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Synthesis, crystal structures, and properties of three coordination polymers of 5-(1H-imidazol-1-yl) isophthalic acid

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Abstract

Three coordination polymers have been obtained by hydrothermal synthesis, namely [Zn(imip)(H2O)2]·0.5H2O (1), [Co(imip)(H2O)2]·0.5H2O (2), and [Cd2(imip)2(H2O)3] (3) [H2imip = 5-(1H-imidazol-1-yl) isophthalic acid]. The coordination polymers were characterized by IR spectra, elemental analysis, powder X-ray diffraction, and thermogravimetric analysis. Furthermore, single-crystal X-ray analysis reveals that they have 2D structures, which are extended into 3D networks via O–H···O hydrogen-bonding interactions. The luminescent properties of these coordination polymers were investigated.

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Acknowledgments

The authors thank the National Natural Science Foundation of China (21267003), P.R. China, the Natural Science Foundation of Guangxi (053020), P.R. China, and Guangxi University for Nationalities.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning, 530006, People’s Republic of China

    Dong-Lin Fang, Shao-Yin Mo, Kai-Fei Wu & Zhong-Jing Huang

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  1. Dong-Lin Fang
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  2. Shao-Yin Mo
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Correspondence to Zhong-Jing Huang.

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Fang, DL., Mo, SY., Wu, KF. et al. Synthesis, crystal structures, and properties of three coordination polymers of 5-(1H-imidazol-1-yl) isophthalic acid. Transit Met Chem 42, 273–283 (2017). https://doi.org/10.1007/s11243-016-0081-0

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