Skip to main content
SpringerLink
Log in

Equilibrium parameters of a liquid—vapor system and thermodynamic characteristics of adsorption of cyclic and cage hydrocarbons in squalane

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The thermodynamic characteristics of adsorption of adamantane molecules and its alkyl derivatives, as well as some mono- and bicyclic hydrocarbons C10H n , were studied by equilibrium gas liquid chromatography on a column packed with the stationary liquid phase squalane under the conditions of infinitely low concentrations of the sorbate in the gas phase. The influence of specific features of the molecular structure of sorbates on the regularities of their retention on the column with squalane was shown. For the first time we obtained the limiting activity coefficients and excess thermodynamic functions of mixing, which made it possible to study in detail the thermodynamics of dissolution of cage molecules in the nonpolar liquid bulk. The changes in the molar isobaric heat capacity of sorbates during adsorption were determined by the chromatographic method. For reference compounds, these values agree well with the results of direct calorimetric measurements of the change in the molar standard isobaric heat capacity during vaporization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ya. I. Yashin, E. Ya. Yashin, A. Ya. Yashin, Gazovaya khromatografiya [Gas Chromatography], TransLit, Moscow, 2009, 528 pp. (in Russian).

    Google Scholar 

  2. V. G. Berezkin, Gazo-zhidko-tverdofaznaya khromatografiya [Gas Liquid Solid-Phase Chromatography], Khimiya, Moscow, 1986, 112 pp. (in Russian).

    Google Scholar 

  3. K. Heberger, J. Chromatogr. A, 2007, 1158, 273.

    Article  CAS  Google Scholar 

  4. S. V. Blokhina, N. V. Usol’tseva, M. V. Ol’khovich, A. V. Sharapova, J. Chromatogr. A, 2008, 1215, 161.

    Article  CAS  Google Scholar 

  5. A. Heintz, S. P. Verevkin, J. K. Lehmann, T. V. Vasiltsova, D. Ondo, J. Chem. Thermodynamics, 2007, 39, 268.

    Article  CAS  Google Scholar 

  6. V. A. Davankov, Chromatographia, 2003, 57, S–195.

    Article  Google Scholar 

  7. L. A. Kartsova, O. V. Markova, Molekulyarnoe raspoznavanie v khromatografii: Ispol’zovanie makrotsiklov v sostave khromatograficheskikh faz [Molecular Recognition in Chromatography: The Use of Macrocycles in the Composition of Chromatographic Phases], Izd. SPbGU, St. Petersburg, 2004, 142 pp. (in Russian).

    Google Scholar 

  8. A. G. Morachevskii, N. A. Smirnova, I. M. Balashova, I. B. Pukinskii, Termodinamika razbavlennykh rastvorov neelektrolitov [Thermodynamics of Dilute Solutions of Nonelectrolytes], Khimiya, Leningrad, 1982, 240 pp. (in Russian).

    Google Scholar 

  9. E. I. Bagrii, T. Yu. Frid, P. I. Sanin, Neftekhimiya, 1970, 10, 480 [Petroleum Chem. (Engl. Transl.), 1970, 10].

    CAS  Google Scholar 

  10. W. S. Wingert, Fuel, 1992, 71, 37.

    Article  CAS  Google Scholar 

  11. E. I. Bagrii, A. T. Saginaev, Usp. Khim., 1983, 52, 1538 [Russ. Chem. Rev. (Engl. Transl.), 1983, 52].

    CAS  Google Scholar 

  12. V. S. Sarkisova, Ph. D. (Chem.) Thesis, SamGTU, Samara, 2000, 163 pp. (in Russian).

  13. V. S. Sarkisova, A. A. Pimerzin, Neftekhimiya, 2005, 45, 63 [Petroleum Chem. (Engl. Transl.), 2005, 45].

    CAS  Google Scholar 

  14. S. N. Yashkin, N. V. Kudasheva, Izv. Vuzov. Khim. Khim. Tekhnol. [Bulletin of Higher School. Chemistry and Chemical Technology], 2009, 52, No. 7, 48 (in Russian).

    CAS  Google Scholar 

  15. A. Roon, J. R. Parsons, H. A. J. Govers, J. Chromatogr. A, 2002, 955, 105.

    Article  Google Scholar 

  16. A. Bashir-Hashemi, J. S. Chickos, W. Hanshaw, H. Zhao, B. S. Farivar, J. F. Liebman, Thermochimica Acta, 2004, 424, 91.

    Article  CAS  Google Scholar 

  17. J. S. Chickos, D. Hesse, S. Hosseini, G. Nichols, P. Webb, Thermochimica Acta, 1998, 313, 101.

    Article  CAS  Google Scholar 

  18. J. Burkhard, J. Vais, L. Vodička, S. Landa, J. Chromatogr., 1969, 42, 207.

    Article  CAS  Google Scholar 

  19. J. Janku, M. Popl, J. Chromatogr., 1974, 89, 319.

    Article  CAS  Google Scholar 

  20. I. Ya. Grava, Ya. Yu. Polis, M. Yu. Lidak, E. E. Liepin’sh, V. D. Shatts, I. V. Dipan, M. P. Gavars, I. P. Sekatsis, Zh. Org. Khim., 1981, 17, 778 [J. Org. Chem. USSR (Engl. Transl.), 1981, 17].

    CAS  Google Scholar 

  21. L. Vodicka, J. Triska, J. Hlavaty, J. Chromatogr., 1986, 366, 382.

    Article  CAS  Google Scholar 

  22. S. V. Kurbatova, Yu. I. Arutyunov, I. K. Moiseev, S. Yu. Kudryashov, Zh. Fiz. Khim., 1998, 72, 1485 [Russ. J. Phys. Chem. (Engl. Transl.), 1998, 72].

    CAS  Google Scholar 

  23. S. N. Yashkin, Ph. D. (Chem.) Thesis, SGU, Saratov, 2000, 189 pp. (in Russian).

  24. K. K. Konstantinova, V. G. Berezkin, S. V. Kurbatova, E. E. Finkel’shtein, Zh. Prikl. Khim., 2005, 78, 1522 [Russ. J. Appl. Chem. (Engl. Transl.), 2005, 78, 1498].

    Google Scholar 

  25. C. Yang, Z. D. Wang, B. P. Hollebone, X. Peng, M. Fingas, M. Landriault, Environmental Forensics, 2006, 7, 377.

    Article  CAS  Google Scholar 

  26. I. A. Suslov, B. A. Rudenko, A. P. Arzamastsev, Zh. Anal. Khim., 1988, 43, 328 [J. Anal. Chem. USSR (Engl. Transl.), 1988, 43].

    CAS  Google Scholar 

  27. T. M. Roshchina, M. S. Shepeleva, Izv. Akad. Nauk, Ser. Khim., 2005, 140 [Russ. Chem. Bull., Int. Ed., 2005, 54, 141].

  28. A. Dallos, A. Sisak, Z. Kulcsár, E. Kováts, J. Chromatogr. A, 2000, 904, 211.

    Article  CAS  Google Scholar 

  29. N. V. Kudasheva, S. N. Yashkin, Sorbtsionnye i khromatograficheskie protsessy [Adsorption and Chromatographic Processes], 2009, 9, 725 (in Russian).

    Google Scholar 

  30. W. V. Steele, I. Watt, J. Chem. Thermodyn., 1977, 9, 843.

    Article  CAS  Google Scholar 

  31. R. C. Reid, J. M. Prausnitz, T. K. Sherwood, The Properties of Gases and Liquids, McGraw-Hill, Inc., New York, 1977.

    Google Scholar 

  32. R. M. Varushchenko, L. L. Pashchenko, A. I. Druzhinina, A. V. Abramenkov, A. A. Pimersin, J. Chem. Thermodyn., 2001, 33, 733.

    Article  CAS  Google Scholar 

  33. Vapor Pressure of Chemicals, in Landolt-Börnstein, New Series, Ed. K. R. Hall, Springer, Berlin, 1999, Group IV: Physical Chemistry, V. 20, Subvolume A, 274 pp.

  34. L. A. Onuchak, A. V. Bulanova, K. V. Egorova, Yu. I. Arutyunov, Nomenklatura v khromatografii. Osnovnye ponyatiya. Terminologiya. Termodinamicheskie kharakteristiki sorbtsionnogo protsessa [Nomenclature in Chromatography: The Main Concepts. Terminology. Thermodynamic Characteristics of the Adsorption Process], Izd-vo “Samarskii Universitet,” Samara, 1999, 35 pp. (in Russian).

    Google Scholar 

  35. W. Engewald, K. Epsch, Th. Welsch, J. Graefe, J. Chromatogr., 1976, 119, 119.

    Article  CAS  Google Scholar 

  36. M. Krejci, J. Pajurek, R. Komers, Vypocty a veliciny v sorpcni kolonove chromatografii, SNTL, Praha, 1990 (in Czech).

    Google Scholar 

  37. Q. Li, C. F. Poole, W. Kiridena, W. W. Koziol, Analyst, 2000, 125, 2180.

    Article  CAS  Google Scholar 

  38. A. Dallos, R. Kresz, Fluid Phase Equilibria, 2006, 248, 78.

    Article  CAS  Google Scholar 

  39. E. Kovats, G. Foti, A. Dallos, J. Chromatogr. A, 2004, 1046, 185.

    CAS  Google Scholar 

  40. S. Yu. Kudryashov, Author’s Abstract of Ph. D. (Chem.) Thesis, SamGU, Samara, 2000, 23 pp. (in Russian).

  41. A. N. Korol’, Nepodvizhnye fazy v gazozhidkostnoi khromatografii [Stationary Phases in Gas Liquid Chromatography], Khimiya, Moscow, 1985, p. 75 (in Russian).

    Google Scholar 

  42. S. V. Kurbatova, S. N. Yashkin, Zh. Strukt. Khim., 2000, 41, 805 [J. Struct. Chem. (Engl. Transl.), 2000, 41].

    Google Scholar 

  43. CRC Handbook of Chemistry and Physics, 90th ed., Ed. D. R. Lide, CRC Press, New York, 2009–2010.

    Google Scholar 

  44. V. Pacakova, L. Feltl, Chromatographic Retention Indices an Aid to Identification of Organic Compounds, Ellis Horwood, New York, 1992, 285 pp.

    Google Scholar 

  45. S. N. Yashkin, N. V. Kudasheva, Izv. Vuzov. Khim. Khim. Tekhnol. [Bulletin of Higher School. Chemistry and Chemical Technology], 2009, 52, No. 8, 32 (in Russian).

    CAS  Google Scholar 

  46. G. R. Vakili-Nezhaad, in Molecular Building Blocks for Nanotechnology: from Diamondoids to Nanoscale Materials and Applications, Topics in Applied Physics, Vol. 109, Eds G. A. Mansoori, T. F. George, L. Assoufid, G. Zhang, Springer, New York, 2007, p. 7.

    Google Scholar 

  47. O. V. Novoselova, Author’s Abstract of Ph. D. (Chem.) Thesis, SamGTU, Samara, 2008, 24 pp. (in Russian).

  48. W. A. Smit, A. F. Bochkov, R. Caple, Organic Synthesis. The Science Behind the Art, The Royal Society of Chemistry, Cambridge, 1998.

    Google Scholar 

  49. E. I. Bagrii, Adamantany [Adamantanes], Nauka, Moscow, 1989, 264 pp. (in Russian).

    Google Scholar 

  50. G. A. Olah, C. S. Lee, G. K. Surya Prakash, R. M. Moriarty, M. S. Chander Rao, J. Am. Chem. Soc., 1993, 115, 10728.

    Article  CAS  Google Scholar 

  51. M. L. Bagal, V. I. Lantvoev, Zh. Org. Khim., 1973, 9, 291 [J. Org. Chem. USSR (Engl. Transl.), 1973, 9].

    CAS  Google Scholar 

  52. S. N. Yashkin, D. A. Svetlov, O. V. Novoselova, E. A. Yashkina, Izv. Akad. Nauk, Ser. Khim., 2008, 2422 [Russ. Chem. Bull., Int. Ed., 2008, 57, 2472].

    Google Scholar 

  53. J. Li, P. W. Carr, J. Chromatogr. A, 1994, 670, 105.

    Article  CAS  Google Scholar 

  54. R. M. Varushchenko, A. I. Druzhinina, V. M. Senyavin, V. S. Sarkisova, J. Chem. Thermodyn., 2005, 37, 141.

    Article  CAS  Google Scholar 

  55. J. S. Chickos, W. E. Acree, J. Phys. Chem. Ref. Data, 2003, 32, 519.

    Article  CAS  Google Scholar 

  56. M. Reinhard, A. Drefahl, Estimating Physicochemical Properties of Organic Compounds, John Wiley and Sons, Inc., New York, 1999, 238 pp.

    Google Scholar 

  57. K. G. Joback, R. C. Reid, Chem. Eng. Commun., 1987, 57, 233.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Samara State Technical University, 244 ul. Molodogvardeiskaya, 443100, Samara, Russian Federation

    S. N. Yashkin

Authors
  1. S. N. Yashkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. N. Yashkin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1974–1986, November, 2010.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yashkin, S.N. Equilibrium parameters of a liquid—vapor system and thermodynamic characteristics of adsorption of cyclic and cage hydrocarbons in squalane. Russ Chem Bull 59, 2026–2038 (2010). https://doi.org/10.1007/s11172-010-0351-5

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-010-0351-5

Key words

Search

Navigation