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Synthesis, characterization and antimicrobial properties of lipophilic palladium complexes bearing iminopyridine ligands

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Abstract

The reaction of [PdCl2(η2-coe)]2 (coe = cis-cyclooctene) with nine lipophilic iminopyridine ligands (NN′, 1a–i) afforded the corresponding metal complexes cis-[PdCl2(NN′)] (2a–i) with concomitant loss of the labile coe ligands. All iminopyridine complexes were characterized by physicochemical and spectroscopic methods. The molecular structures of two complexes, 2a and 2b, were determined by single crystal X-ray diffraction studies. All complexes were tested for their potential antifungal and antibacterial activities.

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Acknowledgments

Thanks are gratefully extended to Mount Allison University, the University of New Brunswick and the Canada Research Chair Program. We also thank Dan G. B. Durant (MAU) for his expert technical assistance and Drs. J. Waller (MAU) and C. Dieni (MAU) for help with the biological testing and anonymous reviewers are thanked for their very helpful comments.

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Authors and Affiliations

  1. Department of Biology, Mount Allison University, Sackville, NB, E4L 1G7, Canada

    Patrick T. Gormley, B. Ninh Khuong & Felix J. Baerlocher

  2. Department of Chemistry and Biochemistry, Mount Allison University, Sackville, NB, E4L 1G8, Canada

    Courtney M. Dickie, Ashley M. Taweel, Heather L. Blundon, Josée-Marie E. J. Melanson, Adam F. LeBlanc, Tara S. Murphy, Curran G. Tompkins, Christopher M. Vogels, Tyson J. MacCormack & Stephen A. Westcott

  3. Department of Chemistry, University of New Brunswick, Fredericton, NB, E3B 5A3, Canada

    Andreas Decken

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  1. Patrick T. Gormley
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  14. Stephen A. Westcott
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Correspondence to Stephen A. Westcott.

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Gormley, P.T., Ninh Khuong, B., Dickie, C.M. et al. Synthesis, characterization and antimicrobial properties of lipophilic palladium complexes bearing iminopyridine ligands. Transition Met Chem 40, 813–819 (2015). https://doi.org/10.1007/s11243-015-9977-3

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  • DOI: https://doi.org/10.1007/s11243-015-9977-3

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