The introduction of copper and CeO2 into nickel-containing catalysts supported on zirconia stabilized by scandia and ceria (ScCeSZ) provides for their stable activity and enhances their resistance to coke deposition in the steam and oxidative steam reforming of butane. The presence of oxygen in the reaction mixture decreases coke deposition on the surface of these catalysts and reduces the temperature required to achieve complete butane conversion in the presence of a Ni-Cu-CeO2/ScCeSZ composite.
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References
Y. M. Choi, C. Compson, M. C. Lin, et al., J. Alloys Comp., 427, Nos. 1/2, 25-29 (2007).
E.ON Ruhrgas AG, Technical Customer Service (2007).
K. Eguchi, K. Tanaka, T. Matsui, et al., Catal. Today, 146, 154-159 (2009).
D. H. Prasad, S. Y. Park, H. Ji, et al., Appl. Catal. A, 411/412, 160-169 (2012).
K. Polychronopoulou, C. Kalamaras, and A. Efsatiou, Recent Patents on Materials Science, 4, 1-24 (2011).
C. Lu, W. L. Worrell, R. J. Gorte, et al., J. Electrochem. Soc., 150, No. 3, A354-A358 (2003).
Z. Zhan and S. A. Barnett, Science, 308, No. 5723, 844-847 (2005).
M. L. Faro, D. L. Rosa, G. Monforte, et al., J. Appl. Electrochem., 37, 203-208 (2007).
S. Ayabe, H. Omoto, T. Utaka, et al., Appl. Catal. A, 241, 261-269 (2003).
L. Pino, A. Vita, and F. Cipiti, Catal. Lett., 122, 121-130 (2008).
V. A. Sadykov, N. M. Mezentseva, R. V. Bunina, et al., Catal. Today, 131, 226-237 (2008).
M. R. Kantserova, V. I. Chedrik, and S. N. Orlyk, Teor. Éksp. Khim., 50, No. 4, 237-243 (2014). [Theor. Exp. Chem., 50, No. 4, 237-244 (2014) (English translation).]
W. Wang and R. J. Gorte, Appl. Catal. A, 224, 209-218 (2002).
S. N. Orlik and T. K. Shashkova, Kinet. Katal., 55, No. 5, 1-14 (2014).
R. J. Gorte and J. M. Vohs, J. Catal., 216, 477-486 (2003).
K. N. Rao, P. Venkataswamy, and B. M. Reddy, Ind. Eng. Chem. Res., 50, No. 21, 11960-11969 (2011).
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 50, No. 6, pp. 375-380, November-December, 2014.
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Kantserova, M.R., Chedryk, V.I. & Orlyk, S.N. Activity and Stability of Multicomponent Nickel-Containing Catalysts Supported on Zirconia in the Steam Reforming and Oxidative Steam Reforming of Butane. Theor Exp Chem 50, 378–383 (2015). https://doi.org/10.1007/s11237-015-9391-0
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DOI: https://doi.org/10.1007/s11237-015-9391-0