubstituted pro-ligand tacntpH3 underwent a hydrothermal Cu(II)-induced cleavage of one of three pendant arms, and the resultant disubstituted pro-ligand tacndpH2 assembled with Cu(II) to give a 1D homo-metallic zigzag chain compound [Cu(tacndp)]ClO4·H2O (3). Magnetic susceptibility measurements on complex 3 revealed a ferromagnetic interaction between the Cu(II) centers within the 1D chain.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant No. 21361004), the Guangxi Natural Science Foundation of China (Grant No. 2014GXNSFAA118044), the Natural Science Foundation of Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Guangxi Normal University), Ministry of Education of China (CMEMR 2012-A08, CMEMR2013-C08).

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Authors and Affiliations

  1. School of Chemistry and Pharmacy of Guangxi Normal University, Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), Guilin, 541004, People’s Republic of China

    Qin Wei, Qi Tang, Yan-Fang Feng & Zhong Zhang

  2. Guangxi Academy of Fishery Sciences, Nanning, People’s Republic of China

    Yong-Zhi Liao

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  1. Qin Wei
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  2. Qi Tang
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  3. Yan-Fang Feng
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  4. Zhong Zhang
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Correspondence to Zhong Zhang or Yong-Zhi Liao.

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Wei, Q., Tang, Q., Feng, YF. et al. Preparation, crystal structures and magnetic properties of hetero- and homo-metallic coordination polymers with triazacyclononane derivatives bearing propionic acid pendant arms. Transit Met Chem 42, 41–50 (2017). https://doi.org/10.1007/s11243-016-0104-x

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