Abstract
A spectrophotometric method was used to select conditions for the development of aqueous systems based on new calix[4]resorcinols containing amino acid moieties at the upper rim and heptyl or nonyl substituents at the lower rim. It was found that the additives of N-metylglucamine lead to the increase in the solubility in water of the macrocycles under study. Traditional surfactants (cetyltrimetylammonium bromide and sodium dodecylsulfate) considerably increase the solubility of calix[4]resorcinols under study due to their solubilization in the nonpolar micelle core when the concentration of the amphiphilic compounds is half as large as the concentration of N-metylglucamine.
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Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1982—1985, August, 2015.
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Gainanova, G.A., Bekmukhametova, A.M., Saifutdinova, M.N. et al. Solubilization of new calix[4]resorcinols with amino acid substituents at the upper rim in surfactant micellar solutions. Russ Chem Bull 64, 1982–1985 (2015). https://doi.org/10.1007/s11172-015-1105-1
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DOI: https://doi.org/10.1007/s11172-015-1105-1