Abstract
Copper manganese mixed oxides were prepared by a hydrolysis-coprecipitation method using tetramethyl ammonium hydroxide and calcined at 573–873 K. The effect of aging treatment after the coprecipitation process on the catalytic properties of the calcined mixed oxides for CO oxidation was investigated. XRD and EXAFS studies showed that spinel phases were mainly formed in the aged catalysts and the degree of disorder in the Cu–Mn spinel oxide phases increased. The aging treatment suppressed the formation of crystallites of mixed oxides, but the treatment promoted the crystallization of impurity CuO phase. The aged catalyst exhibited higher activity for CO oxidation than the unaged catalysts. The optimum calcination temperature for obtaining the highest activity was changed by aging treatment. Refluxing during the aging treatment led to the detrimental effect on the CO oxidation activities.
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Zafiris GS, Gorte RJ (1993) J Catal 140:418
Chen H, Tong X, Li Y (2009) Appl Catal A 370:59
Li WB, Chu WB, Zhuang M, Hua J (2004) Catal Today 93–95:205
Morales MR, Barbero BP, Cadús LE (2008) Fuel 87:1177
Njagi EC, Genuino HC, King’ondu CK, Dharmarathna S, Suib SL (2012) Appl Catal A 421–422:154
Kondrat SA, Davies TE, Zu Z, Boldrin P, Bartley JK, Carley AF, Taylor SH, Rosseinsky MJ, Hutchings GJ (2011) J Catal 281:279
Mirzaei AA, Shaterian HR, Joyner RW, Stockenhuber M, Taylor SH, Hutchings GJ (2003) Catal Commun 4:17
Clarke TJ, Davies TE, Kondart SA, Taylor SH (2015) Appl Catal B 165:222
Njagi EC, Genuino HC, King’ondu CK, Chen C-H, Horvath D, Suib SL (2011) Int J Hydrog Energy 36:6768
Cai L-N, Guo Y, Lu A-H, Branton P, Li WC (2012) J Mol Catal A 360:35
Hasegawa Y, Fukumoto K, Ishima T, Yamamoto H, Sano M, Miyake T (2009) Appl Catal B 89:420
Rogers TH, Piggot CS, Bahlke WH, Jennings JM (1921) J Am Chem Soc 43:1973
Veprek S, Cocke DL, Kehl S, Oswald HR (1986) J Catal 100:250
Porta P, Moretti G, Jacono ML, Musicanti M, Nardella A (1991) J Mater Chem 1:129
Tang Z-R, Jones CD, Aldridge JKW, Davies TE, Bartley JK, Carley AF, Taylor SH, Allix M, Dickinson C, Rosseinsky MJ, Claridge JB, Xu Z, Crudace MJ, Hutchings GJ (2009) Chem Cat Chem 1:247
Hosseini SA, Niaei A, Salari D, Alvarez-Galvan MC, Fierro JLG (2014) Ceram Int 40:6157
Njagi EC, Chen C-H, Genuino H, Galindo H, Huang H, Suib SL (2010) Appl Catal B 99:103
Hutchings GJ, Mirzaei AA, Joyner RW, Siddiqui MRH, Taylor SH (1996) Catal Lett 42:21
Hutchings GJ, Mirzaei AA, Joyner RW, Siddiqui MRH, Taylor SH (1998) Appl Catal A 166:143
Jones C, Cole KJ, Taylor SH, Crudace MJ, Hutchings GJ (2009) J Mol Catal A 305:121
Porta P, Moretti G, Musicanti M, Nardella A (1993) Solid State Ion 63–65:257
Einaga H, Kiya A, Yoshioka S, Teraoka Y (2014) Catal Sci Technol 4:3713
Koningsberger DC (1993) Jpn J Appl Phys Suppl 32–2:8
Ankudinov AL, Ravel B, Rehr JJ, Conradson SD (1998) Phys Rev B 58:7565
Ressler T, Brock SL, Wong J, Suib SL (1993) J Phys Chem B 103:6407
Ressler T, Wong J, Roots J, Smith IL (2000) Environ Sci Technol 34:950
Pauly N, Tougaard S, Yubero F (2014) Surf Sci 620:17
Ghijsen J, Tjeng LH, van Elp J, Eskes H, Westerink J, Sawatzky GA (1988) Phys Rev B 38:11322
Svintsitskiy DA, Chupakhin AP, Slavinskaya EM, Stonkus OA, Stadnichenko AI, Koscheev SV, Boronin AI (2013) J Mol Catal A: Chem 368:95
Chuah GK, Jaenicke S, Cheong SA, Chan KS (1996) Appl Catal A 145:267–284
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This study was financially supported by New Energy and Industrial Technology Development Organization.
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Einaga, H., Kiya, A. Effect of aging on the CO oxidation properties of copper manganese oxides prepared by hydrolysis–coprecipitation using tetramethyl ammonium hydroxide. Reac Kinet Mech Cat 117, 521–536 (2016). https://doi.org/10.1007/s11144-016-0974-0
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DOI: https://doi.org/10.1007/s11144-016-0974-0