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Synthesis and photoelectric property of N-confused porphyrins bearing an ethynylbenzoic and benzoic acid moiety

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Abstract

Two novel π-enlarged palladium N-confused porphyrins (Pd-NCPs) containing benzoic acid or 4-ethynylbenzoic acid moiety were synthesized by dibromination, silver metallation, Pd-catalyzed cross-coupling, and hydrolysis reaction. All compounds were characterized by 1H-NMR and mass spectra. Optical and electrochemical properties were also obtained. The photovoltaic properties of these π-enlarged Pd-NCPs were examined and the sensitizers achieved low efficiency, which was well explained by quantum chemistry calculation.

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Acknowledgements

This work was supported by the Research Foundation of Yichang Science and Technology Bureau (No. A16-302-a03) and Startup Foundation from China Three Gorges University (No. 20154406, 20154407). We gratefully acknowledge Prof. Hiroyuki Furuta for chemical synthesis and DFT calculation.

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    Authors and Affiliations

    1. College of Materials and Chemical Engineering and Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, 443002, Hubei, People’s Republic of China

      Nuonuo Zhang, Jiaqi Chen, Kai Cheng, Yujiao Li, Long Wang, Kaibo Zheng, Qingqing Yang, Dejiang Li & Jiaying Yan

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    1. Nuonuo Zhang
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    2. Jiaqi Chen
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    3. Kai Cheng
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    Correspondence to Jiaying Yan.

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    Nuonuo Zhang and Jiaqi Chen have contributed equally.

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    Zhang, N., Chen, J., Cheng, K. et al. Synthesis and photoelectric property of N-confused porphyrins bearing an ethynylbenzoic and benzoic acid moiety. Res Chem Intermed 43, 2921–2929 (2017). https://doi.org/10.1007/s11164-016-2803-5

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