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Antioxidant activity and effect of quince pulp extract on the corrosion of C-steel in 1M HCl

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Abstract

The inhibition effect of quince pulp extract (QPE) on the adsorption and corrosion of carbon steel in 1M HCl solution was investigated using the weight loss method, potentiodynamic polarization and impedance spectroscopy measurements. At first, the quince extract was characterized, its polyphenolic content was qualitatively and quantitatively determined and its anti-oxidant activity was assessed. The HPLC–DAD–MS showed that the quince extract contained a high quantity of polyphenols with the main compounds being neochlorogenic acid, rutin and chlorogenic acid (7.68, 9.05 and 18.57 mg/g fw, respectively), which represent together about 84 % of total phenolics. The extract exhibited a strong antioxidant potential as it inhibited 87 % of the DPPH· anionic radical. The polarization measurements indicate that the extract acts as a mixed inhibitor. The values of inhibition efficiency increase with inhibitor concentration reaching a maximum value (88 %) at 5 × 10−1 g/L. The presence of QPE enhances the values of R t and reduces the C dl values. The adsorption of QPE under consideration on a steel/acidic solution interface at all temperatures follows the Langmuir adsorption isotherm. The QPE inhibitor efficiency was temperature-independent.

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Authors and Affiliations

  1. LIP-MB, INSAT, University of Carthage, Tunis, Tunisia

    Tesnime Ghazouani, Emna Meddeb & Sami Fattouch

  2. Laboratory of Environmental Engineering and Biotechnology, ENSA, Université IBN ZOHR, PO Box 1136, 80000, Agadir, Morocco

    Dris Ben Hmamou, Rachid Salghi & Houceine Bouya

  3. Department of Biology, Faculty of Sciences, Saïda University, Saida, Algeria

    Omar Benali

  4. LCAE-URAC 18, Faculty of Science, University of Mohammed Premier, PO Box 717, 60000, Oujda, Morocco

    Belkheir Hammouti

Authors
  1. Tesnime Ghazouani
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  2. Dris Ben Hmamou
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  3. Emna Meddeb
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  4. Rachid Salghi
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  5. Omar Benali
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  6. Houceine Bouya
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  7. Belkheir Hammouti
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  8. Sami Fattouch
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Correspondence to Rachid Salghi or Sami Fattouch.

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Ghazouani, T., Ben Hmamou, D., Meddeb, E. et al. Antioxidant activity and effect of quince pulp extract on the corrosion of C-steel in 1M HCl. Res Chem Intermed 41, 7463–7480 (2015). https://doi.org/10.1007/s11164-014-1837-9

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  • DOI: https://doi.org/10.1007/s11164-014-1837-9

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