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Uniform, luminescent Eu:LuF3 nanoparticles

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Abstract

A simple procedure for the synthesis of orthorhombic, uniform, LuF3 particles with two different morphologies (rhombus- and cocoon-like) and nanometer and sub-micrometer size, respectively, is reported. The method consists in the aging, at 120 °C for 2 h, a solution containing [BMIM]BF4 ionic liquid (0.5 mL) and lutetium acetate (in the case of the rhombi) or lutetium nitrate (in the case of the cocoons) (0.02 M) in ethylene glycol (total volume 10 mL). This synthesis method was also adequate for the synthesis of Eu3+-doped LuF3 particles of both morphologies, whose luminescence properties were investigated in detail. The experimental observations reported herein suggest that these materials are suitable phosphors for optoelectronic as well as in vitro biotechnological applications.

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References

  • Blasse G, Grabmaier BC (1994) Luminescent materials. Springer, Berlin

    Book  Google Scholar 

  • Carniato F, Thangavel K, Tei L, Botta M (2013) Structure and dynamics of the hydration shells of citrate-coated GdF3 nanoparticles. J Mater Chem B 1:2442–2446

    Article  Google Scholar 

  • Cui Y, Fan X, Hong Z, Wang M (2006) Synthesis and luminescence properties of lanthanide (III)-doped YF3 nanoparticles. J Nanosci Nanotechnol 6:830–836

    Article  Google Scholar 

  • Diamente PR, Raudsepp M, van Veggel FCJM (2007) Dispersible Tm3+-doped nanoparticles that exhibit strong 1.47 μm photoluminescence. Adv Funct Mater 17:363–368

    Article  Google Scholar 

  • Downing E, Hesselink L, Ralston J, Macfarlane R (1996) A three-color, solid-state, three-dimensional display. Science 273:1185–1189

    Article  Google Scholar 

  • Feldmann C (2003) Polyol-mediated synthesis of nanoscale functional materials. Adv Funct Mater 13:101–107

    Article  Google Scholar 

  • Jacob DS, Bitton L, Grinblat J, Felner I, Koltypin Y, Gedanken A (2006) Are ionic liquids really a boon for the synthesis of inorganic materials? a general method for the fabrication of nanosized metal fluorides. Chem Mater 18:3162–3168

    Article  Google Scholar 

  • Kiran N (2014) Eu3 + ion doped sodium-lead borophosphate glasses for red light emission. J Mol Struct 93:1065–1066

    Google Scholar 

  • Li C, Yang J, Yang P, Lian H, Lin J (2008a) Hydrothermal synthesis of lanthanide fluorides LnF3 (Ln = La to Lu) nano-/microcrystals with multiform structures and morphologies. Chem Mater 20:4317–4326

    Article  Google Scholar 

  • Li C, Quan Z, Yang P, Huang S, Lian H, Lin J (2008b) Shape-controllable synthesis and upconversion properties of lutetium fluoride (doped with Yb3+/Er3+) microcrystals by hydrothermal process. J Phys Chem C 112:13395–13404

    Article  Google Scholar 

  • Li YP, Zhang JH, Luo YS, Zhang X, Hao ZD, Wang XJ (2011) Color control and white light generation of upconversion luminescence by operating dopant concentrations and pump densities in Yb3+, Er3+ and Tm3+ tri-doped Lu2O3 nanocrystals. J Mater Chem 21:2895–2900

    Article  Google Scholar 

  • Lin J, Huo J, Cai Y, Wang Q (2013) Controllable synthesis of Eu3+/Tb3+ activated lutetium fluorides nanocrystals and their photophysical properties. J Luminescence 144:1–5

    Article  Google Scholar 

  • Liu Q, Sun Y, Yang TS, Feng W, Li CG, Li FY (2011) Sub-10 nm hexagonal lanthanide-doped NaLuF4 upconversion nanocrystals for sensitive bioimaging in vivo. J Am Chem Soc 133:17122–17125

    Article  Google Scholar 

  • Mai HX, Zhang YW, Si R, Yan ZG, Sun LD, You LP, Yan CH (2006) High-quality sodium rare-earth fluoride nanocrystals: controlled synthesis and optical properties. J Am Chem Soc 128:6426–6436

    Article  Google Scholar 

  • Matijevic E (1993) Preparation and properties of uniform size colloids. Chem Mater 5:412–426

    Article  Google Scholar 

  • Maunier C, Doualan JL, Moncorge R, Cavalli E (2002) Growth, spectroscopic characterization, and laser performance of Nd:luVO4, a new infrared laser material that is suitable for diode pumping. J Opt Soc Am B 19:1794–1800

    Article  Google Scholar 

  • Pi D, Wang F, Fan X, Wang M, Zhang Y (2005) Luminescence behavior of Eu3+ doped LaF3 nanoparticles. Spectrochim Acta Part A 61:2455–2459

    Article  Google Scholar 

  • Privman V, Goia DV, Park J, Matijević E (1999) Mechanism of formation of monodisperse colloids by aggregation of nanosize precursors. J Colloid Interface Sci 213:36–45

    Article  Google Scholar 

  • Qiu P, Zhou N, Wang Y, Zhang C, Wang Q, Sun R, Gao G, Cui D (2014) Tuning lanthanide ion-doped upconversion nanocrystals with different shapes via a one-pot cationic surfactant-assisted hydrothermal strategy. CrystEngComm 16:1859–1863

    Article  Google Scholar 

  • Rao L, Lu W, Ren G, Wang H, Yi Z, Liu H, Zeng S (2014) Monodisperse LaF3 nanocrystals: shape-controllable synthesis, excitation-power-dependent multi-color tuning and intense near-infrared upconversion emission. Nanotechnology 25:065703

    Article  Google Scholar 

  • Shannon RD (1976) Revised effective ionic-radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Cryst A 32:751–767

    Article  Google Scholar 

  • Singh NS, Ningthoujam RS, Phaomei G, Dorendrajit S, Vinu A, Vatsa RK (2012) Re-dispersion and film formation of GdVO4: Ln3+ (Ln3+ = Dy3+, Eu3+, Sm3+, Tm3+) nanoparticles: particle size and luminescence studies. Dalton Trans 41:4404–4412

    Article  Google Scholar 

  • Sudesh V, Asai K (2003) Spectroscopic and diode-pumped-laser properties of Tm, Ho:YLF; Tm, Ho:LuLF; and Tm, Ho:LuAG crystals: a comparative study. J Opt Soc Am B 20:1829–1837

    Article  Google Scholar 

  • Sun YJ, Chen Y, Tian LJ, Yu Y, Kong XG, Zhao JW, Zhang H (2007) Controlled synthesis and morphology dependent upconversion luminescence of NaYF4:Yb, Er nanocrystals. Nanotechnology 18:275609

    Article  Google Scholar 

  • Tanner PA (2013) Some misconceptions concerning the electronic spectra of tri-positive europium and cerium. Chem Soc Rev 42:5090–5101

    Article  Google Scholar 

  • Vegard L (1921) The constitution of the mixed crystals and the filling of space of the atoms. Z Phys 5:17–26

    Article  Google Scholar 

  • Vijayakumar R, Maheshvaran K, Sudarsan V, Marimuthu K (2014) Concentration dependent luminescence studies on Eu3+ doped telluro fluoroborate glasses. J Lumin 154:160–167

    Article  Google Scholar 

  • Wang LY, Li YD (2006) Green upconversion nanocrystals for DNA detection. Chem Comm 24:2557–2559

    Article  Google Scholar 

  • Wang L, Li Y (2007) Controlled synthesis and luminescence of lanthanide doped NaYF4 nanocrystals. Chem Mater 19:727–731

    Article  Google Scholar 

  • Xiao S, Yang X, Ding JW, Yan XH (2007) Up-conversion in Yb3+-Tm3+Co-doped lutetium fluoride particles prepared by a combustion-fluorization method. J Phys Chem C 111:8161–8165

    Article  Google Scholar 

  • Yan R, Li Y (2005) Down/up conversion in Ln3+-doped YF3 nanocrystals. Adv Funct Mater 15:763–770

    Article  Google Scholar 

  • Yi GH, Lu HC, Zhao SY, Yue G, Yang WJ, Chen DP, Guo LH (2004) Synthesis, characterization, and biological application of size-controlled nanocrystalline NaYF4: Yb, Er infrared-to-visible up-conversion phosphors. Nano Lett 4:2191–2196

    Article  Google Scholar 

Download references

Acknowledgments

Supported by MEC (Project. MAT2012-34919), Junta de Andalucía (JA FQM 06090) and CSIC (201460E005).

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Correspondence to Ana I. Becerro.

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Becerro, A.I., Gonzalez-Mancebo, D. & Ocaña, M. Uniform, luminescent Eu:LuF3 nanoparticles. J Nanopart Res 17, 58 (2015). https://doi.org/10.1007/s11051-015-2874-z

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