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Synthesis and crystal structures of PrIII and NdIII complexes with the macrocyclic cavitand cucurbit[6]uril

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Abstract

The [{Pr(NO3)2(H2O)3}{Pr(NO3)(H2O)4} (C36H36N24O12)](NO3)3·4H2O and [{Nd(NO3)(H2O)4} 2(NO3@C36H36N24O12)][Nd(NO3)6] complexes were prepared by heating a mixture of lanthanide nitrates, cucurbit[6]uril, and water in a sealed tube. X-ray diffraction study demonstrated that the metal atoms in the former complex are linked to the macrocycle through tridentate coordination of the portal oxygen atoms of cucurbit[6]uril to the praseodymium(III) cation. The neodymium(III) complex is the first example of lanthanide compounds with cucurbit[6]uril belonging to coordination polymers.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    E. A. Mainicheva, A. A. Tripolskaya, O. A. Gerasko, D. Yu. Naumov & V. P. Fedin

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  1. E. A. Mainicheva
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  2. A. A. Tripolskaya
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  3. O. A. Gerasko
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  4. D. Yu. Naumov
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  5. V. P. Fedin
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1511–1517, September, 2006.

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Mainicheva, E.A., Tripolskaya, A.A., Gerasko, O.A. et al. Synthesis and crystal structures of PrIII and NdIII complexes with the macrocyclic cavitand cucurbit[6]uril. Russ Chem Bull 55, 1566–1573 (2006). https://doi.org/10.1007/s11172-006-0455-0

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  • DOI: https://doi.org/10.1007/s11172-006-0455-0

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