Abstract
A plasma-initiated degenerative transfer (DT) graft polymerization (PDTGP) was carried out on the surface of porous polypropylene membrane, with acrylic acid as monomer and iodoform as transfer agent. The polymerization rate was found to increase linearly with time. Well-defined poly(acrylic acid), with a narrow polydispersity (1.31), were obtained. Less solvent effect was observed in the PDTGP, whereas stronger solvent occurred in the plasma-initiated polymerization without iodoform. It was speculated that the unconventional radical induced by plasma should behave similarly in forming the dormant species as the conventional radical did. The polymerization is proposed to undergo via a DT mechanism. For modified membranes, graft amounts were indicated to increase linearly with conversions, i.e., proportional to molecular weights of graft chains. The PDTGP was proved a desirable method for controlling pore sizes of porous membranes.
Similar content being viewed by others
References
Matyjaszewski K, Patten TE, Xia J (1997) J Am Chem Soc 119:674–680
Long S, Wan F, Yang W (2013) J Appl Polym Sci 128:2687–2693
Matyjaszewski K, Tsarevsky NV (2009) Nat Chem 1:276–288
Convertine AJ, Ayres N, Scales CW, Lowe AB, McCormick CL (2004) Biomacromolecules 5:1177–1180
Iovu MC, Matyjaszewski K (2003) Macromolecules 36:9346–9354
Nicolas J, Guillaneuf Y, Lefay C, Bertin D, Gigmes D, Charleux B (2013) Prog Polym Sci 38:63–235
Krishnan R, Srinivasan KSV (2004) Macromolecules 37:3614–3622
Liu X, Zhang G, Li B, Bai Y, Pan D, Li Y (2008) Eur Polym J 44:1200–1208
Tonnar J, Pouget E, Lacroix-Desmazes P, Boutevin B (2008) Eur Polym J 44:318–328
Gaynor SG, Wang JS, Matyjaszewski K (1995) Macromolecules 28:8051–8056
Matyjaszewski K, Gaynor S, Wang JS (1995) Macromolecules 28:2093–2095
Borkar S, Sen A (2005) J Polym Sci, Part A: Polym Chem 43:3728–3736
Gu J, Yan X, Fu Z, Yang W, Shi Y (2013) J Appl Polym Sci 128:2291–2296
Li B, Shi Y, Zhu W, Fu Z, Yang W (2006) Polym J 38:387–394
Li B, Shi Y, Fu Z, Yang W, Jiao S (2007) Chin J Polym Sci 25:609–619
Pyun J, Matyjaszewski K (2001) Chem Mater 13:3436–3448
You Y, Hong C, Bai R, Pan C, Wang J (2002) Macromol Chem Phys 203:477–483
Ran R, Yu Y, Wan T (2007) J Appl Polym Sci 105:398–404
Zhou G, Ma Y (2008) Chem Lett 37:850–851
Quinn JF, Barner L, Rizzardo E, Davis TP (2002) J Polym Sci, Part A: Polym Chem 40:19–25
Chen G, Zhu X, Zhu J, Cheng Z (2004) Macromol Rapid Commun 25:818–824
Nabifar A, McManus NT, Vivaldo-Lima E, Lona LMF, Penlidis A (2009) Chem Eng Sci 64:304–312
Zhang Z, Zhu X, Zhu J, Cheng Z, Zhu S (2006) J Polym Sci, Part A: Polym Chem 44:3343–3354
Simionescu BC, Natansohn A, Simionescu CI (1980) Polym Bull 2:809–815
Simionescu CI, Simionescu BC (1984) Pure Appl Chem 56:427–438
Johnson DR, Osada Y, Bell AT, Shen M (1981) Macromolecules 14:118–124
Osada Y, Mizumoto A (1985) Macromolecules 18:302–304
Osada Y, Takase M, Iriyama Y (1983) Polym J 15:81–86
Kuzuya M, Kamiya K, Kawaguchi T, Okuda T (1983) J Polym Sci: Polym Lett Ed 21:509–514
Huang J, Wang X, Chen X, Yu X (2003) J Appl Polym Sci 89:3180–3187
Simionescu CI, Simionescu B, Leanca M, Ananiescu C (1981) Polym Bull 5:61–66
Osada Y, Iriyama Y (1982) J Am Chem Soc 104:2925–2926
Yin S, Ren L, Wang Y (2013) Plasma Sci Technol 15:1041–1046
Lee YM, Shim JK (1997) Polymer 38:1227–1232
Yamaguchi T, Nakao SI, Kimura S (1996) J Polym Sci Polym Chem 34:1203–1208
Wavhal DS, Fisher ER (2002) J Membr Sci 209:255–269
Paul CW, Bell AT, Soong DS (1985) Macromolecules 18:2318–2321
Yoshikawa C, Goto A, Tsujii Y, Fukuda T, Yamamoto K, Kishida A (2005) Macromolecules 38:4604–4610
Acknowledgments
This work was supported by the National Basic Research Program of China (2009CB623404) and the National Natural Science Foundation of China (20476045).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shi, S., Zhou, Y., Lu, X. et al. Plasma-Initiated DT Graft Polymerization of Acrylic Acid on Surface of Porous Polypropylene Membrane for Pore Size Control. Plasma Chem Plasma Process 34, 1257–1269 (2014). https://doi.org/10.1007/s11090-014-9572-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11090-014-9572-y