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Aggregation and catalytic activity of 2-hydroxybenzylated polyethyleneimines in water-organic solutions

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Abstract

The aggregation of 2-hydroxybenzylated derivatives of polyethyleneimine in a water—DMF medium in the absence and in the presence of cationic surfactants was studied. The catalytic activity of modified polyethyleneimines in hydrolysis of phosphorus acid esters depends on the pH of the medium and increases with the formation of polymer-colloidal complexes. The polymer-colloidal complexes based on surfactants with two hydroxyethyl substituents in the head group have the maximum catalytic activity (increase in the reaction rate by up to three orders of magnitude).

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References

  1. L. Ya. Zakharova, A. B. Mirgorodskaya, E. P. Zhil’tsova, L. A. Kudryavtseva, A. I. Konovalov, Izv. Akad. Nauk, Ser. Khim., 2004, 1331 [Russ. Chem. Bull., Int. Ed., 2004, 53, 1385].

  2. E. P. Tishkova, L. A. Kudryavtseva, Izv. Akad. Nauk, Ser. Khim., 1996, 298 [Russ. Chem. Bull. (Engl. Transl.), 1996, 45, 284].

  3. T. Dwars, E. Paetzold, G. Oehme, Angew. Chem., 2005, 44, 7174.

    Article  CAS  Google Scholar 

  4. L. Ya. Zakharova, F. G. Valeeva, A. R. Ibragimova, L. A. Kudryavtseva, Zh. Fiz. Khim., 2002, au]76, 2042 [Russ. J. Phys. Chem. (Engl. Transl.), 2002, 76].

  5. C. A. Bunton, S. Wright, Langmuir, 1993, 9, 117.

    Article  CAS  Google Scholar 

  6. K. Holmberg, B. JÖnsson, B. Kronberg, B. Lindman, Surfactants and Polymers in Aqueous Solution, John Wiley and Sons, Ltd, 2003.

  7. P. A. Gembitskii, D. S. Zhuk, V. A. Kargin, Polietile-nimin [Polyethyleneimine], Nauka, Moscow, 1971, 204 pp. (in Russian).

    Google Scholar 

  8. Y. Jianguo, W. Lin, V. Otieno-Alego, D. P. Schweinsberg, Corros. Sci., 1995, 37, 975.

    Article  CAS  Google Scholar 

  9. V. E. Sladkov, E. A. Osipova, Zh. Anal. Khim., 2001, 56, 52 [J. Anal. Chem. (Engl. Transl.), 2001, 56, 43].

    Google Scholar 

  10. C. L. Densmore, F. M. Orson, B. Xu, B. M. Kinsey, J. C. Waldrep, P. Hua, B. Bhogal, V. Knight, Mol. Therapy, 2000, 1, 180.

    Article  CAS  Google Scholar 

  11. V. V. Lapin, T. I. Misyutina, B. I. Sokolova, V. M. Drobo-syuk, N. P. Shpenzer, S. L. Talmud, Zh. Prikl. Khim., 1979, 52, 226 [J. Appl. Chem. USSR (Engl. Transl.), 1979, 52].

  12. E. M. Kosacheva, D. B. Kudryavtsev, R. F. Bakeeva, A. I. Kuklin, A. Kh. Islamov, L. A. Kudryavtseva, V. F. Sopin, A. I. Konovalov, Kolloid. Zh., 2006, 68, 784 [Colloid J. (Engl. Transl.), 2006, 68, 713].

    Google Scholar 

  13. L. Ya. Zakharova, F. G. Valeeva, D. B. Kudryavtsev, A. V. Bilalov, A. Ya. Tret’yakova, L. A. Kudryavtseva, A. I. Kono-valov, V. P. Barabanov, Izv. Akad. Nauk, Ser. Khim., 2005, 630 [Russ. Chem. Bull., Int. Ed., 2005, 54, 641].

    Google Scholar 

  14. M. A. Winnik, S. M. Bystryak, C. Chassenieux, Langmuir, 2000, 16, 4495.

    Article  CAS  Google Scholar 

  15. R. Meszaros, L. Thompson, M. Bos, I. Varga, T. Gilanyi, Langmuir, 2003, 19, 609.

    Article  CAS  Google Scholar 

  16. H. Wang, Y. Wang, H. Yan, Langmuir, 2006, 22, 1526.

    Article  CAS  Google Scholar 

  17. S. M. Bystryak, M. A. Winnik, Langmuir, 1999, 15, 3748.

    Article  CAS  Google Scholar 

  18. B. M. D. O’Driscoll, E. Milson, C. Fernandez-Martin, L. White, S. J. Roser, K. J. Edler, Macromolecules, 2005, 38, 8785.

    Article  Google Scholar 

  19. L. Ya. Zakharova, F. G. Valeeva, D. B. Kudryavtsev, A. R. Ibragimova, L. A. Kudryavtseva, A. P. Timosheva, V. E. Kataev, Kinet. Katal., 2003, 44, 599 [Kinet. Catal. (Engl. Transl.), 2003, 44, 547].

    Article  Google Scholar 

  20. D. B. Kudryavtsev, R. F. Bakeeva, L. A. Kudryavtseva, L. Ya. Zakharova, V. F. Sopin, Izv. Akad. Nauk, Ser. Khim., 2000, 1510 [Russ. Chem. Bull., Int. Ed., 2000, 49, 1501].

  21. S. S. Lukashenko, A. V. Yurina, T. N. Pashirova, D. B. Kudryavtsev, E. M. Kosacheva, L. A. Kudryavtseva, A. I. Konovalov, Kolloid. Zh., 2008, 70, 351 [Colloid J. (Engl. Transl.), 2008, 70, 317].

    Google Scholar 

  22. V. S. Pshezhetskii, G. A. Murtazaeva, V. A. Kabanov, in Sintez, svoistva i prakticheskoe ispol’zovanie polietilenimina [Synthesis, Properties, and Practical Use of Polyethyleneimine], INKhS, Moscow, 1974, 100 (in Russian).

    Google Scholar 

  23. F. Avenier, J. B. Domingos, L. D. Van Vliet, F. Hollfelder, J. Am. Chem. Soc., 2007, 129, 7611.

    Article  CAS  Google Scholar 

  24. W. P. Jencks, Catalysis in Chemistry and Enzymology, McGraw-Hill, New York-St. Louis-San Francisco-Lon don-Sidney-Toronto-Mexico-Panama, 1969.

  25. V. E. Bel’skii, L. S. Novikova, L. A. Kudryavtseva, B. E. Ivanov, Zh. Obshch. Khim., 1978, 48, 1512 [J. Gen. Chem. USSR (Engl. Transl.), 1978, 48].

    Google Scholar 

  26. M. J. Minch, S.-S. Chen, R. Peters, J. Org. Chem., 1978, 43, 31.

    Article  CAS  Google Scholar 

  27. C. A. Bunton, L. G. Ionescu, J. Am. Chem. Soc., 1973, 95, 2912.

    Google Scholar 

  28. J. H. Fendler, E. J. Fendler, Catalysis in Micellar and Macromolecular Systems, Acad. Press, New York-San Fran-cisko-London, 1975, 545 pp.

    Google Scholar 

  29. I. V. Berezin, K. Martinek, A. K. Yatsimirskii, Usp. Khim., 1973, 42, 1729 [Russ. Chem. Rev. (Engl. Transl.), 1973, 42, 1343].

    CAS  Google Scholar 

  30. G. A. Gainanova, E. P. Zhil’tsova, L. A. Kudryavtseva, S. S. Lukashenko, A. P. Timosheva, A. R. Burilov, I. R. Knyaze-va, A. I. Konovalov, Zh. Obshch. Khim., 2006, 76, 1871 [Russ. J. Gen. Chem. (Engl. Transl.), 2006, 76, 1788].

    Google Scholar 

  31. T. N. Pashirova, S. S. Lukashenko, E. M. Kosacheva, L. Z. Rizvanova, G. A. Gainanova, I. R. Knyazeva, A. R. Burilov, L. A. Kudryavtseva, A. I. Konovalov, Izv. Akad. Nauk, Ser. Khim., 2007, 924 [Russ. Chem. Bull., Int. Ed., 2007, 56, 959].

    Google Scholar 

  32. R. F. Bakeeva, L. A. Kudryavtseva, V. E. Bel’skii, B. E. Ivanov, Zh. Obshch. Khim., 1983, 53, 1058 [J. Gen. Chem. USSR (Engl. Transl.), 1983, 53].

    CAS  Google Scholar 

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    G. A. Gaynanova, A. V. Yurina, S. S. Lukashenko, E. P. Zhil’tsova, L. Ya. Zakharova, L. A. Kudryavtseva & A. I. Konovalov

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  1. G. A. Gaynanova
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  2. A. V. Yurina
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  3. S. S. Lukashenko
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  4. E. P. Zhil’tsova
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  5. L. Ya. Zakharova
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  6. L. A. Kudryavtseva
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  7. A. I. Konovalov
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Correspondence to G. A. Gaynanova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1306–1312, July, 2010.

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Gaynanova, G.A., Yurina, A.V., Lukashenko, S.S. et al. Aggregation and catalytic activity of 2-hydroxybenzylated polyethyleneimines in water-organic solutions. Russ Chem Bull 59, 1336–1342 (2010). https://doi.org/10.1007/s11172-010-0243-8

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  • DOI: https://doi.org/10.1007/s11172-010-0243-8

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