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Cationic hexamethylbenzene-diene cobalt complexes

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Abstract

Cationic complexes [(diene)Co(η-C6Me6)]+ (diene is buta-1,3-diene (2a), 5-isopropyl-2-methylcyclohexa-1,3-diene (2b), cycloocta-1,3-diene (2c), and cyclohexa-1,5-diene (2d)) were synthesized by the reaction of [Co(η-C6Me6)2]+ (1) with dienes in a CH2Cl2-Me2CO mixture. In the absence of dienes, cation 1 undergoes hydrogenation to form [(1,2,3,4,5,6-HMCD-1,3)-Co(η-C6Me6)]+ (HMCD is hexamethylcyclohexadiene, 2e). Structures [2c–e]PF6 were determined by X-ray diffraction analysis. According to the DFT calculations, the Co-C6H6 bond in the complexes with conjugated dienes is stronger than that in the complexes with nonconjugated dienes.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. A. Loginov, A. A. Pronin, Z. A. Starikova, P. V. Petrovskii & A. R. Kudinov

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  1. D. A. Loginov
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  2. A. A. Pronin
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  3. Z. A. Starikova
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  4. P. V. Petrovskii
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  5. A. R. Kudinov
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Correspondence to A. R. Kudinov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 44–49, January, 2012.

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Loginov, D.A., Pronin, A.A., Starikova, Z.A. et al. Cationic hexamethylbenzene-diene cobalt complexes. Russ Chem Bull 61, 45–50 (2012). https://doi.org/10.1007/s11172-012-0007-8

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  • DOI: https://doi.org/10.1007/s11172-012-0007-8

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