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Intraannual and long-term variations of the carbonate system of the aerobic zone in the black sea

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Physical Oceanography

We provide an expert quality assessment of the data for 1932–1993 and used these data to perform the numerical analysis of the carbonate system of the aerobic zone in the Black Sea. The intraannual and long-term variations of the carbonate system are studied in the abyssal part of the sea for 1960–1993. We propose explanations of the intraannual variations of the analyzed system for various layers of the aerobic zone and reveal long-term variations of the pH values, total alkalinity, and the ratios of the components of the carbonate system. We discover and explain the observed increase in the concentrations of TCO2 and CO2 and the partial pressure of carbon dioxide pCO2, as well as a decrease in pH values and the concentration of CO 2−3 in waters of the aerobic zone of the Black Sea.

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References

  1. R. A. Horne, Marine Chemistry, Wiley-Interscience, New York (1969).

    Google Scholar 

  2. R.E. Zeebe and D. Wolf-Gladrow, CO 2 in Seawater: Equilibrium, Kinetics, Isotopes, Elsevier, Amsterdam (2001).

    Google Scholar 

  3. V. A. Zhorov, T. N. Abakumova, E. E. Sovga, and S. V. Lyashenko, “On the exchange of CO2 between the sea and the atmosphere in some regions of the Black Sea,” Okeanologiya, 21, Issue 1, 55–62 (1981).

    Google Scholar 

  4. V. A. Zhorov, S. G. Boguslavskii, and T. N. Abakumova, “Free carbonic acid in the Black Sea during the period of warming of waters,” Okeanologiya, 21, Issue 3, 456–463 (1981).

    Google Scholar 

  5. C. Goyet, A. L. Bradshaw, and P. G. Brewer, “The carbonate system in the Black Sea,” Deep-Sea Res., 38, No. 2, 1049–1067 (1991).

    Article  Google Scholar 

  6. P. N. Makkaveev and P. V. Bubnov, “Specific features of the vertical distribution of components of the carbonate system in the aerobic zone of the Black Sea,” Okeanologiya, 33, No. 3, 354–359 (1993).

    Google Scholar 

  7. P. N. Makkaveev, Yu. R. Nalbandov, and E. S. Vlasova, “The distribution of dissolved inorganic carbon in the zone of contact of aerobic and anaerobic waters of the Black Sea,” Oceanology, 45, No. 1, S85–S92 (2005).

    Google Scholar 

  8. W.T. Hiscock and F.J. Millero, “Alkalinity of anoxic waters in the Western Black Sea,” Deep-Sea Res., 53, 1787–1801 (2006).

    Article  Google Scholar 

  9. A. Poisson, F. Culkin, and P. Ridout, “Intercomparison of CO2 measurement,” Deep-Sea Res., 37, No. 10, 1647–1650 (1990).

    Article  Google Scholar 

  10. UNESCO Technical Papers in Marine Science. No. 51. Thermodynamics of the Carbon Dioxide System in Seawater, UNESCO, New York (1987), pp. 3–21.

  11. F.J. Millero, Chemical Oceanography, CRC Press, Boca Raton, Fl, (1996).

    Google Scholar 

  12. http://www.ocean.ru/content/57/51/.

  13. O. A. Alekin and Yu. I. Lyakhin, Chemistry of the Ocean [in Russian], Gidrometeoizdat, Leningrad (1984).

    Google Scholar 

  14. M. E. Vinogradov and Yu. R. Nalbandov, “Influence of the variations of density of water on the distributions of physical, chemical, and biological characteristics of the ecosystem of pelagic zone in the Black Sea,” Okeanologiya, 30, No. 5, 769–777 (1990).

    Google Scholar 

  15. Yu. I. Lyakhin, V. P. Aleksandrov, and N. I. Pal’shin, “Analysis of the balance of exchange with CO2 between the ocean and the atmosphere over the water areas of the Atlantic, Indian, and Pacific Oceans,” in: Investigation and Development of the World Ocean [in Russian], Issue 65, Leningrad Hydrometeorological Institute, Leningrad (1978), pp. 48–60.

  16. F. E. Gernot, W. T. Hiscock, G. W., Luther, S. K. Konovalov, et al. “Detailed measurements of carbon dioxide distributions in the Black Sea: indication of horizontal mixing and unexpected surface layer carbon deficit,” in: Abstr. of the Second Internat. Conf. “Oceanography of the Eastern Mediterranean and Black Sea. Similarities and Differences of two Interconnected Basins,” Ankara (2002), p. 310.

  17. E. A. Kuftarkova, “Seasonal carbonate cycle of variations of the components of the carbonate system in the Sevastopol Bay,” Ékol. Morya, Issue 1, 41–47 (1980).

    Google Scholar 

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Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 42–57, November–December, 2010.

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Moiseenko, O.G., Konovalov, S.K. & Kozlovskaya, O.N. Intraannual and long-term variations of the carbonate system of the aerobic zone in the black sea. Phys Oceanogr 20, 435–450 (2011). https://doi.org/10.1007/s11110-011-9097-3

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