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Thermal decomposition of iron cyano complexes in an inert atmosphere

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Abstract

The thermal decomposition of K3[Fe(CN)6] (1), [Co(NH3)6][Fe(CN)6] (2), [Co(NH3)6]4[Fe(CN)6]3•13H2O (3), Ni3[Fe(CN)6]2•20H2O (4), and [Ni(NH3)6]3[Fe(CN)6]2 (5) was studied in an inert atmosphere (argon and nitrogen) in the temperature range from 20 to 1000 °С. The TG—DSC—DTG curves were obtained. The analyses of solid thermolysis products of compounds 1—5 and gaseous thermolysis products of compounds 1 and 5 were carried out using IR spectroscopy. Depending on temperature, the solid thermolysis products of K3[Fe(CN)6] (1) are K4[Fe(CN)6], Fe4[Fe(CN)6], KCN, Fe3C, and C, and the gaseous thermolysis products are (CN)2 and N2. A deficient of potassium is observed in the residues obtained at ≥800 °С. The thermal decomposition of compounds 2—5 is accompanied by the evolution of Н2О (3, 4), NH3, N2, and HCN. Free metals Co and Fe and intermetallic compounds CoFe, FeNi, and Ni3Fe in a mixture with carbon (25—60% of the initial C content in the complex) are formed in the solid state. Gaseous (CN)2 is formed only in the case of compound 1. The thermolysis of the hydrogen-containing complexes gives HCN.

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References

  1. S. I. Pechenyuk, D. P. Domonov, J. Struct. Chem. (Engl. Transl.), 2011, 52, 412

    CAS  Google Scholar 

  2. S. I. Pechenyuk, Zh. Strukt. Khim., 2011, 52, 419].

    Google Scholar 

  3. S. V. Korenev, A. B. Venediktov, Yu. Shubin, S. A. Gromilov, K. V. Yusenko, J. Struct. Chem. (Engl. Transl.), 2003, 44, 46

    CAS  Google Scholar 

  4. S. V. Korenev, Zh. Strukt. Khim., 2003, 44, 58].

    Google Scholar 

  5. S. I. Pechenyuk, D. P. Domonov, D. L. Rogachev, A. T. Belyaevskii, Russ. J. Inorg. Chem. (Engl. Transl.), 2007, 52, 1033

    Article  Google Scholar 

  6. S. I. Pechenyuk, Zh. Neorg. Khim., 2007, 52, 1110].

    CAS  Google Scholar 

  7. S. I. Pechenyuk, A. N. Gosteva, D. P. Domonov, T. I. Makarova, Vestn. Yuzhno-Ural. Gos. Un-ta. Ser. Khim. [Bulletin of South Ural State Univ., Ser. Khim.], 2012, no. 24, 4 (in Russian).

    Google Scholar 

  8. S. I. Pechenyuk, A. N. Gosteva, Russ. J. Coord. Chem. (Engl. Transl.), 2014, 40, 547

    Article  CAS  Google Scholar 

  9. S. I. Pechenyuk, Koord. Khim., 2014, 40, 476].

    Article  Google Scholar 

  10. S. I. Pechenyuk, D. P. Domonov, A. N. Gosteva, G. I. Kadyrova, V. T. Kalinnikov Russ. J. Coord. Chem. (Engl. Transl.), 2012, 38, 596

    Article  CAS  Google Scholar 

  11. S. I. Pechenyuk, Koord. Khim., 2012, 38, 618].

    Article  Google Scholar 

  12. S. I. Pechenyuk, D. P. Domonov, A. A. Avedisyan, S. V. Ikorskii, Russ. J. Inorg. Chem. (Engl. Transl.), 2010, 55, 734

    Article  CAS  Google Scholar 

  13. S. I. Pechenyuk, Zh. Neorg. Khim., 2010, 55, 788].

    Google Scholar 

  14. G. B. Seifer, Zh. Neorg. Khim., 1960, 5, 68

    CAS  Google Scholar 

  15. G. B. Seifer, J. Inorg. Chem. USSR (Engl. Transl.), 1960, 5].

    Google Scholar 

  16. C. Aparicio, L. Machala, Z. Marusak, J. Therm. Anal. Calorim., 2012, 110, 661.

    Article  CAS  Google Scholar 

  17. G. B. Seifer, V. I. Belova, Z. A. Makarova, Zh. Neorg. Khim., 1964, 9, 1556

    CAS  Google Scholar 

  18. G. B. Seifer, J. Inorg. Chem. USSR (Engl. Transl.), 1964, 9].

    Google Scholar 

  19. M. M. Chamberlain, A. F. Greene, J. Inorg. Nucl. Chem., 1963, 25, 1471.

    Article  CAS  Google Scholar 

  20. J. Lehto, M. Pettersson, J. Hinkula, M. Räsänen, M. Elomaa, Thermochim. Acta, 1995, 265, 25.

    Article  CAS  Google Scholar 

  21. C. W. Ng, J. Ding, L. M. Gant, J. Solid State Chem., 2001, 156, 400.

    Article  CAS  Google Scholar 

  22. B. Mohai, Z. anorg. allg. Chemie, 1972, 392, 287.

    Article  CAS  Google Scholar 

  23. A. Horvath, B. Mohai, J. Inorg. Nucl. Chem., 1980, 42, 195.

    Article  CAS  Google Scholar 

  24. S. Kohata, M. Asakawa, T. Maeda, H. Shyo, A. Ohyoshi, Analyt. Sci., 1986, 2, 325.

    Article  CAS  Google Scholar 

  25. H. Chen, X. Xin, J. Niuet, A. Dai (A. P. Tai), X. Wang, Yu. Zhang, Chem. J. Chinese Univ., Engl. Ed., 1988, 4, 8.

    Google Scholar 

  26. Z. Travnicek, R. Zboril, M. Matikova-Malarovaet, B. Drahos, J. Cernak, Chem. Central J., 2013, 7, 28.

    Article  CAS  Google Scholar 

  27. B. F. Ormont, B. A. Petrov, Zh. Fiz. Khim. [Sov. J. Phys. Chem.], 1933, 5, 706 (in Russian).

    Google Scholar 

  28. B. A. Petrov, B. F. Ormont, Zh. Prikl. Khim. [Sov. J. Appl. Chem.], 1935, 8, 1330 (in Russian).

    CAS  Google Scholar 

  29. B. F. Ormont, B. A. Petrov, Zh. Fiz. Khim. [Sov. J. Phys. Chem.], 1935, 6, 695 (in Russian).

    Google Scholar 

  30. Handbuch der Präparativen anorganischen Chemie in drei Bänden, Herausgegeben von Georg Brauer, Ferdinand Enke Verlag, Stuttgart, 1978.

  31. JCPDS-ICDD Card. Newtown Square (PA, USA): International Centre for Diffraction Data, 2002.

    Google Scholar 

  32. C. R. Keedy, J. Chem. Educ., 1992, 69, A296.

    Article  CAS  Google Scholar 

  33. F. Cataldo, E. Lilla, O. Ursini, G. Angelini, J. Anal. Appl. Pyrolysis, 2010, 87, no. 1, 34.

    Article  CAS  Google Scholar 

  34. Gmelins Handbuch der anorganische Chemie, S-N4, Stickstoff. Lfg. 1, Verlag Chemie GmbH, Berlin, 1936, S. 320—344.

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Authors and Affiliations

  1. I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, 26a Akademgorodok, 184209, Apatity, Russian Federation

    S. I. Pechenyuk, D. P. Domonov & Yu. V. Ivanov

  2. All-Russia Research Institute of Aviation Materials, 17 ul. Radio, 105005, Moscow, Russian Federation

    A. A. Shimkin

Authors
  1. S. I. Pechenyuk
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  2. D. P. Domonov
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  3. A. A. Shimkin
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  4. Yu. V. Ivanov
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Correspondence to S. I. Pechenyuk.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0322—0328, February, 2015.

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Pechenyuk, S.I., Domonov, D.P., Shimkin, A.A. et al. Thermal decomposition of iron cyano complexes in an inert atmosphere. Russ Chem Bull 64, 322–328 (2015). https://doi.org/10.1007/s11172-015-0862-1

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  • DOI: https://doi.org/10.1007/s11172-015-0862-1

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