Skip to main content
SpringerLink
Log in

Synthesis, crystal structures and photocatalytic properties of four silver(I) coordination polymers based on semirigid bis(pyrazole) and carboxylic acid co-ligands

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Four Ag(I) coordination polymers, formulated as [Ag(L1)(tpa)0.5] n (1), {[Ag(L2)(ndc)0.5]·0.5H2ndc} n (2), [Ag(L3)0.5(ndc)0.5] n (3) and {[Ag(L3)]·H3bptc} n (4) (L1 = 4,4′-bis(pyrazole-1-ylmethyl)-biphenyl, L2 = 4,4′-bis(3,5-dimethylpyrazol-1-ylmethyl)-biphenyl, L3 = 1,4-bis(3,5-dimethylpyrazol-1-ylmethyl)benzene, H2tpa = terephthalic acid, H2ndc = 2,6-naphthalenedicarboxylic acid, H4bptc = 3,3′,4,4′-biphenyltetracarboxylic acid), have been hydrothermally synthesized and structurally characterized. Complex 1 features the rare binodal (4,4)-connected 2D 4,4L10 topological network with a point symbol of {32·4.62·7}2{32·62·72}. Complex 2 has a folded ladder-like chain structure, which is further extended into a 3D supramolecular network via O–H···O hydrogen bonding and π···π stacking interactions. Complexes 3 and 4 both possess 1D zigzag chain structures. Complex 3 is further extended into a binodal (3,4)-connected network with the point symbol of {4.84·10}{62·82}2 by Ag···O weak interactions, while complex 4 is further connected through O–H···O hydrogen bonding and π···π interactions to afford a 2D supramolecular structure. The photoluminescence spectra and photocatalytic properties of these complexes for degradation of methylene blue and methyl orange are reported.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Cui GH, He CH, Jiao CH, Geng JC, Blatov VA (2012) CrystEngComm 14:4210–4216

    Article  CAS  Google Scholar 

  2. Shustova NB, McCarthy BD, Dinca M (2011) J Am Chem Soc 133:20126–20129

    Article  CAS  Google Scholar 

  3. Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, Yaghi OM (2003) Science 300:1127–1129

    Article  CAS  Google Scholar 

  4. Li HH, Shi W, Xu N, Zhang ZJ, Niu Z, Han T, Cheng P (2012) Cryst Growth Des 12:2602–2612

    Article  CAS  Google Scholar 

  5. Wang JC, Liu QK, Ma JP, Huang F, Dong YB (2014) Inorg Chem 53:10791–10793

    Article  CAS  Google Scholar 

  6. Jaros SWM, Guedes da Silva MFC, Florek M, Oliveira MC, Smolenski P, Pombeiro AJ, Kirillov AM (2014) Cryst Growth Des 14:5408–5417

    Article  CAS  Google Scholar 

  7. Stephenson A, Ward MD (2012) RSC Adv 2:10844–10853

    Article  CAS  Google Scholar 

  8. Argent SP, Adams H, Riis-Johannessen T, Jeffery JC, Harding LP, Mamula O, Ward MD (2006) Inorg Chem 45:3905–3919

    Article  CAS  Google Scholar 

  9. Hao JM, Yu B, Hecke KV, Cui GH (2015) CrystEngComm 17:2279–2293

    Article  CAS  Google Scholar 

  10. Barreiro E, Casas JS, Couce MD, Laguna A, López-de-Luzuriaga JM, Monge M, López EMV (2013) Dalton Trans 42:5916–5923

    Article  CAS  Google Scholar 

  11. Liang MX, Ruan CZ, Sun D, Kong XJ, Ren YP, Long LS, Zheng LS (2014) Inorg Chem 53:897–902

    Article  CAS  Google Scholar 

  12. Huan DH, Liu YG, Yu B, Hecke KV, Cui GH (2016) Inorg Chem Commun 67:17–21

    Article  CAS  Google Scholar 

  13. Sun D, Wei ZH, Wang DF, Zhang N, Huang RB, Zheng LS (2011) Cryst Growth Des 11:1427–1430

    Article  CAS  Google Scholar 

  14. Wang XX, Liu YG, Ge M, Cui GH (2015) Chinese. J Inorg Chem 31:2065–2072

    CAS  Google Scholar 

  15. Salonen LM, Ellermann M, Diederich F (2011) Angew Chem 123:4908–4944

    Article  Google Scholar 

  16. Liu GZ, Wang JG, Wang LY (2012) CrystEngComm 14:951–960

    Article  CAS  Google Scholar 

  17. Wang XX, Yu B, Hecke KV, Cui GH (2014) RSC Adv 4:61281–61289

    Article  CAS  Google Scholar 

  18. Zhao XL, Zhang LL, Ma HQ, Sun D, Wang DX, Feng SY, Sun DF (2012) RSC Adv 2:5543–5549

    Article  CAS  Google Scholar 

  19. Li CP, Yu Q, Chen J, Du M (2010) Cryst Growth Des 10:2650–2660

    Article  CAS  Google Scholar 

  20. Su Z, Fan J, Okamura TA, Sun WY, Ueyama N (2010) Cryst Growth Des 10:3515–3521

    Article  CAS  Google Scholar 

  21. Zheng B, Dong H, Bai JF, Li YZ, Li SH, Scheer M (2008) J Am Chem Soc 130:7778–7779

    Article  CAS  Google Scholar 

  22. Hu JM, Blatov VA, Yu B, Hecke KV, Cui GH (2016) Dalton Trans 45:2426–2429

    Article  CAS  Google Scholar 

  23. Dias SSP, André V, Kłak J, Duarte MT, Kirillov AM (2014) Cryst Growth Des 14:3398–3407

    Article  CAS  Google Scholar 

  24. Christer BA, John D, Meg EF (2006) CrystEngComm 8:586–588

    Article  Google Scholar 

  25. Hazel F, Ian ST, Michael DW (2011) CrystEngComm 13:1432–1440

    Article  Google Scholar 

  26. Wang XY, Liu SQ, Wei XL, Zhang CY, Song G, Bai FY, Xing YH, Shi Z (2012) Polyhedron 47:151–164

    Article  CAS  Google Scholar 

  27. Hoskins BF, Robson R, Slizys DA (1997) J Am Chem Soc 119:2952–2953

    Article  CAS  Google Scholar 

  28. Hartshorn CM, Steel PJ (1995) Aust J Chem 48:1587–1599

    Article  CAS  Google Scholar 

  29. Agilent Technologies (2012) CrysAlis PRO Agilent Technologies, Yarnton, England

  30. Sheldrick GM (2008) Acta Crystallogr Sect A: Found Crystallogr 64:112–122

    Article  CAS  Google Scholar 

  31. Deacon GB, Phillips RJ (1980) Coord Chem Rev 33:227–250

    Article  CAS  Google Scholar 

  32. Cordero B, Gómez V, Platero-Prats AE, Revés M, Echeverría J, Cremades E, Alvarez S (2008) Dalton Trans 21:2832–2838

    Article  Google Scholar 

  33. Bisht KK, Kathalikkattil AC, Suresh E (2012) RSC Adv 2:8421–8428

    Article  CAS  Google Scholar 

  34. Li Q, Fu ML, Liu X, Guo GC, Huang JS (2006) Inorg Chem Commun 9:767–771

    Article  CAS  Google Scholar 

  35. Hau SC, Mak TC (2013) Polyhedron 64:63–72

    Article  CAS  Google Scholar 

  36. Marcinkowski D, Wałęsa-Chorab M, Patroniak V, Kubicki M, Kądziołka G, Michalkiewicz B (2014) New J Chem 38:604–610

    Article  CAS  Google Scholar 

  37. Kole GK, Chin CK, Tan GK, Vittal JJ (2013) Polyhedron 52:1440–1448

    Article  CAS  Google Scholar 

  38. Yang L, Powell DR, Houser RP (2007) Dalton Trans 9:955–964

    Article  Google Scholar 

  39. Sun D, Liu FJ, Huang RB, Zheng LS (2013) CrystEngComm 15:1185–1193

    Article  CAS  Google Scholar 

  40. Xu JX, Wang RY, Li YM, Gao ZY, Yao R, Wang S, Wu BL (2012) Eur J Inorg Chem 20:3349–3360

    Article  Google Scholar 

  41. Sarma D, Ramanujachary KV, Lofland SE, Magdaleno T, Natarajan S (2009) Inorg Chem 48:11660–11676

    Article  CAS  Google Scholar 

  42. Gong Y, Jiang PG, Wang YX, Wu T, Lin JH (2013) Dalton Trans 42:7196–7203

    Article  CAS  Google Scholar 

  43. Wang SL, Hu FL, Zhou JY, Zhou Y, Huang Q, Lang JP (2015) Cryst Growth Des 15:4087–4097

    Article  CAS  Google Scholar 

  44. Zhang HM, Yang J, Kan WQ, Liu YY, Ma JF (2015) Cryst Growth Des 16:265–276

    Article  CAS  Google Scholar 

  45. Wang XL, Gong CH, Zhang JW, Hou LL, Luan J, Liu GC (2014) CrystEngComm 16:7745–7752

    Article  CAS  Google Scholar 

  46. Hu Y, Luo F, Dong FF (2011) Chem Commun 47:761–763

    Article  CAS  Google Scholar 

  47. Kan WQ, Liu B, Yang J, Liu YY, Ma JF (2012) Cryst Growth Des 12:2288–2298

    Article  CAS  Google Scholar 

  48. Liu L, Ding J, Li M, Lv XF, Wu J, Hou HW, Fan YT (2014) Dalton Trans 43:12790–12799

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation—Steel and Iron Foundation of Hebei Province (B2015209299).

Author information

Authors and Affiliations

  1. College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science and Technology, Tangshan, 063009, Hebei, People’s Republic of China

    Dian-Heng Huan, Yan-Qin Zhao, Gui-Ying Dong & Sheng-Chun Wang

  2. Jiangsu Marine Resources Development Research Institute, Huaihai Institute of Technology, Lianyungang, 222005, Jiangsu, People’s Republic of China

    Fu-Jun Yin

Authors
  1. Dian-Heng Huan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yan-Qin Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Gui-Ying Dong
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Fu-Jun Yin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Sheng-Chun Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Gui-Ying Dong or Sheng-Chun Wang.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 1987 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Huan, DH., Zhao, YQ., Dong, GY. et al. Synthesis, crystal structures and photocatalytic properties of four silver(I) coordination polymers based on semirigid bis(pyrazole) and carboxylic acid co-ligands. Transit Met Chem 41, 701–712 (2016). https://doi.org/10.1007/s11243-016-0071-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-016-0071-2

Keywords

Search

Navigation