Skip to main content
SpringerLink
Log in

Magnetite-coated metal foams as one-body catalysts for Fenton-like reactions

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The possibility of preparing one-body catalyst was investigated for heterogeneous Fenton-like reactions by coating magnetite powder on metal foams. Up to 10 wt% magnetite could be coated onto metal foams with strong enough adhesion. The catalytic efficiency of the catalyst was investigated using a model reaction of methylene blue degradation at a circumneutral pH using H2O2 as the source of OH radicals and oxalic acid as the chelating agent. Comparison with conventional magnetite powder indicated that the catalytic efficiency of magnetite-coated metal foam was better than that of the powder only due to a larger exposed surface area. After treatment, separation of the one-body catalyst was easier and cleaner than that of conventional magnetite powder catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. K. Rusevova, F.-D. Kopinke, A. Georgi, J. Hazard. Mater. 241–242, 433–440 (2012)

    Article  Google Scholar 

  2. E. Neyens, J. Baeyens, J. Hazard. Mater. 98, 33–50 (2003)

    Article  CAS  Google Scholar 

  3. S. Chou, C. Huang, Chemosphere 38, 2719–2731 (1999)

    Article  CAS  Google Scholar 

  4. M.C. Pereira, L.C.A. Oliveira, E. Murad, Clay Miner. 47, 285–302 (2012)

    Article  CAS  Google Scholar 

  5. J. Chun, H. Lee, S.-H. Lee, S.-W. Hong, J. Lee, C. Lee, J. Lee, Chemosphere 89, 1230–1237 (2012)

    Article  CAS  Google Scholar 

  6. W.P. Kwan, B.M. Voelker, Environ. Sci. Technol. 37, 1150–1158 (2003)

    Article  CAS  Google Scholar 

  7. A. Dhakshinamoorthy, S. Navalon, M. Alvaro, H. Garcia, ChemSusChem 5, 46–64 (2012)

    Article  CAS  Google Scholar 

  8. D.H. Kim, B.Y. Yu, P.R. Cha, W.Y. Yoon, J.Y. Byun, S.H. Kim, Surf, Coat. Technol. 209, 169–176 (2012)

  9. M. Klokkenburg, B.H. Erné, A. Wiedenmann, A.V. Petukhov, A.P. Philipse, Phys. Rev. E 75, 051408 (2007)

    Article  CAS  Google Scholar 

  10. X. Xue, K. Hanna, C. Despas, F. Wu, N. Deng, J. Mol. Catal. A: Chem. 311, 29–35 (2009)

    Article  CAS  Google Scholar 

  11. S. Wang, Dyes Pigm. 76, 714–720 (2008)

    Article  CAS  Google Scholar 

  12. L. Xu, J. Wang, Appl. Cataly. B Environ. 123–124, 117–126 (2012)

    Article  Google Scholar 

  13. S. Rahim Pouran, A.A. Abdul Raman, W.M.A. Wan Daud, J. Clean. Prod. 64, 24–35 (2014)

    Article  Google Scholar 

  14. Y.C. Li, L.G. Bachas, D. Bhattacharyya, Environ. Eng. Sci. 22, 756–771 (2005)

    Article  CAS  Google Scholar 

  15. A. Romero, A. Santos, F. Vicente, J. Hazard. Mater. 162, 785–790 (2009)

    Article  Google Scholar 

  16. M.A. Blesa, E.B. Borghi, A.J.G. Maroto, A.E. Regazzoni, J. Colloid Interface Sci. 98, 295–305 (1984)

    CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the KIST–UNIST partnership program (UNIST 2.140442.01) and by a grant from the future program of KIST (2E25371).

Author information

Authors and Affiliations

  1. Center for Materials Architecturing, Korea Institute of Science and Technology, Seoul, 136-791, Korea

    Thi May Do, Ji Young Byun & Sang Hoon Kim

  2. Department of Nanomaterials Science and Engineering, University of Science and Technology, Daejeon, 305-350, Korea

    Thi May Do & Sang Hoon Kim

Authors
  1. Thi May Do
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ji Young Byun
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sang Hoon Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sang Hoon Kim.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Do, T.M., Byun, J.Y. & Kim, S.H. Magnetite-coated metal foams as one-body catalysts for Fenton-like reactions. Res Chem Intermed 43, 3481–3492 (2017). https://doi.org/10.1007/s11164-016-2440-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-016-2440-z

Keywords

Search

Navigation